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Total alkalinity

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Total alkalinity is a measure of the capacity of water to neutralize acids, primarily due to the presence of bicarbonate, carbonate, and hydroxide ions. It reflects the buffering capacity of water, influencing its pH stability and overall chemical balance.
lightbulbAbout this topic
Total alkalinity is a measure of the capacity of water to neutralize acids, primarily due to the presence of bicarbonate, carbonate, and hydroxide ions. It reflects the buffering capacity of water, influencing its pH stability and overall chemical balance.

Key research themes

1. How can precise and accurate measurement methods improve the determination of total alkalinity in seawater and natural waters?

Accurate measurement of total alkalinity (TA) is critical for characterizing carbonate chemistry essential to oceanic carbon dioxide system analysis and environmental monitoring. This research theme addresses methodological improvements, interlaboratory comparisons, and calibration approaches that enhance the precision and reproducibility of alkalinity determinations, which underpin understanding of geochemical processes and climate models.

Key finding: Reported a interlaboratory exercise comparing three potentiometric titration methods and demonstrated that TA measurement precision between labs was improved significantly (mean standard deviation reduced to ~0.87 µmol/kg)... Read more
Key finding: Demonstrated the use of Gran titration methods for measuring alkalinity to link theoretical carbonate equilibria with practical data in surface waters, thereby enhancing pedagogical understanding of carbonate chemistry. This... Read more
Key finding: Developed a systematic theoretical framework to interpret the volume of acid consumed in titration-based alkalinity determination, addressing difficulties in conceptual understanding among students. Provided mathematical and... Read more
Key finding: Presented a refined calibration methodology for pH meters in highly alkaline solutions relevant to cementitious systems, highlighting limitations of the conventional pH 4, 7, 10 calibration which underestimates true pH by up... Read more

2. What are the implications and challenges of increasing alkalinity in marine environments for carbon dioxide removal and environmental stability?

This theme investigates the use of ocean alkalinity enhancement (OAE) as a carbon dioxide removal approach and analyzes the stability, chemical consequences, and environmental implications of artificially increasing alkalinity in seawater. Key concerns include carbonate mineral precipitation that may reduce alkalinity and CO 2 storage efficiency, and methods to optimize application of alkaline materials to avoid unintended losses.

Key finding: Conducted laboratory experiments demonstrating that addition of alkaline solutions (rather than reactive alkaline solids) to seawater minimizes alkalinity loss by avoiding carbonate mineral precipitation. Found exceeding... Read more

3. How do natural and anthropogenic factors contribute to high environmental alkalinity and its effects on soils and waters?

This research focuses on understanding the genesis, spatial distribution, and ecological impacts of environments exhibiting unusually high alkalinity (pH ≥ 9), commonly influenced by geological, hydrological, and biogeochemical processes. It evaluates how alkalinity levels affect soil and water chemistry, plant growth, and ecosystem health, especially considering evapotranspiration-driven concentration and hydrological stagnation in sedimentary basins.

Key finding: Proposed and empirically supported a conceptual model that very high alkalinity environments arise primarily due to hydrological stagnation combined with evaporative concentration exceeding the calcite buffering capacity.... Read more

All papers in Total alkalinity

Experiments for evaluating growth, survival and production performance of Indian Major Carp (IMC) fry were conducted in three creeks of Kaptai Lake viz., Islamabad, Hazachara and Vaittapara of Bangladesh for a period of eight weeks.... more
The present work evaluate the chemical conditions of the Murucupi river with relationship to the physical-chemical parameters and the presence of chemical elements in the water and correlations. The Murucupi river is located in the amazon... more
In order to study the effect of aquaculture activities in a rainbow trout breeding and cultivation farm on water physicochemical properties of Daryasar Stream (North of Iran), 5 sampling sites were selected inside the stream. The first... more
Rhodolith beds are the dominant submerged calcifying aquatic vegetation in some coastal marine environments worldwide but few quantitative data are available regarding their physiology. In the Gulf of California (Mexico), Lithophyllum... more
Patients with epilepsy and treated with antiepileptic drugs (AEDs) may develop metabolic bone disease; however, the exact pathogenesis of bone loss with AEDs is still unclear. Included were 75 adults with epilepsy (mean age: 31.90 ± 5.62... more
The present study was focused to determine the distributional patterns of the functional feeding groups (FFG) benthic macroinvertebrate in assessment of river health of the river Bhagirathi. The benthic macroinvertebrate samples were... more
The Baltic-C project aims at building predictive capability regarding the Baltic Sea organic/inorganic carbon and oxygen systems during present and future climate conditions. This modeling framework will be used for the predictive... more
We estimated the net annual air-sea exchange of CO2 using high-quality monitoring data from the Gotland Sea, Bornholm Sea, and Kattegat for the 1993-2007 period. Sea surface partial pressure of CO2 (pCO2w), was calculated from pH, total... more
Background: Chronic Kidney Disease (CKD) and Mineral-Bone Disorders (MBD) are important health problems. According to the KDIGO CKD-MBD guideline, bone loss and fracture risks are higher in CKD patients than in age-matched controls... more
Experiments were conducted in laboratory to observe periphytic growth on four types of plastic sheets, such as polyethylene (PE), polypropylene (PP), fiber reinforced plastic (FRP) and acrylic placed inside the glass aquaria filled with... more
High biomass and heavy particle loads may interfere with carbonate chemistry analyses of samples from experimental aquaria and cultures used to investigate the impact of ocean acidification on organisms, as well as from biologically... more
Ocean liming, OL is proposed as a geoengineering technic with the intention to artificial increase ocean alkalinisation. Enhanced alkalinity will increase the acid neutralizing capacity and thereby reverse ocean acidification. The... more
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