TWI682726B - Flavor inhaler, combustion type heat source - Google Patents

Flavor inhaler, combustion type heat source Download PDF

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Publication number
TWI682726B
TWI682726B TW106121982A TW106121982A TWI682726B TW I682726 B TWI682726 B TW I682726B TW 106121982 A TW106121982 A TW 106121982A TW 106121982 A TW106121982 A TW 106121982A TW I682726 B TWI682726 B TW I682726B
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Taiwan
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fragrance
heat source
combustion
type heat
flavor
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TW106121982A
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Chinese (zh)
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TW201806497A (en
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中野拓磨
秋山健
小田崇
鈴木正昭
山田敦郎
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日商日本煙草產業股份有限公司
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Abstract

A flavor inhaler 11 includes a tubular holder 12 extending from a mouth end 12A to a distal end 12B, a flavor source 16 retained in the holder 12, and a combustion type heat source 13 provided at the distal end 12B and containing activated carbon and carrying perfume 15, wherein the BET specific surface area of the activated carbon is 1300 m2/ g or more.

Description

香味吸嚐器、燃燒型熱源 Aroma taster, burning heat source

本發明係關於可由吸口端吸嚐香味之香味吸嚐器,及用於該香味吸嚐器之燃燒型熱源。 The invention relates to a scent taster which can taste scent from the mouth end, and a combustion type heat source used for the scent taster.

日本特表2010-535530號公報揭示蒸餾基底之吸煙物品。該文獻中揭示可在可燃性熱源之後部端面附加1種以上的香味料。 Japanese Special Publication No. 2010-535530 discloses a smoking article with a distillation base. This document discloses that one or more flavors can be added to the rear end surface of the flammable heat source.

國際公開WO2013/146951號說明書揭示以碳熱源加熱香味產生源而吸嚐香味之香味吸嚐具。 International Publication No. WO2013/146951 discloses a scent taster that uses a carbon heat source to heat a scent generation source and taste the scent.

使用者對於此類香味吸嚐器的嗜好多元,而強化製品所保有的香味,係在提供合乎使用者的嗜好之具吸引力製品時為有效的手段。 The user's preferences for such flavor inhalers are diverse, and the aroma retained by the fortified product is an effective means of providing attractive products that fit the user's preferences.

本發明之一形態之香味吸嚐器係具備:由吸口端延伸至前端之筒狀固持器;保持於前述固持器內之香味源;及燃燒型熱源,係設置於前述前端,含有活性碳且擔載有香料,且BET比表面積為1300m2/g以上。 A flavor taster according to one aspect of the present invention includes: a cylindrical holder extending from the suction end to the front end; a flavor source held in the holder; and a combustion-type heat source, which is provided at the front end and contains activated carbon and Perfume is supported, and the BET specific surface area is 1300 m 2 /g or more.

根據本發明可提供合乎使用者嗜好之香味吸嚐器。 According to the present invention, it is possible to provide a flavor inhaler suitable for the user's taste.

11‧‧‧香味吸嚐器 11‧‧‧Fragrant taste taster

12‧‧‧固持器 12‧‧‧Retainer

12A‧‧‧吸口端 12A‧‧‧Suction port

12B‧‧‧前端 12B‧‧‧Front end

13‧‧‧燃燒型熱源 13‧‧‧Combustion heat source

14‧‧‧突出部 14‧‧‧Projection

15‧‧‧香料 15‧‧‧ Spice

16‧‧‧香味源 16‧‧‧Scent source

17‧‧‧杯具 17‧‧‧Cup

17A‧‧‧段部 17A‧‧‧

18‧‧‧鋁貼合紙 18‧‧‧Aluminum laminated paper

21‧‧‧過濾器部 21‧‧‧Filter Department

22‧‧‧膠囊 22‧‧‧ capsules

23‧‧‧第1部分 23‧‧‧Part 1

24‧‧‧第2部分 24‧‧‧Part 2

25‧‧‧底部 25‧‧‧Bottom

25A‧‧‧開孔部 25A‧‧‧Opening

26‧‧‧緣部 26‧‧‧ Edge

27‧‧‧本體部分 27‧‧‧Body part

28‧‧‧前端面 28‧‧‧Front face

29‧‧‧基端面 29‧‧‧Base end face

31‧‧‧通氣路 31‧‧‧Ventilation

32‧‧‧外周面 32‧‧‧Perimeter

33‧‧‧溝部 33‧‧‧ Ditch

34‧‧‧第1倒角部 34‧‧‧First chamfer

35‧‧‧第2倒角部 35‧‧‧Chamfer 2

36‧‧‧吸口 36‧‧‧Suction

41‧‧‧第2香料 41‧‧‧ Second Spice

42‧‧‧擔載部 42‧‧‧ Carrying Department

51‧‧‧第3香料 51‧‧‧3rd spice

61‧‧‧測定裝置 61‧‧‧Determination device

62‧‧‧固持器部 62‧‧‧Retainer Department

63‧‧‧劍橋式過濾器 63‧‧‧Cambridge filter

64‧‧‧自動吸煙器 64‧‧‧Automatic smoking machine

65‧‧‧空氣採集器 65‧‧‧Air collector

66‧‧‧管 66‧‧‧ tube

C‧‧‧中心軸 C‧‧‧Central axis

第1圖係將實施形態之香味吸嚐器以含中心軸C的面裁切表示之剖面圖。 Fig. 1 is a cross-sectional view of the flavor inhaler of the embodiment cut along the surface including the central axis C.

第2圖之斜視圖係表示第1圖所示的香味吸嚐器之燃燒型熱源。 The perspective view of FIG. 2 shows the combustion-type heat source of the flavor taster shown in FIG.

第3圖之斜視圖係表示第2圖所示的香味吸嚐器之燃燒型熱源之製造步驟。 FIG. 3 is a perspective view showing the manufacturing process of the combustion type heat source of the flavor inhaler shown in FIG. 2.

第4圖係表示於燃燒型熱源之突出部擔載各種香料時的藏置試驗結果。 Figure 4 shows the results of storage tests when various fragrances were loaded on the protrusions of the combustion-type heat source.

第5圖之示意圖係表示用以測定往主流煙之轉移率之測定裝置。 The schematic diagram in Fig. 5 shows a measuring device for measuring the transfer rate to mainstream smoke.

[實施形態] [Embodiment]

以下參照圖式說明香味吸嚐器之實施形態。該香味吸嚐器係例如以位於前端側之燃燒型熱源加溫香味源,並由吸口側進行吸嚐,藉此讓使用者品嚐來自香味源之香味。 The embodiment of the flavor taster will be described below with reference to the drawings. The flavor inhaler, for example, uses a combustion-type heat source located on the front end side to warm the flavor source, and the intake side performs tasting, thereby allowing the user to taste the flavor from the flavor source.

如第1圖、第2圖所示,香味吸嚐器11係具備:由吸口端12A延伸至前端12B之筒狀(圓筒形)固持器12;設置於固持器12之前端12B之燃燒型熱源13;擔 載於燃燒型熱源13之香料15、第2香料41及第3香料51;設置於固持器12內之香味源16;於內部收納香味源16之杯具17;在固持器12內側中介存在於與杯具17的空間之鋁貼合紙18;在固持器12內側設置於吸口端12A側之過濾器部21;及填埋於過濾器部21內部之膠囊22(香料膠囊)。 As shown in FIGS. 1 and 2, the flavor taster 11 is provided with: a cylindrical (cylindrical) holder 12 extending from the mouth end 12A to the front end 12B; a combustion type provided at the front end 12B of the holder 12 Heat source 13 The fragrance 15, the second fragrance 41, and the third fragrance 51 contained in the combustion-type heat source 13; the fragrance source 16 provided in the holder 12; the cup 17 containing the fragrance source 16 inside; and the medium 12 present inside the holder 12 The aluminum bonding paper 18 in the space of the cup 17; the filter part 21 provided on the suction port end 12A side inside the holder 12; and the capsule 22 (perfume capsule) buried inside the filter part 21.

固持器12係具有:保持燃燒型熱源13及杯具17之第1部分23、及連結第1部分23與位於吸口端12A側之過濾器部21之第2部分24。第1部分23係將紙捲為圓筒形而形成的紙管。第2部分24係外層紙(tipping paper)用紙,該外層紙用紙一般係使用作為附過濾器香菸(紙捲菸香菸)中包覆過濾器部的紙,且將該外層紙用紙捲成為圓筒形而形成第2部分24。鋁貼合紙18一般係將鋁貼合於紙而形成,且與一般的紙相比更提高耐熱性及熱傳導性。藉由該鋁貼合紙18,即使於燃燒型熱源13點火時亦不會燃燒固持器12之第1部分23(紙管)。固持器12之中心軸C與燃燒型熱源13之中心軸C一致。 The holder 12 includes a first portion 23 that holds the combustion-type heat source 13 and the cup 17, and a second portion 24 that connects the first portion 23 and the filter portion 21 on the suction port end 12A side. The first part 23 is a paper tube formed by rolling a paper into a cylindrical shape. The second part 24 is a paper for outer paper (tipping paper). The outer paper is generally used as a paper covering a filter part in a cigarette with a filter (paper cigarette), and the outer paper is rolled into a cylindrical shape Instead, the second part 24 is formed. The aluminum bonding paper 18 is generally formed by bonding aluminum to paper, and it has improved heat resistance and thermal conductivity compared to general paper. With the aluminum bonding paper 18, even when the combustion-type heat source 13 is ignited, the first portion 23 (paper tube) of the holder 12 is not burned. The central axis C of the holder 12 coincides with the central axis C of the combustion-type heat source 13.

香味源16係在鄰接燃燒型熱源13之位置設置於燃燒型熱源13的下游處。以由菸草萃取物等所形成的顆粒而構成香味源16。又,香味源16並不限於顆粒,可使用菸草的葉片本身。亦即,香味源16亦可採用香菸中所使用之一般的絲狀細切菸草、鼻菸中所使用之粒狀菸草、卷狀菸草、成型菸草等菸草原料。香味源16可採用在多孔質素材或非多孔質素材之載體擔載有香味者。卷狀菸草係 將薄片狀再生菸草成型為卷狀而獲得,並在內部具有流路。又,成型菸草係藉由將粒狀菸草以模具成型而獲得。使用作為香味源16之菸草原料或載體中可含有所要求的香料。香味源16係例如具有酸性pH。 The fragrance source 16 is disposed downstream of the combustion-type heat source 13 at a position adjacent to the combustion-type heat source 13. The flavor source 16 is constituted by particles formed from tobacco extract or the like. In addition, the flavor source 16 is not limited to particles, and the tobacco leaf itself may be used. In other words, the flavor source 16 may also use tobacco raw materials such as general filament-like fine-cut tobacco used in cigarettes, granular tobacco used in snuff, rolled tobacco, and formed tobacco. The scent source 16 may be one that carries a scent on a carrier of porous material or non-porous material. Rolled Tobacco The sheet-shaped regenerated tobacco is obtained by molding into a roll shape, and has a flow path inside. Moreover, the molded tobacco is obtained by molding granular tobacco in a mold. The tobacco material or carrier used as flavor source 16 may contain the desired flavor. The fragrance source 16 has an acidic pH, for example.

香味源16之pH分析例如可採用以下方法。首先採集400mg香味源16,添加純水4mL並振動萃取60分鐘。在控制為22℃室溫之實驗室內,將萃取液放置於密閉容器內並進行溫度調和至達到室溫為止,而進行溫度調和。調和後打開蓋子,將於pH計(METTLERTOLEDO公司製:seveneasy S20)之玻璃電極浸於捕集液,並開始測定。pH計事先以pH4.01、6.87、9.21之pH計校正液校正。將感應器之輸出變動於5秒內安定在0.1mV內之點,作為其萃取溶液(香味源16)之pH。又,此香味源16之pH測定方法只為其中一例,當然亦可採用其他手法。 For the pH analysis of the fragrance source 16, for example, the following method can be used. First, 400 mg of fragrance source 16 was collected, 4 mL of pure water was added, and vibration extraction was performed for 60 minutes. In a laboratory controlled to a room temperature of 22°C, place the extract in a closed container and adjust the temperature until it reaches room temperature, and then adjust the temperature. After reconciliation, the lid is opened, and the glass electrode of the pH meter (manufactured by METTLERTOLEDO: seveneasy S20) is immersed in the trapping liquid and the measurement is started. The pH meter is calibrated in advance with pH meter calibration solutions of pH 4.01, 6.87, and 9.21. The point where the output of the sensor fluctuates within 0.1mV within 5 seconds is taken as the pH of its extraction solution (fragrance source 16). In addition, the method of measuring the pH of the fragrance source 16 is only one example, and of course other methods may be used.

杯具17係以金屬材料形成為有底的圓筒狀。於杯具17之底部25形成有複數個開孔部25A。使用者吸嚐時,菸草香味與空氣一起通過該開孔部25A而往固持器12之下游側被吸引。杯具17之緣部26係朝固持器12之半徑方向外側彎曲,並可卡在固持器12及鋁貼合紙18之前端。於杯具17之內周面設置有與燃燒型熱源13之基端面29抵接之段部17A。杯具17之內周面係可與段部17A一起收容燃燒型熱源13之本體部分27,而保持使燃燒型熱源13不會脫落。 The cup 17 is formed into a cylindrical shape with a bottom by a metal material. A plurality of openings 25A are formed on the bottom 25 of the cup 17. When the user tastes, the tobacco flavor and air pass through the opening 25A and are attracted to the downstream side of the holder 12. The edge portion 26 of the cup 17 is curved outward in the radial direction of the holder 12 and can be caught on the front end of the holder 12 and the aluminum bonding paper 18. The inner peripheral surface of the cup 17 is provided with a segment portion 17A that is in contact with the base end surface 29 of the combustion-type heat source 13. The inner peripheral surface of the cup 17 can accommodate the body portion 27 of the combustion-type heat source 13 together with the segment 17A, while keeping the combustion-type heat source 13 from falling off.

杯具17可為紙製杯具。紙製杯具例如具有 與上述金屬製杯具相同之構造。紙製杯具可使用紙漿射出成型之公知技術製造。具體而言,紙製杯具係藉由將含有紙漿、黏合劑及水之原料混練,注入於經加熱模具並使其乾燥固化而製造。以香味之觀點來看,黏合劑較佳為使用CMC(羧甲基纖維素)或CMC-Na(羧甲基纖維素鈉)。相較於金屬製杯具,紙製杯具有熱對於香味源16之傳導速度較慢之特性。又,紙製杯具可輕量化香味吸嚐器或降低製造成本。 The cup 17 may be a paper cup. Paper cups for example have It has the same structure as the metal cup described above. Paper cups can be manufactured using well-known techniques of pulp injection molding. Specifically, the paper cup is manufactured by kneading raw materials containing pulp, a binder, and water, pouring it into a heated mold, and drying and solidifying it. From the viewpoint of flavor, the binder is preferably CMC (carboxymethyl cellulose) or CMC-Na (carboxymethyl cellulose sodium). Compared to metal cups, paper cups have the characteristic that the heat transfer rate to the flavor source 16 is slower. In addition, paper cups can lighten the flavor inhaler or reduce manufacturing costs.

過濾器部21係以香菸一般使用之過濾器而構成。膠囊22亦同樣地為香菸中一般所使用之香料膠囊,並在內部儲藏含有薄荷醇、醛系香料及單萜烯香料等之中至少一種之溶液。其中,尤其醛系香料及單萜烯香料會因與外部空氣接觸而氧化,故較佳為封入於膠囊22內。又,薄荷醇揮散並轉移至燃燒型熱源13時會產生不佳香味,故較佳為封入於膠囊22內。 The filter unit 21 is constituted by a filter generally used for cigarettes. The capsule 22 is also a flavor capsule generally used in cigarettes, and a solution containing at least one of menthol, aldehyde flavor, and monoterpene flavor is stored inside. Among them, in particular, aldehyde-based fragrances and monoterpene fragrances are oxidized by contact with outside air, so it is preferably enclosed in the capsule 22. In addition, when menthol is volatilized and transferred to the combustion-type heat source 13, an unfavorable flavor is generated, so it is preferably enclosed in the capsule 22.

過濾器部21可以各種類的填充材形成。本實施形態中,過濾器部21例如以纖維素乙酸酯等纖維素系半合成纖維之填充材而構成,但填充材並不限定於此。填充材可使用例如綿、麻、馬尼拉麻(Musa textilis)、椰子、燈心草等植物纖維、羊毛、喀什米爾羊毛等動物纖維、嫘縈(rayon)等纖維素系再生纖維、耐綸、聚酯、丙烯酸酯、聚乙烯、聚丙烯等合成纖維、或組合該等者。過濾器部21之構成要素除了包括上述纖維素乙酸酯纖維之填充物以外,也可為含有木炭(charcoal)之木炭過濾器、或加入木炭 以外之粒狀物之過濾器。又,過濾器部21可為在軸方向連接2個以上相異種類區段而成之多區段構造。 The filter portion 21 can be formed of various types of fillers. In the present embodiment, the filter portion 21 is formed of, for example, a filler material of cellulose-based semi-synthetic fibers such as cellulose acetate, but the filler material is not limited to this. For the filler, plant fibers such as cotton, hemp, manila hemp (Musa textilis), coconut, rushes, animal fibers such as wool, cashmere wool, rayon and other cellulose-based regenerated fibers, nylon, polyester, Synthetic fibers such as acrylate, polyethylene, polypropylene, or a combination of these. The constituent elements of the filter unit 21 may be a charcoal filter containing charcoal or a charcoal addition, in addition to the filler including the cellulose acetate fiber described above Filters for other particles. In addition, the filter portion 21 may have a multi-segment structure in which two or more different types of segments are connected in the axial direction.

如第2圖所示,燃燒型熱源13(碳熱源)係藉由將含有源自於植物之活性碳、不燃添加物、黏合劑(有機黏合劑或無機黏合劑)、水等之混合物之燃燒材料,以壓錠、壓鑄等方法予以一體成型而形成。燃燒型熱源13係含有活性碳及黏合劑等如蜂窩煤之混合物。燃燒型熱源13係含有在活性碳中所謂的被稱為所謂高活性碳者。高活性碳是指活性碳中以ISO9277:2010、JIS Z 8830:2013規格化且經Brunauer-Emmett-Teller方法(BET法)所測定之比表面積例如為1300m2/g以上者。燃燒型熱源13所使用活性碳係具有含有複數個大孔隙及複數個微孔隙之多孔質構造。 As shown in Figure 2, the combustion-type heat source 13 (carbon heat source) is obtained by burning a mixture containing activated carbon derived from plants, non-combustible additives, binder (organic binder or inorganic binder), water, etc. The material is formed by integral molding using methods such as die ingot and die casting. The combustion-type heat source 13 is a mixture containing activated carbon and a binder such as honeycomb coal. The combustion-type heat source 13 contains what is called so-called highly activated carbon in activated carbon. Highly activated carbon refers to the activated carbon standardized to ISO9277:2010 and JIS Z 8830:2013 and having a specific surface area measured by the Brunauer-Emmett-Teller method (BET method) of, for example, 1300 m 2 /g or more. The activated carbon used in the combustion-type heat source 13 has a porous structure containing plural macropores and plural micropores.

本實施形態之燃燒型熱源13之活性碳之BET比表面積例如為1300m2/g以上2500m2/g以下。更佳三燃燒型熱源13之活性碳之BET比表面積例如為2000m2/g以上2500m2/g以下。最佳的燃燒型熱源13之活性碳之BET比表面積例如為2050m2/g以上2300m2/g以下。因此,本實施形態之燃燒型熱源13所使用的活性碳係分類為高活性碳者,其大孔隙及微孔隙之量較一般的活性碳多。換言之,相較於一般活性碳,本實施形態之燃燒型熱源13所使用之賦活度較一般的活性碳高。亦即,燃燒型熱源13所使用之活性碳係藉由將碳材料進行加熱處理等而去除揮發性雜質,並較一般的活性碳更為提高賦活度而獲得。與香味源 16相異,燃燒型熱源13係例如具有鹼性pH。 The BET specific surface area of the activated carbon of the combustion-type heat source 13 of this embodiment is, for example, 1300 m 2 /g or more and 2500 m 2 /g or less. More preferably, the BET specific surface area of the activated carbon of the three-combustion heat source 13 is, for example, 2000 m 2 /g or more and 2500 m 2 /g or less. The activated carbon optimal combustion type heat source 13, for example, BET specific surface area of 2050m 2 / g or more 2300m 2 / g or less. Therefore, the activated carbon used in the combustion-type heat source 13 of this embodiment is classified as highly activated carbon, and the amount of macropores and micropores is larger than that of general activated carbon. In other words, the combustion-type heat source 13 of the present embodiment uses a higher degree of activation than general activated carbon compared to general activated carbon. That is, the activated carbon used in the combustion-type heat source 13 is obtained by heat treatment of the carbon material to remove volatile impurities, and the activation degree is higher than that of general activated carbon. Unlike the fragrance source 16, the combustion-type heat source 13 has an alkaline pH, for example.

燃燒型熱源13可含有10重量%至99重量%之範圍之活性碳。在此,以供給充分的熱量或防止灰掉落等燃燒特性之觀點來看,燃燒型熱源13所含之活性碳之濃度例如較佳為30重量%以上60重量%以下。更佳係燃燒型熱源13所含的活性碳之濃度為30重量%以上45重量%以下。 The combustion-type heat source 13 may contain activated carbon in the range of 10% to 99% by weight. Here, the concentration of the activated carbon contained in the combustion-type heat source 13 is preferably 30% by weight or more and 60% by weight or less from the viewpoint of supplying sufficient heat or preventing combustion characteristics such as ash fall. More preferably, the concentration of activated carbon contained in the combustion-type heat source 13 is 30% by weight or more and 45% by weight or less.

有機黏合劑可使用例如含有CMC(羧甲基纖維素)、CMC-Na(羧甲基纖維素鈉)、海藻酸鹽、乙烯乙酸乙烯酯(EVA)、聚乙烯醇(PVA)、聚乙酸乙烯酯(PVAc)及糖類之至少1種之混合物。 As the organic binder, for example, CMC (carboxymethyl cellulose), CMC-Na (carboxymethyl cellulose sodium), alginate, ethylene vinyl acetate (EVA), polyvinyl alcohol (PVA), polyvinyl acetate can be used. A mixture of at least one ester (PVAc) and sugar.

又,無機黏合劑可使用例如精製膨土等礦物系、或膠體二氧化矽、水玻璃、矽酸鈣等二氧化矽系黏合劑。 In addition, as the inorganic binder, for example, mineral-based binders such as refined bentonite, or silica-based binders such as colloidal silica, water glass, and calcium silicate.

例如以香味之觀點來看,上述黏合劑較佳為含有1重量%至10重量%之CMC或CMC-Na,更佳為含有1重量%至8重量%之CMC或CMC-Na。 For example, from the viewpoint of fragrance, the above-mentioned adhesive preferably contains 1 to 10% by weight of CMC or CMC-Na, more preferably contains 1 to 8% by weight of CMC or CMC-Na.

又,不燃添加物可使用例如包含鈉、鉀、鈣、鎂、矽等之碳鹽或氧化物。又,燃燒型熱源13可含有40重量%至89重量%之不燃添加物。 In addition, as the non-combustible additive, for example, carbon salts or oxides containing sodium, potassium, calcium, magnesium, silicon, and the like can be used. In addition, the combustion-type heat source 13 may contain 40% to 89% by weight of non-combustible additives.

在此,不燃添加物係使用碳酸鈣,燃燒型熱源13較佳為含有40重量%至60重量%之不燃添加物。 Here, calcium carbonate is used as the non-combustible additive, and the combustion-type heat source 13 preferably contains 40 to 60% by weight of the non-combustible additive.

以改善燃燒特性為目的,燃燒型熱源13亦可含有1重量%以下比例之氯化鈉等鹼金屬鹽。 For the purpose of improving combustion characteristics, the combustion-type heat source 13 may also contain alkali metal salts such as sodium chloride at a ratio of 1% by weight or less.

如第1圖、第2圖所示,燃燒型熱源13係形成為圓柱形。燃燒型熱源13係具有:保持於固持器12內之本體部分27、由固持器12之前端12B突出之突出部14(露出部)、設置於突出部14之前端面28、與前端面28相對向之基端面29、用以在固持器12內部供給空氣之通氣路31、鄰接前端面28之外周面32、及設置於突出部14之溝部33。通氣路31係沿燃燒型熱源13之中心軸C而設置,且以貫通燃燒型熱源13之方式設置。通氣路31係使前端面28與基端面29連通。通氣路31係以跨越本體部分27及突出部14兩者之方式設置。通氣路31之前端面28側之部分係與溝部33成為一體。外周面32係在對應突出部14之位置形成於燃燒型熱源13周圍。突出部14(露出部)係亦由杯具17之前端突出。 As shown in FIGS. 1 and 2, the combustion-type heat source 13 is formed in a cylindrical shape. The combustion-type heat source 13 includes a body portion 27 held in the holder 12, a protruding portion 14 (exposed portion) protruding from the front end 12B of the holder 12, a front end surface 28 provided on the protruding portion 14, and a front end surface 28 facing The base end surface 29, the ventilation path 31 for supplying air inside the holder 12, the outer peripheral surface 32 adjacent to the front end surface 28, and the groove portion 33 provided in the protruding portion 14. The ventilation path 31 is provided along the central axis C of the combustion-type heat source 13 and is provided so as to penetrate the combustion-type heat source 13. The air passage 31 connects the front end surface 28 and the base end surface 29. The ventilation path 31 is provided so as to straddle both the body portion 27 and the protruding portion 14. The portion of the air passage 31 on the front end surface 28 side is integrated with the groove 33. The outer peripheral surface 32 is formed around the combustion-type heat source 13 at a position corresponding to the protruding portion 14. The protruding portion 14 (exposed portion) also protrudes from the front end of the cup 17.

燃燒型熱源13係具有形成於前端面28與外周面32之間之第1倒角部34、及形成於基端面29與外周面32之間之第2倒角部35。藉由第1倒角部34及第2倒角部35,而不易產生燃燒型熱源13之角部中的破裂或缺陷。 The combustion-type heat source 13 has a first chamfered portion 34 formed between the front end surface 28 and the outer peripheral surface 32 and a second chamfered portion 35 formed between the base end surface 29 and the outer peripheral surface 32. With the first chamfered portion 34 and the second chamfered portion 35, cracks or defects in the corner portion of the combustion-type heat source 13 are less likely to occur.

由前端面28側觀看,溝部33整體係形成「十」字狀。溝部33之形狀並不限定於「十」字狀。溝部33的條數為任意。又,溝部33整體所形成的形狀可設為任意形狀。例如複數個溝部33可以通氣路31為中心朝向外周面32延伸成放射狀。此時,鄰接之溝部33彼此間所夾的角角度例如可適宜設定為5°以上95°以下之範圍內。 又,本實施形態中,溝部33係以跨越為前端面28與外周面32之方式自該等凹陷而形成。溝部33係以與通氣路31連通之方式設置。燃燒型熱源13在中心軸C方向之溝部33深度(長度)較佳為例如中心軸C方向之全長之1/3至1/5。 Viewed from the front end surface 28 side, the entire groove 33 is formed in a "ten" shape. The shape of the groove 33 is not limited to the "ten" shape. The number of grooves 33 is arbitrary. The shape of the groove 33 as a whole may be any shape. For example, the plurality of grooves 33 may extend radially toward the outer peripheral surface 32 with the air passage 31 as the center. At this time, the angle between the adjacent groove portions 33 may be set appropriately within a range of 5° or more and 95° or less, for example. In the present embodiment, the groove 33 is formed from these depressions so as to span the front end surface 28 and the outer peripheral surface 32. The groove 33 is provided so as to communicate with the air passage 31. The depth (length) of the groove portion 33 of the combustion-type heat source 13 in the direction of the central axis C is preferably, for example, 1/3 to 1/5 of the total length in the direction of the central axis C.

燃燒型熱源13較佳為形成如以下尺寸。燃燒型熱源13之全長(中心軸C方向之燃燒型熱源13之長度)例如適宜設定在5mm以上30mm以下之範圍內,更佳為10mm以上20mm以下之範圍內。其中,中心軸C方向之突出部14之長度例如適宜設定於5mm以上15mm以下之範圍內,更佳為5mm以上10mm以下之範圍內。因此,突出部14之長度例如設定在燃燒型熱源13全長之2/3以上4/5以下之範圍內。又,燃燒型熱源13插入杯具17之部分之長度(本體部分27在中心軸C方向之長度,插入長度)係適宜設定在2mm以上10mm以下之範圍內,更佳為2mm以上5mm以下之範圍內。 The combustion-type heat source 13 preferably has the following dimensions. The total length of the combustion-type heat source 13 (the length of the combustion-type heat source 13 in the direction of the central axis C) is suitably set in the range of 5 mm or more and 30 mm or less, and more preferably in the range of 10 mm or more and 20 mm or less. Among them, the length of the protruding portion 14 in the direction of the central axis C is suitably set within a range of 5 mm or more and 15 mm or less, and more preferably within a range of 5 mm or more and 10 mm or less. Therefore, the length of the protruding portion 14 is set within a range of 2/3 or more and 4/5 or less of the total length of the combustion-type heat source 13, for example. In addition, the length of the portion where the combustion-type heat source 13 is inserted into the cup 17 (the length of the body portion 27 in the direction of the central axis C, the insertion length) is suitably set within the range of 2 mm or more and 10 mm or less, more preferably 2 mm or more and 5 mm or less Inside.

燃燒型熱源13之直徑(與中心軸C正交的方向之燃燒型熱源13之長度)例如適宜設定在3mm以上15mm以下之範圍內。中心軸C方向之溝部33之深度(長度)例如適宜設定在1mm以上5mm以下之範圍內,更佳為2mm以上4mm以下之範圍內。溝部33之寬度(內徑)W例如適宜設定在0.5mm以上1mm以下之範圍內。 The diameter of the combustion-type heat source 13 (the length of the combustion-type heat source 13 in the direction orthogonal to the central axis C) is suitably set within a range of 3 mm or more and 15 mm or less, for example. The depth (length) of the groove 33 in the direction of the central axis C is suitably set within a range of 1 mm or more and 5 mm or less, and more preferably within a range of 2 mm or more and 4 mm or less. The width (inner diameter) W of the groove 33 is suitably set within a range of 0.5 mm or more and 1 mm or less, for example.

溝部33可由前端面28及外周面32之至少一者凹陷而設置。例如溝部33係可以由前端面28凹陷而 連通於通氣路31之方式設置,並以不於外周面32側開口之方式設置。同樣地,例如溝部33係可以由外周面32凹陷而連通於通氣路31之方式設置,並以不於前端面28側開口之方式設置。後者之情形時,通氣路31較佳為延伸至前端面28,並在前端面28往外部開口。 The groove 33 can be provided by recessing at least one of the front end surface 28 and the outer peripheral surface 32. For example, the groove 33 can be recessed by the front end surface 28 It is provided so as to communicate with the air passage 31 and is provided so as not to open on the outer peripheral surface 32 side. Similarly, for example, the groove portion 33 may be recessed from the outer peripheral surface 32 to communicate with the air passage 31, and may be provided so as not to open on the front end surface 28 side. In the latter case, the ventilation path 31 preferably extends to the front end surface 28 and opens to the outside at the front end surface 28.

又,燃燒型熱源13可不具有通氣路31。此時較佳為在固持器12(第1部分23)形成複數個通氣用小孔。使用者吸嚐時,空氣係透過該小孔而供給至固持器12內及位於固持器12內之香味源16。 In addition, the combustion-type heat source 13 may not have the ventilation path 31. In this case, it is preferable to form a plurality of small holes for ventilation in the holder 12 (first part 23). When the user tastes, the air is supplied into the holder 12 and the fragrance source 16 located in the holder 12 through the small hole.

作為一例,燃燒型熱源13亦可用以下方法製造。混合235.5g高活性碳(BET比表面積:2050m2/g)、323.8g碳酸鈣及28.1g羧甲基纖維素鈉後,加入含有5.4g的氯化鈉之水745.3g,進一步混合。混練該混合物後,以成為外徑6.5mm之圓柱形狀之方式進行擠出成型。乾燥藉由該擠出成型所得之成型物後,裁切為13mm之長度,而獲得一次成型體。以1.0mm直徑的鑽頭,於該一次成型體之中心部設置內徑1.0mm之貫通孔。於該一次成型體之一端面以鑽石刀盤實施十字溝加工。經過該等步驟而完成燃燒型熱源13。 As an example, the combustion-type heat source 13 can also be manufactured by the following method. After mixing 235.5 g of high activated carbon (BET specific surface area: 2050 m 2 /g), 323.8 g of calcium carbonate, and 28.1 g of sodium carboxymethyl cellulose, 745.3 g of water containing 5.4 g of sodium chloride was added and further mixed. After kneading the mixture, it was extruded to form a cylindrical shape with an outer diameter of 6.5 mm. After drying the molded product obtained by this extrusion molding, it was cut to a length of 13 mm to obtain a primary molded body. With a 1.0 mm diameter drill, a through hole with an inner diameter of 1.0 mm is provided in the center of the primary molded body. A diamond cutter is used to perform cross groove processing on one end surface of the primary molded body. After these steps, the combustion-type heat source 13 is completed.

藉此製造燃燒型熱源13,其係具有第2圖所示的形態,含有具有2050m2/gBET的比表面積之活性碳,並具有39.7重量%之活性碳濃度。 Thereby, a combustion-type heat source 13 was produced, which had the form shown in FIG. 2, contained activated carbon having a specific surface area of 2050 m 2 /gBET, and had an activated carbon concentration of 39.7% by weight.

本實施形態中,香料15係分別擔載於燃燒型熱源13之前端面28、第1倒角部34及溝部33之內周 面。在燃燒型熱源13之外周面32中擔載有第2香料41。在通氣路31(通氣路31之內周面)中擔載有第3香料51。又,香料15、第2香料41及第3香料51較佳為實質上不擔載於燃燒型熱源13之基端面29及第2倒角部35。但是,由前端面28及第1倒角部34揮散或擴散之香料15可能被吸附而保持於基端面29及第2倒角部35。如此情況時,前端面28及第1倒角部34所含的香料15之量亦大於基端面29及第2倒角部35所含的香料15之量。 In this embodiment, the fragrance 15 is carried on the inner periphery of the front end surface 28 of the combustion-type heat source 13, the first chamfered portion 34, and the groove 33, respectively surface. The second fragrance 41 is supported on the outer peripheral surface 32 of the combustion-type heat source 13. The third fragrance 51 is supported on the air passage 31 (inner peripheral surface of the air passage 31). Furthermore, the fragrance 15, the second fragrance 41, and the third fragrance 51 are preferably not substantially supported on the base end surface 29 and the second chamfered portion 35 of the combustion-type heat source 13. However, the fragrance 15 scattered or diffused by the front end surface 28 and the first chamfered portion 34 may be adsorbed and held by the base end surface 29 and the second chamfered portion 35. In this case, the amount of fragrance 15 contained in the front end surface 28 and the first chamfered portion 34 is also greater than the amount of fragrance 15 contained in the base end surface 29 and the second chamfered portion 35.

擔載於燃燒型熱源13之香料15之量可沿著中心軸C而改變。亦即,本實施形態中,在前端面28及第1倒角部34時香料15的擔載量最多。此時,香料15擔載的量在燃燒型熱源13內部可不為均一。香料15可以從前端面28朝向基端面29而逐漸減少香料15之量之方式擔載於燃燒型熱源13的內部。 The amount of the fragrance 15 carried on the combustion-type heat source 13 can be changed along the central axis C. That is, in the present embodiment, the load amount of the fragrance 15 is greatest when the front end surface 28 and the first chamfered portion 34 are used. At this time, the amount of fragrance 15 carried may not be uniform within the combustion-type heat source 13. The fragrance 15 can be carried inside the combustion-type heat source 13 so as to gradually reduce the amount of fragrance 15 from the front end surface 28 toward the base end surface 29.

第2香料41係擔載於複數個環狀擔載部42,該複數個環狀擔載部42係在中心軸C方向隔著既定間隔而形成於外周面32者。複數個擔載部42在中心軸C方向具有既定寬度並形成為帶狀。擔載部42之形狀並不限定於複數個環狀。擔載部42亦可形成為1個較寬帶狀(環狀)。又,擔載部42之形狀並不限於環狀,例如可設置複數個與中心軸C平行且直線延伸之帶狀擔載部42。此時,擔載部42較佳為與鄰接之其他擔載部42隔有固定間隔而配置。此時,複數個擔載部42係在中心軸C周圍隔有固定間隔而配置。 The second fragrance 41 is supported on a plurality of ring-shaped supporting portions 42 formed on the outer peripheral surface 32 at predetermined intervals in the direction of the central axis C. The plurality of load-bearing portions 42 have a predetermined width in the direction of the central axis C and are formed in a band shape. The shape of the supporting portion 42 is not limited to a plurality of rings. The load-bearing part 42 may be formed into a relatively wide shape (ring-shaped). In addition, the shape of the supporting portion 42 is not limited to a ring shape. For example, a plurality of belt-shaped supporting portions 42 that are parallel to the central axis C and extend linearly may be provided. At this time, the supporting portion 42 is preferably arranged at a fixed interval from other adjacent supporting portions 42. At this time, the plurality of load-bearing portions 42 are arranged at fixed intervals around the central axis C.

複數個擔載部42較佳為設置於較前端面28及溝部33更靠基端面29側(吸口端12A側)之處。又,複數個擔載部42較佳為設置於由前端面28離3mm以上之基端面29側(吸口端12A側)。更佳為複數個擔載部42設置於由前端面28離5mm以上之基端面29側(吸口端12A側)。藉由配置該等擔載部42,即使使用者在前端面28附近進行點火時,也可將香料15配置於不會因點火而暴露於火之位置。尤其在擔載部42擔載會因點火而失去香氣之香料15時,如此配置係有用的。又,擔載部42之形狀並不限定於複數個環狀。擔載部42亦可形成為1個較寬帶狀(環狀)。 The plurality of supporting portions 42 are preferably provided closer to the base end surface 29 side (the suction port end 12A side) than the front end surface 28 and the groove portion 33. Moreover, it is preferable that the plurality of supporting portions 42 are provided on the base end surface 29 side (at the suction port end 12A side) that is 3 mm or more from the front end surface 28. More preferably, a plurality of load portions 42 are provided on the side of the base end surface 29 (at the side of the suction port end 12A) separated from the front end surface 28 by 5 mm or more. By arranging these load-bearing parts 42, even when the user performs ignition near the front end surface 28, the fragrance 15 can be arranged at a position where it is not exposed to fire due to ignition. This arrangement is particularly useful when the loading portion 42 carries the fragrance 15 that loses its aroma due to ignition. In addition, the shape of the supporting portion 42 is not limited to a plurality of rings. The load-bearing part 42 may be formed into a relatively wide shape (ring-shaped).

擔載於燃燒型熱源13之第2香料41之量可沿著燃燒型熱源13之半徑方向而改變。亦即,本實施形態中,在外周面32時第2香料41的擔載量最多。此時,第2香料41之擔載量在燃燒型熱源13內部可不為均一。第2香料41可以從外周面32朝向中心軸C而逐漸減少香料15的量之方式擔載於燃燒型熱源13的內部。 The amount of the second fragrance 41 carried on the combustion-type heat source 13 can be changed along the radial direction of the combustion-type heat source 13. That is, in the present embodiment, the load amount of the second fragrance 41 is the largest on the outer peripheral surface 32. At this time, the loading amount of the second fragrance 41 may not be uniform within the combustion-type heat source 13. The second fragrance 41 can be carried inside the combustion-type heat source 13 so as to gradually decrease the amount of fragrance 15 from the outer peripheral surface 32 toward the central axis C.

本實施形態中,香料15、第2香料41及第3香料51互相相異。香料15係例如以茴香腦構成,但可為茴香腦以外之香料。亦即,香料15可含有選自由2-蒎烯、β-香茅醇、乙酸沈香酯、檸檬烯、大茴香醛、4-萜品醇、2-β-蒎烯、茉莉酮(jasmon)、檜烯、沈香醇、1,8-桉油醇(1,8-cineol)、苯乙醇、及肉豆蔻醚所組成群組之至少一種。香料15之茴香腦之蒸氣壓為0.07mmHg(25℃)。第2 香料41係例如以檸檬烯構成,但可為檸檬烯以外之香料。亦即,第2香料41可含有選自由茴香腦、2-蒎烯、β-香茅醇、乙酸沈香酯、大茴香醛、4-萜品醇、2-β-蒎烯、茉莉酮、檜烯、沈香醇、1,8-桉油醇、苯乙醇、及肉豆蔻醚所組成群組之至少一種。第2香料之41檸檬烯(d-檸檬烯)之蒸氣壓為1.44mmHg(25℃)。第3香料51係以沈香醇構成,但可為沈香醇以外之香料。亦即,第3香料51可含有選自由茴香腦、2-蒎烯、β-香茅醇、乙酸沈香酯、檸檬烯、大茴香醛、4-萜品醇、2-β-蒎烯、茉莉酮、檜烯、1,8-桉油醇、苯乙醇、及肉豆蔻醚所組成群組之至少一種。第3香料51之沈香醇之蒸氣壓為0.16mmHg(25℃)。此所稱「相異」的概念並非僅指化合物的種類相異。「相異」的概念中,當香料係混合複數種化合物而構成香料時,則亦包括:(1)作為香料構成要素之化合物種類(組合)相異之情形、及(2)作為香料構成要素之化合物種類(組合)相同但化合物摻配比率互相相異之情形。 In this embodiment, the fragrance 15, the second fragrance 41, and the third fragrance 51 are different from each other. The fragrance 15 is composed of, for example, anethole, but it may be a fragrance other than anethole. That is, the fragrance 15 may contain a member selected from the group consisting of 2-pinene, β-citronellol, agarwood acetate, limonene, anisaldehyde, 4-terpineol, 2-β-pinene, jasmon, juniper At least one of the group consisting of alkene, linalool, 1,8-cineol (1,8-cineol), phenethyl alcohol, and myristyl ether. The vapor pressure of the anethole of the fragrance 15 is 0.07 mmHg (25°C). 2nd The fragrance 41 is composed of limonene, for example, but may be a fragrance other than limonene. That is, the second fragrance 41 may contain a compound selected from the group consisting of anethole, 2-pinene, β-citronellol, agaryl acetate, anisaldehyde, 4-terpineol, 2-β-pinene, jasmonone, juniper At least one of the group consisting of ene, linalool, 1,8-cineol, phenethyl alcohol, and myristyl ether. The vapor pressure of 41 limonene (d-limonene), the second fragrance, was 1.44 mmHg (25°C). The third fragrance 51 is composed of linalool, but may be a fragrance other than linalool. That is, the third fragrance 51 may contain a compound selected from the group consisting of anethole, 2-pinene, β-citronellol, agarwood acetate, limonene, anisaldehyde, 4-terpineol, 2-β-pinene, and jasmonone. , Juniper, 1,8-cineole, phenethyl alcohol, and myristyl ether are at least one group. The vapor pressure of linalool in the third fragrance 51 is 0.16 mmHg (25°C). The concept of "dissimilarity" does not only refer to the different types of compounds. In the concept of "different", when a perfume system mixes a plurality of compounds to form a perfume, it also includes: (1) the type of compound (combination) as a component of the perfume is different, and (2) as a component of the perfume The compound types (combinations) are the same, but the compounding ratios of the compounds are different from each other.

香料15可與第2香料41或第3香料51相同。第2香料41可與第3香料51相同。香料15、第2香料41、及第3香料51可混合複數種香料而構成。本實施形態中,香料15、第2香料41及第3香料51係擔載於燃燒型熱源13,但可適宜選擇是否設置該等3種類之香料。作為本實施形態之變形例,可不設置香料15、第2香料41及第3香料51中任1者以上。 The fragrance 15 may be the same as the second fragrance 41 or the third fragrance 51. The second fragrance 41 may be the same as the third fragrance 51. The fragrance 15, the second fragrance 41, and the third fragrance 51 may be constituted by mixing plural kinds of fragrances. In the present embodiment, the fragrance 15, the second fragrance 41, and the third fragrance 51 are carried on the combustion-type heat source 13, but it is possible to appropriately select whether to install these three types of fragrances. As a modification of the present embodiment, any one or more of fragrance 15, second fragrance 41, and third fragrance 51 may not be provided.

於燃燒型熱源13之前端面28擔載香料15 之方法可採用各種方法。例如第3圖所示,可以與前端面28相對向之方式配置噴嘴,如第3圖箭頭所示,由該噴嘴起,將含有香料15的溶液的液滴由噴嘴向前端面28及第1倒角部34吐出(滴入),使含有香料15的溶液附著於前端面28及第1倒角部34。含有香料15的溶液可吐出於前端面28之整體,也可部分吐出於前端面28之一部分。例如較佳為為了不使香料15附著在對應通氣路31之部分(通氣路31及界定通氣路31之外緣的壁部),而將含有香料15的溶液的液滴吐出於偏離對應通氣路31之部分的位置。該液係由前端面28浸透至燃燒型熱源13內部,藉此使香料15被擔載於前端面28附近。或者可握住燃燒型熱源13之外周面32之基端面29側的位置,將燃燒型熱源13之前端面28、第1倒角部34及溝部33浸漬於含有香料15的溶液既定時間,藉此可在前端面28、第1倒角部34及溝部33擔載香料15。又,可將前端面28壓附於含有香料15之彈性多孔質體(例如海綿),藉此在前端面28及第1倒角部31附近擔載香料15。又,吐出含有香料15的溶液的液滴時可利用噴墨方式。 Carrying perfume 15 on end surface 28 before combustion-type heat source 13 Various methods can be used. For example, as shown in FIG. 3, the nozzle may be arranged to face the front end surface 28. As shown by the arrow in FIG. 3, from this nozzle, droplets of the solution containing the fragrance 15 will be directed from the nozzle to the front end surface 28 and the first The chamfered portion 34 is discharged (dropped), and the solution containing the fragrance 15 is attached to the front end surface 28 and the first chamfered portion 34. The solution containing the fragrance 15 may be spit out from the entire front end surface 28, or may be partly spit out from a part of the front end surface 28. For example, it is preferable to discharge the droplets of the solution containing the fragrance 15 out of the corresponding ventilation path so that the fragrance 15 does not adhere to the portion corresponding to the ventilation path 31 (the ventilation path 31 and the wall portion defining the outer edge of the ventilation path 31) 31 part of the location. This liquid system penetrates into the combustion-type heat source 13 from the front end surface 28, thereby allowing the fragrance 15 to be supported near the front end surface 28. Alternatively, you can hold the combustion heat source 13 at the position of the base end surface 29 side of the outer peripheral surface 32, and immerse the front end surface 28, the first chamfered portion 34, and the groove portion 33 of the combustion heat source 13 in the solution containing the fragrance 15 for a predetermined time, thereby The fragrance 15 can be carried on the front end surface 28, the first chamfered portion 34 and the groove portion 33. In addition, the front end surface 28 can be pressed against the elastic porous body (for example, sponge) containing the perfume 15, whereby the perfume 15 can be supported near the front end surface 28 and the first chamfered portion 31. In addition, an inkjet method can be used when discharging droplets of the solution containing the fragrance 15.

於燃燒型熱源13之外周面32擔載第2香料41之方法可採用各種方法。例如,準備將一部分已浸漬於含有第2香料41的溶液之複數個微小的輥互相串聯排列而成者。各輥的旋轉方向為與複數個輥串聯排列時的方向交差之方向。對於如上述構成之複數個輥,以從上側跨越之方式配置燃燒型熱源13,並在該等複數個輥上旋轉燃燒型 熱源13。藉此以於外周面32形成複數個帶狀(環狀)擔載部42之方式,可轉印(塗布)第2香料41。或者,藉由對於進行旋轉之燃燒型熱源13而從接近外周面32之噴嘴連續地塗布較高黏度之含有第2香料41的溶液,亦可使第2香料41擔載於外周面32。又,將第2香料41塗布於外周面32而在外周面32擔載第2香料41之方法,係可採用噴墨方式等各種方法。 Various methods can be used for the method of supporting the second fragrance 41 on the outer peripheral surface 32 of the combustion-type heat source 13. For example, one prepared by arranging a plurality of tiny rollers partially immersed in the solution containing the second fragrance 41 in series with each other. The rotation direction of each roller is the direction that intersects the direction when a plurality of rollers are arranged in series. For the plurality of rollers configured as described above, the combustion-type heat source 13 is arranged so as to span from the upper side, and the combustion-type heat source is rotated on the plurality of rollers Heat source 13. Thereby, the second fragrance 41 can be transferred (applied) by forming a plurality of belt-shaped (ring-shaped) supporting portions 42 on the outer peripheral surface 32. Alternatively, the second fragrance 41 may be supported on the outer peripheral surface 32 by continuously applying the solution containing the second fragrance 41 with a higher viscosity from the nozzle close to the outer peripheral surface 32 to the rotating combustion-type heat source 13. In addition, the method of applying the second fragrance 41 to the outer peripheral surface 32 and supporting the second fragrance 41 on the outer peripheral surface 32 may be various methods such as an inkjet method.

第3香料51係例如用以下方法擔載於通氣路31。亦即,以與通氣路31相對向之方式配置噴嘴,如第3圖之虛線箭頭所示般,由該噴嘴吐出(滴入)含有第3香料51的溶液之液滴。藉此在通氣路31之內周面附著含有第3香料51的溶液,並使該液浸透於燃燒型熱源13內部,藉此使第3香料51擔載於通氣路31之內周面附近。含有第3香料51的溶液之吐出可與吐出含有香料15的溶液同時進行,也可與吐出含有香料15的溶液錯開時間進行。 The third fragrance 51 is carried on the air passage 31 by, for example, the following method. That is, the nozzle is arranged so as to face the air passage 31, and as shown by the dotted arrow in FIG. 3, droplets of the solution containing the third fragrance 51 are discharged (dropped) from the nozzle. As a result, a solution containing the third fragrance 51 is adhered to the inner peripheral surface of the air passage 31, and the liquid is penetrated into the combustion-type heat source 13, whereby the third fragrance 51 is supported near the inner peripheral surface of the air passage 31. The solution containing the third fragrance 51 can be discharged at the same time as the solution containing the fragrance 15 or at a time different from the solution containing the fragrance 15.

又,如上所述,關於含有香料15、第2香料41及第3香料51的溶液之液滴吐出(塗布),主要說明使每個香料分別附著,但可利用噴墨方式一次性地進行該等香料之塗布。 In addition, as described above, regarding the liquid droplet discharge (coating) of the solution containing the fragrance 15, the second fragrance 41, and the third fragrance 51, it is mainly explained that each fragrance is separately attached, but this can be performed at once by the inkjet method. Coating of other spices.

說明本實施形態之香味吸嚐器11之作用。在燃燒型熱源13點火時及點火後,使用者可藉由點火源或來自燃燒型熱源13之熱,而感受到前端面28所散發之香氣(外香)。 The function of the flavor taster 11 of this embodiment will be described. When the combustion-type heat source 13 is ignited and after ignition, the user can feel the aroma (external fragrance) emitted by the front end surface 28 by the ignition source or the heat from the combustion-type heat source 13.

使用者在燃燒型熱源13之前端面28附近點進行火,若使用者開始吸嚐,則燃燒型熱源13會發熱至既定溫度(例如250℃至900℃),藉由來自燃燒型熱源13之熱加溫香味源16。藉此散發香味源16所含的成分,並透過過濾器部21到達使用者的嘴。藉此,使用者可品嚐香味源16之香味。此時,擔載於前端面28之香料係與周邊的空氣一起透過通氣路31而導入至固持器12內部,並在杯具17內與香味源16釋出之成分混合,經由過濾器部21到達使用者的嘴。因此,使用者可透過主流煙所含的內香之形式感受擔載於前端面28之香料15。更進一步,使用者視需要亦可用手指擠壓膠囊22,藉此改變主流煙之香吸味。又,在此所述內香係透過經過嘴(口腔)後傳遞至鼻(鼻腔)之香料成分所感受到的香氣。又,外香係透過不經由嘴(口腔)而傳遞至鼻(鼻腔)之香料成分所感受到的香氣。 The user ignites a fire near the end surface 28 before the combustion-type heat source 13, and if the user starts to taste, the combustion-type heat source 13 will heat up to a predetermined temperature (eg, 250°C to 900°C) by the heat from the combustion-type heat source 13 Heating the fragrance source 16. Thereby, the components contained in the fragrance source 16 are emitted, and pass through the filter portion 21 to reach the user's mouth. Thereby, the user can taste the fragrance of the fragrance source 16. At this time, the fragrance carried on the front end surface 28 is introduced into the holder 12 through the air passage 31 together with the surrounding air, and is mixed with the components released from the fragrance source 16 in the cup 17 and passes through the filter section 21 Reach the user's mouth. Therefore, the user can feel the fragrance 15 carried on the front end surface 28 in the form of the inner fragrance contained in the mainstream smoke. Furthermore, the user can squeeze the capsule 22 with his fingers as needed, thereby changing the smell of mainstream smoke. In addition, the inner fragrance mentioned here is the fragrance felt by the fragrance component that passes through the mouth (oral cavity) and passes to the nose (nasal cavity). In addition, the outer fragrance is the fragrance that is felt through the fragrance component that is transmitted to the nose (nasal cavity) without passing through the mouth (oral cavity).

使用者進行既定時間吸嚐,當燃燒型熱源13燃燒盡或香味源16的香吸味消失時,便結束吸嚐。此時,燃燒型熱源13之灰不會掉落至地面,而保持於固持器12之前端,故對周邊環境的負擔較小。又,與以往的紙捲菸(香菸)相比,由香味吸嚐器11產生的煙顯著減少,故對周邊環境的負擔較小。 The user performs tasting for a predetermined period of time, and the tasting ends when the burning heat source 13 is burnt out or the flavor of the flavor source 16 disappears. At this time, the ash of the combustion-type heat source 13 does not fall to the ground, but remains at the front end of the holder 12, so the burden on the surrounding environment is small. In addition, compared with the conventional paper cigarette (cigarette), the smoke generated by the flavor taster 11 is significantly reduced, so the burden on the surrounding environment is small.

(實施例) (Example) [實施例1] [Example 1] [藏置試驗結果] [Results of hiding test] (燃燒型熱源之製造) (Manufacture of combustion type heat source)

根據與上述實施形態所記載的方法相同之方法而製造燃燒型熱源13。藉此製造燃燒型熱源13,其係具有第2圖所示的形態,含有具有2050m2/gBET的比表面積之活性碳,並具有39.7重量%之活性碳濃度。 The combustion-type heat source 13 is manufactured according to the same method as described in the above embodiment. Thereby, a combustion-type heat source 13 was produced, which had the form shown in FIG. 2, contained activated carbon having a specific surface area of 2050 m 2 /gBET, and had an activated carbon concentration of 39.7% by weight.

(試驗結果) (test results)

接著參照第4圖說明在以本實施形態之高活性碳所構成之燃燒型熱源13擔載各種香料並進行藏置試驗後之結果。在用於藏置試驗之燃燒型熱源13中,係對本實施形態之高活性碳之燃燒型熱源13之前端面28、第1倒角部34及溝部33之內周面吐出(滴入)含有香料的溶液,並在前端面28、第1倒角部34及溝部33之內周面擔載香料。在溫度40℃之開放系統放置已擔載香料之燃燒型熱源13,在4週後分析殘存香料之殘存率。具體而言,將燃燒型熱源13置入添加有內部標準液之乙醇,將燃燒型熱源13振盪20小時,進行過濾而藉此獲得樣品液。以GC/MS分析該樣品液。藉此獲得燃燒型熱源13所殘存的香料之定量值。根據燃燒型熱源13所殘存之香料的量及擔載於燃燒型熱源13之香料的量而求出殘存率(重量%)。香料殘存率之結果表示於第4圖的表中。第4圖所示之表的香料中,顯示大致70%至100%之殘存率,第4圖所示的表中之香料中,較佳的香料係顯示80%以上之殘存率。 Next, referring to FIG. 4, the results of carrying out various storage tests on the combustion-type heat source 13 composed of the highly activated carbon of this embodiment and carrying out storage tests will be described. In the combustion-type heat source 13 used in the storage test, the front end surface 28, the first chamfered portion 34, and the inner circumferential surface of the groove portion 33 of the highly activated carbon-fired heat source 13 of the present embodiment are spouted (dropped) containing fragrance And the fragrance is carried on the inner peripheral surface of the front end surface 28, the first chamfered portion 34 and the groove portion 33. The combustion-type heat source 13 loaded with fragrance was placed in an open system at a temperature of 40°C, and the residual rate of remaining fragrance was analyzed after 4 weeks. Specifically, the combustion-type heat source 13 is placed in ethanol to which an internal standard liquid is added, the combustion-type heat source 13 is shaken for 20 hours, and filtered to obtain a sample liquid. The sample liquid was analyzed by GC/MS. Thereby, the quantitative value of the fragrance remaining in the combustion-type heat source 13 is obtained. The residual rate (weight %) was determined from the amount of fragrance remaining in the combustion heat source 13 and the amount of fragrance supported on the combustion heat source 13. The results of the remaining percentage of fragrances are shown in the table in Figure 4. The fragrance in the table shown in FIG. 4 shows a residual rate of approximately 70% to 100%. Among the fragrances in the table shown in FIG. 4, the preferred fragrance shows a residual rate of 80% or more.

另一方面,以不使用高活性碳而使用通常 的碳並於其擔載香料而成之燃燒型熱源作為比較例。比較例之藏置試驗結果中,存在有殘存率大幅降低之香料成分。其原因認為是賦活度低的碳中,大孔隙及微孔隙的數量不充分,可吸附香料的位置較少。因此,比較例中,香料會隨著時間經過而揮散,使香料殘存率大幅降低。因此認為,使用高活性碳作為燃燒型熱源,對於提高香料之藏置安定性為有效的。 On the other hand, use high-activation carbon instead of As a comparative example. In the storage test results of the comparative example, there is a fragrance component whose residual rate is greatly reduced. The reason for this is considered to be that in the low-activity carbon, the number of macropores and micropores is insufficient, and there are few places where perfume can be adsorbed. Therefore, in the comparative example, the fragrance is scattered with the passage of time, and the residual rate of fragrance is greatly reduced. Therefore, it is considered that the use of highly activated carbon as a combustion-type heat source is effective for improving the stability of the storage of spices.

上述實施形態中係以茴香腦作為香料15、檸檬烯作為第2香料41、沈香醇作為第3香料51。但香料15可以茴香腦以外之第4圖的表中之其他香料構成。又,第2香料41亦可以檸檬烯以外之第4圖的表中之其他香料構成。第3香料51亦可以沈香醇以外之第4圖的表中之其他香料構成。 In the above embodiment, anethole is used as the flavor 15, limonene is used as the second flavor 41, and linalool is used as the third flavor 51. However, the flavor 15 may be composed of other flavors in the table of FIG. 4 other than anethole. In addition, the second fragrance 41 may be composed of other fragrances in the table of FIG. 4 other than limonene. The third fragrance 51 may be composed of other fragrances in the table of FIG. 4 other than linalool.

[實施例2] [Example 2] [往主流煙之轉移率之測定結果] [Measurement results of transfer rate to mainstream smoke] (燃燒型熱源之製造) (Manufacture of combustion type heat source)

根據與上述實施形態所記載的方法相同之方法而製造燃燒型熱源13。藉此製造燃燒型熱源13,其係具有第2圖所示的形態,含有具有2050m2/gBET的比表面積之活性碳,並具有39.7重量%之活性碳濃度。 The combustion-type heat source 13 is manufactured according to the same method as described in the above embodiment. Thereby, a combustion-type heat source 13 was produced, which had the form shown in FIG. 2, contained activated carbon having a specific surface area of 2050 m 2 /gBET, and had an activated carbon concentration of 39.7% by weight.

(測定結果) (The measurement results)

使用第5圖所示的測定裝置61,測定擔載於本實施形 態之高活性碳之燃燒型熱源13之香料(茴香腦)往主流煙之轉移率。使用測定裝置61,測定裝置61係具有:保持香味吸嚐器11之吸口端12A之固持器部62(香菸固持器)、設置於固持器部62的下游側之劍橋式過濾器(cambridge filter)63、設置於劍橋式過濾器63的下游側之空氣採集器65、連接自動吸煙器64與空氣採集器65之管66、及設置於空氣採集器65的下游之自動吸煙器64。於空氣採集器65內部係保持添加有內部標準液之甲醇。 Using the measuring device 61 shown in FIG. 5, the measurement is carried in this embodiment. The transfer rate of the spice (anethole) of the combustion type heat source 13 with high activated carbon to mainstream smoke. Using the measuring device 61, the measuring device 61 includes a holder portion 62 (cigarette holder) that holds the mouth end 12A of the flavor taster 11, and a cambridge filter provided on the downstream side of the holder portion 62 63. An air collector 65 provided downstream of the Cambridge filter 63, a tube 66 connecting the automatic smoker 64 and the air collector 65, and an automatic smoker 64 provided downstream of the air collector 65. Inside the air collector 65, methanol containing the internal standard solution is kept.

香料往主流煙之轉移率係以以下順序測定。 The transfer rate of flavors to mainstream smoke is measured in the following order.

以下述條件使用自動吸煙器64來吸煙香味吸嚐器11。 The automatic smoker 64 is used to smoke the flavor inhaler 11 under the following conditions.

Figure 106121982-A0202-12-0019-1
Figure 106121982-A0202-12-0019-1

如上述表所示方式設定自動吸煙器64之吸煙條件。例如以時間為橫軸、壓力降低為縱軸時,在1次抽吸之吸嚐中,香味吸嚐器11之固持器12內之壓力降低曲線係成為所謂的鐘型(在吸嚐時間內中間時點為壓力降低最大)。如上述表所示,吸煙開始的時間間隔為30秒。吸煙時間(Duration)為2秒。因此,該吸煙條件中係以吸煙時間2秒→非吸煙時間28秒→吸煙時間2秒→非吸煙時間28秒之方式交替重複吸煙時間及非吸煙時間。又,1次吸煙所吸入的煙之體積為55ml。抽吸次數設為15次(確認到 燃燒型熱源之紅熱為12次+3次)。 The smoking conditions of the automatic smoking device 64 are set as shown in the above table. For example, when the time is the horizontal axis and the pressure decrease is the vertical axis, the pressure decrease curve in the holder 12 of the flavor taster 11 becomes a so-called bell shape (within the taste time) (The middle point is the maximum pressure drop). As shown in the table above, the time interval between the start of smoking is 30 seconds. The smoking time (Duration) is 2 seconds. Therefore, in this smoking condition, smoking time and non-smoking time are alternately repeated in a manner of smoking time 2 seconds → non-smoking time 28 seconds → smoking time 2 seconds → non-smoking time 28 seconds. In addition, the volume of smoke inhaled in one smoking was 55 ml. The number of suctions is set to 15 times (confirmed The red heat of the burning heat source is 12 times + 3 times).

以如此吸煙條件進行吸煙並使用劍橋式過濾器63来捕集煙。將該劍橋式過濾器63置入添加有內部標準液之甲醇,粉碎劍橋式過濾器63並振盪,經過過濾而獲得樣品液。以GC/MS分析該樣品液。藉此獲得由劍橋式過濾器63所捕集的香料之定量值。 Smoking is carried out in such smoking conditions and the Cambridge filter 63 is used to capture the smoke. The Cambridge filter 63 was placed in methanol to which an internal standard solution was added, the Cambridge filter 63 was pulverized and shaken, and the sample liquid was obtained by filtration. The sample liquid was analyzed by GC/MS. Thereby, the quantitative value of the fragrance captured by the Cambridge filter 63 is obtained.

同樣地,針對通過劍橋式過濾器63之煙,亦用置入添加有內部標準液之甲醇的空氣採集器65進行捕集。以GC/MS分析由空氣採集器65所得之樣品液。藉此獲得由空氣採集器65所捕集的香料之定量值。 Similarly, for the smoke passing through the Cambridge filter 63, the air collector 65 with methanol added with the internal standard liquid is also used for trapping. The sample liquid obtained by the air collector 65 was analyzed by GC/MS. Thereby, the quantitative value of the fragrance collected by the air collector 65 is obtained.

又,附著於管66的內壁之煙亦以以下要領回收。首先,將管66弄碎後,置入於添加有內部標準液之甲醇。將其振盪並過濾,而獲得樣品液。以GC/MS分析該樣品液。藉此獲得附著於管66的內壁之香料之定量值。GC/MS係用下表2所示的條件進行。 In addition, the smoke attached to the inner wall of the tube 66 is also recovered in the following manner. First, after crushing the tube 66, it is placed in methanol to which an internal standard solution is added. This was shaken and filtered to obtain a sample liquid. The sample liquid was analyzed by GC/MS. Thereby, the quantitative value of the fragrance adhering to the inner wall of the tube 66 is obtained. GC/MS was performed under the conditions shown in Table 2 below.

Figure 106121982-A0202-12-0020-2
Figure 106121982-A0202-12-0020-2

以劍橋式過濾器63所捕集的香料之定量值、空氣採集器65所捕的集香料之定量值、及附著於管66的內壁之香料之定量值之和,作為轉移至主流煙之香料的重量。香料對於主流煙之轉移率可用以下數學式計算。 The sum of the quantitative value of the fragrance collected by the Cambridge filter 63, the quantitative value of the collected fragrance collected by the air collector 65, and the quantitative value of the fragrance attached to the inner wall of the tube 66 is regarded as the transfer to mainstream smoke The weight of spices. The transfer rate of spices to mainstream smoke can be calculated using the following mathematical formula.

(轉移率)(%)={(劍橋式過濾器63所捕集的香料之定量值)+(空氣採集器65所捕集的香料之定量值)+(附著於管66的內壁之香料之定量值)}/(燃燒型熱源13中香料的總重量)…式(1) (Transfer rate) (%) = ((quantity value of fragrance captured by Cambridge filter 63) + (quantity value of fragrance captured by air collector 65) + (perfume attached to the inner wall of tube 66 Quantitative value)}/(total weight of spices in combustion-type heat source 13)... Equation (1)

作為一例,表示使用茴香腦作為香料時以如此方法計算轉移率之結果。 As an example, the result of calculating the transfer rate in this way when using anethole as a spice.

擔載於燃燒型熱源13之香料的總重量為3075μg(對應式(1)之分母)。另一方面,轉移至主流煙之香料的總重量為42.77μg(對應式(1)之分子)。因此,使用茴香腦作為香料時,茴香腦往主流煙之轉移率以式(1)求為1.39%。 The total weight of the fragrance loaded on the combustion-type heat source 13 is 3075 μg (corresponding to the denominator of formula (1)). On the other hand, the total weight of flavor transferred to mainstream smoke is 42.77 μg (corresponding to the molecule of formula (1)). Therefore, when anethole is used as a spice, the transfer rate of anethole to mainstream smoke is 1.39% using equation (1).

由上述本實施形態、藏置試驗結果及往主流煙之轉移率之測定結果可得以下結論。亦即,香味吸嚐器11係具備:由吸口端12A延伸至前端12B之筒狀固持器12;保持於固持器12內之香味源16;燃燒型熱源13,係設置於前端12B,含有活性碳且擔載有香料,前述活性碳之BET比表面積為1300m2/g以上2500m2/g以下。 The following conclusions can be drawn from the above-mentioned embodiments, the results of storage tests and the measurement results of the transfer rate to mainstream smoke. That is, the flavor taster 11 is provided with: a cylindrical holder 12 extending from the suction port end 12A to the front end 12B; a fragrance source 16 held in the holder 12; a combustion-type heat source 13, which is provided at the front end 12B and contains active Carbon and perfume are supported, and the BET specific surface area of the activated carbon is 1300 m 2 /g or more and 2500 m 2 /g or less.

根據該構成,燃燒型熱源13係可使用含有所謂的高活性碳者。藉此,藉由高活性碳之大量含有大孔隙及微孔隙之多孔質構造,而在燃燒型熱源13中吸附香 料,可大量確保可長期間安定地保持香料之位置。藉此可實現在藏置後香料殘存率亦高之附香料之燃燒型熱源13,及具備該燃燒型熱源13之香味吸嚐器11。因此可提供合乎使用者的嗜好之具吸引力的製品。又,根據上述構成而可藉由高活性碳之多孔質構造來提高點火性,可實現容易點火之香味吸嚐器11。又,藉由高活性碳之多孔質構造可提高燃燒型熱源13之燃燒性,可在燃燒型熱源13持續安定燃燒。又,根據上述構成,活性碳之BET比表面積為2500m2/g以下,故可實現具有充分強度之燃燒型熱源13。藉此可防止燃燒型熱源13變得脆弱。 According to this configuration, those containing the so-called high-activated carbon can be used for the combustion-type heat source 13 system. In this way, by adopting a porous structure containing a large amount of macropores and micropores in a large amount of high-activated carbon, the fragrance is adsorbed in the combustion-type heat source 13 to ensure that the fragrance can be stably maintained for a long period of time. Thereby, a combustion-type heat source 13 with fragrance and a fragrance taster 11 provided with the combustion-type heat source 13 having a high fragrance residual rate after storage can be realized. Therefore, it is possible to provide attractive products suitable for users' preferences. In addition, according to the above configuration, the ignitability can be improved by the porous structure of highly activated carbon, and the flavor taster 11 that can be easily ignited can be realized. In addition, the porous structure of highly activated carbon can improve the combustion of the combustion-type heat source 13, and the combustion can continue to be stabilized in the combustion-type heat source 13. In addition, according to the above configuration, the BET specific surface area of the activated carbon is 2500 m 2 /g or less, so that the combustion-type heat source 13 having sufficient strength can be realized. This prevents the combustion-type heat source 13 from becoming weak.

此時,前述活性碳之BET比表面積為2000m2/g以上2500m2/g以下。根據該構成,即使在所謂的高活性碳中,亦可使用賦活度較高者,可進一步長期間安定地保持香料。藉此可實現一種即使在藏置後香料殘存率亦較高之香味吸嚐器11,該香味吸嚐器11係具備附香料之燃燒型熱源13。又,可進一步提高燃燒型熱源13之點火性及燃燒性。 At this time, the BET specific surface area of the activated carbon is 2000 m 2 /g or more and 2500 m 2 /g or less. According to this configuration, even in so-called high-activated carbon, those with a high activation degree can be used, and the fragrance can be stably maintained for a longer period of time. Thereby, a fragrance taster 11 having a high fragrance remaining rate even after storage can be realized. The fragrance taster 11 is provided with a combustion-type heat source 13 with fragrance. In addition, the ignitability and combustibility of the combustion-type heat source 13 can be further improved.

前述活性碳之BET比表面積為2050m2/g以上2300m2/g以下。一般若高活性碳之賦活度變高(BET比表面積變大),則有製造成本增加之傾向。根據該構成可實現一種具備燃燒型熱源13之香味吸嚐器11,該燃燒型熱源13在所謂的高活性碳中亦賦活度較高,可長期間安定地保持香料且製造成本不會過高。 The aforementioned BET specific surface area of activated carbon was 2050m 2 / g or more 2300m 2 / g or less. Generally, if the activation degree of high activated carbon becomes higher (the BET specific surface area becomes larger), the manufacturing cost tends to increase. According to this configuration, a flavor taster 11 with a combustion-type heat source 13 can be realized. The combustion-type heat source 13 is also highly active in the so-called high-activated carbon, can stably maintain fragrance for a long period of time, and the manufacturing cost is not too high .

燃燒型熱源13所含之前述活性碳之濃度為 30重量%以上60重量%以下。燃燒型熱源13所含有的碳量中係存在必要充分的量。亦即,燃燒型熱源13所含有之碳量過多時,有所產生的熱量過大之問題,在燃燒型熱源13所含有的碳量過少時,有無法獲得充分的熱量之問題。如上述構成,燃燒型熱源13所含的活性碳之濃度為30重量%以上時,可對香味源16供給充分的熱量。藉此可以適當溫度加溫香味源16,並從香味源16有效率地取出成分並到達使用者的口腔內。又,燃燒型熱源13所含的活性碳之濃度為60重量%以下時,可降低伴隨燃燒之灰飛散,並可降低主流煙中所含之一氧化碳的量。 The concentration of the aforementioned activated carbon contained in the combustion-type heat source 13 is 30% by weight or more and 60% by weight or less. The amount of carbon contained in the combustion-type heat source 13 is necessary and sufficient. That is, when the amount of carbon contained in the combustion-type heat source 13 is too large, there is a problem that the amount of heat generated is too large. When the amount of carbon contained in the combustion-type heat source 13 is too small, there is a problem that sufficient heat cannot be obtained. As described above, when the concentration of the activated carbon contained in the combustion-type heat source 13 is 30% by weight or more, sufficient heat can be supplied to the flavor source 16. Thereby, the fragrance source 16 can be heated at an appropriate temperature, and the ingredients can be efficiently taken out from the fragrance source 16 and reach the user's mouth. In addition, when the concentration of the activated carbon contained in the combustion-type heat source 13 is 60% by weight or less, ash scattering accompanying combustion can be reduced, and the amount of carbon monoxide contained in mainstream smoke can be reduced.

燃燒型熱源13所含之前述活性碳之濃度為30重量%以上45重量%以下。根據該構成,可進一步實現具有適當碳含量(活性碳含量)之燃燒型熱源13。藉此可進一步確實防止產生香味源16之溫度過於提高、或施加於香味源16之熱量不足的情況。又,根據上述構成,可實現降低灰飛散量及降低主流煙中所含之一氧化碳量。 The concentration of the aforementioned activated carbon contained in the combustion-type heat source 13 is 30% by weight or more and 45% by weight or less. According to this configuration, the combustion-type heat source 13 having an appropriate carbon content (active carbon content) can be further realized. Thereby, it is possible to further surely prevent the temperature of the fragrance source 16 from being excessively increased or the amount of heat applied to the fragrance source 16 from being insufficient. In addition, according to the above configuration, it is possible to reduce the amount of ash scattering and the amount of carbon monoxide contained in mainstream smoke.

燃燒型熱源13係具有由固持器12之前端12B突出之突出部14,前述香料係擔載於突出部14。根據該構成,不僅使擔載於突出部14之香料導入至主流煙,發揮內香的作用,並且以未導入至主流煙的狀態直接到達使用者的鼻子,發揮外香的作用。尤其,以嘴銜住香味吸嚐器11時,燃燒型熱源13之突出部14係配置於接近使用者的鼻子之位置,故即使為少量之香料15,香氣(外香)亦可有效率地到達使用者鼻子。藉由該等可實現合乎使用者的 嗜好之香味吸嚐器11。 The combustion-type heat source 13 has a protruding portion 14 protruding from the front end 12B of the holder 12, and the aforementioned fragrance system is carried on the protruding portion 14. According to this configuration, not only can the fragrance loaded on the protruding portion 14 be introduced into the mainstream smoke to exert the effect of internal fragrance, but also directly reach the user's nose without being introduced into the mainstream smoke to exert the effect of external fragrance. In particular, when the taste inhaler 11 is held by the mouth, the protruding portion 14 of the combustion-type heat source 13 is disposed close to the user's nose, so even if a small amount of the fragrance 15 is used, the aroma (outer fragrance) can be efficiently Reach the user's nose. With these, user-friendly 味的味吸味器11。 Scent of taste hobby 11.

突出部14係具有前端面28,香料15係擔載於前端面28。根據該構成,可將香料15擔載於被使用者握持的可能性較低之前端面28,即使使用者在吸嚐香味吸嚐器11前握持燃燒型熱源13之外周面32時,亦可防止香調15轉移至使用者的手指等不良情形。 The protruding portion 14 has a front end surface 28, and the fragrance 15 is supported on the front end surface 28. According to this configuration, the fragrance 15 can be carried on the front end surface 28 that is less likely to be held by the user, even when the user holds the outer peripheral surface 32 of the combustion-type heat source 13 before savouring the flavor inhaler 11 It can prevent bad situations such as the fragrance 15 being transferred to the user's finger.

具備過濾器部21,其係設置於固持器12內之吸口端12A側並具有香料膠囊。根據該構成可藉由弄碎香料膠囊而改變主流煙之香吸味。藉此可提供合乎使用者的嗜好之更具吸引力之製品。又,可以將被擔載於燃燒型熱源13時會因熱而分解或揮發之香料保持於香料膠囊內。藉此,根據香料之特性而可擔載於燃燒型熱源13或擔載於香料膠囊內,可進一步提高製品在設計香料時之自由度(增加香料之選擇)。 A filter portion 21 is provided, which is provided on the side of the mouth end 12A in the holder 12 and has a fragrance capsule. According to this configuration, the aroma and flavor of mainstream smoke can be changed by breaking up the spice capsules. This can provide a more attractive product that suits the user's preferences. In addition, the fragrance that is decomposed or volatilized by heat when supported on the combustion-type heat source 13 can be held in the fragrance capsule. Thereby, according to the characteristics of the fragrance, it can be carried in the combustion-type heat source 13 or in the fragrance capsule, which can further improve the freedom of the product when designing the fragrance (increasing the choice of fragrance).

前述香料膠囊內封入有薄荷醇、醛系香料及單萜烯香料中之至少一種。發明人等係於燃燒型熱源13擔載薄荷醇,並進行確認香味之試驗,結果確認會產生如金屬之不佳香味。又,亦確認醛系香料及單萜烯香料會因與外氣接觸而氧化變質。根據上述構成,可在不損及被廣泛使用在紙捲菸(香菸)之薄荷醇、醛系香料及單萜烯香料之風味的情況下,進一步與擔載於燃燒型熱源13之其他香料相互作用,而實現具有理想香吸味之香味吸嚐器11。又,於香料膠囊內封入薄荷醇時,薄荷醇係密閉於香料膠囊內,故藏置時薄荷醇不會揮散而轉移至燃燒型熱源13。 又,有關擔載於燃燒型熱源13時會產生不佳香味之香料等,可以使其擔載於香料膠囊內等因應香料特性來適宜設計製品。藉此可進一步提高製品在設計香料時之自由度(增加香料之選擇)。 At least one of menthol, aldehyde-based fragrance and monoterpene fragrance is enclosed in the aforementioned fragrance capsule. The inventors carried out a test for confirming the fragrance by carrying menthol on the combustion-type heat source 13, and as a result, it was confirmed that an unfavorable fragrance such as metal was generated. In addition, it was also confirmed that aldehyde-based fragrances and monoterpene fragrances will oxidatively deteriorate due to contact with outside air. According to the above configuration, it is possible to further interact with other flavors carried on the combustion-type heat source 13 without compromising the flavors of menthol, aldehyde flavors, and monoterpene flavors widely used in paper cigarettes (cigarettes). , And realize a flavor taster 11 with an ideal aroma. In addition, when menthol is enclosed in the fragrance capsule, the menthol is sealed in the fragrance capsule, so the menthol is transferred to the combustion-type heat source 13 without being scattered during storage. In addition, for fragrances, etc., which produce unfavorable fragrance when loaded on the combustion-type heat source 13, they can be carried in fragrance capsules, etc., and products can be appropriately designed according to the characteristics of the fragrance. This can further increase the freedom of the product when designing the fragrance (increasing the choice of fragrance).

香味吸嚐器11並不限定於上述實施形態,在實施階段中,在不超出其主旨的範圍內可改變構成要素並具體化。例如,固持器12之形狀並不限於圓筒形,例如可為四角筒狀、剖面惰圓形之筒狀、或具有其他具有多邊形剖面(六角形、八角形等)之筒狀,自不需贅言。 The flavor taster 11 is not limited to the above-mentioned embodiment, and in the implementation stage, the constituent elements can be changed and embodied within the scope not exceeding the gist thereof. For example, the shape of the holder 12 is not limited to a cylindrical shape. For example, it can be a rectangular tube, a cylindrical tube with an inert circular cross-section, or another cylindrical tube with a polygonal cross-section (hexagonal, octagonal, etc.). Repeat.

以下彙整出較佳的實施形態。 The following summarizes the preferred embodiments.

[1]一種香味吸嚐器,係具備:由吸口端延伸至前端之筒狀固持器;保持於前述固持器內之香味源;及燃燒型熱源,係設置於前述前端,含有活性碳且擔載有香料,前述活性碳之BET比表面積為1300m2/g以上2500m2/g以下。 [1] A fragrance taster, comprising: a cylindrical holder extending from the suction end to the front end; a fragrance source held in the holder; and a combustion-type heat source provided at the front end, containing activated carbon and supporting Perfume is loaded, and the BET specific surface area of the activated carbon is 1300 m 2 /g or more and 2500 m 2 /g or less.

[2]如[1]所記載之香味吸嚐器,其中前述活性碳之BET比表面積為2000m2/g以上2500m2/g以下。 [2] The flavor taster according to [1], wherein the BET specific surface area of the activated carbon is 2000 m 2 /g or more and 2500 m 2 /g or less.

[3]如[2]所記載之香味吸嚐器,其中前述活性碳之BET比表面積為2050m2/g以上2300m2/g以下。 [3] [2] described in the suction taste flavor, wherein the activated carbon the BET specific surface area of 2050m 2 / g or more 2300m 2 / g or less.

[4]如[1]至[3]中任1項所記載之香味吸嚐器,其中前述燃燒型熱源所含的前述活性碳之濃度為30重量%以上60重量%以下。 [4] The flavor inhaler according to any one of [1] to [3], wherein the concentration of the activated carbon contained in the combustion-type heat source is 30% by weight or more and 60% by weight or less.

[5]如[4]所記載之香味吸嚐器,其中前述燃燒型熱源所含的前述活性碳之濃度為30重量%以上45重量%以下。 [5] The flavor taster according to [4], wherein the concentration of the activated carbon contained in the combustion-type heat source is 30% by weight or more and 45% by weight or less.

[6]如[1]至[5]中任1項所記載之香味吸嚐器,其中前 述燃燒型熱源係具有由前述固持器之前述前端突出之突出部,前述香料係擔載於前述突出部。 [6] The aroma inhaler as described in any one of [1] to [5], where the front The combustion-type heat source has a protruding portion protruding from the front end of the holder, and the fragrance is carried on the protruding portion.

[7]如[6]所記載之香味吸嚐器,其中前述突出部係具有前端面,前述香料係擔載於前述前端面。 [7] The flavor taster according to [6], wherein the protruding portion has a front end surface, and the fragrance is carried on the front end surface.

[8]如[7]所記載之香味吸嚐器,其中前述突出部具有鄰接前述前端面之外周面及擔載於前述外周面之第2香料。 [8] The flavor taster according to [7], wherein the protruding portion has an outer peripheral surface adjacent to the front end surface and a second fragrance carried on the outer peripheral surface.

[9]如[8]所記載之香味吸嚐器,其中前述第2香料係與前述香料相同。 [9] The flavor taster according to [8], wherein the second fragrance is the same as the fragrance.

[10]如[8]所記載之香味吸嚐器,其中前述第2香料係與前述香料相異。 [10] The flavor taster according to [8], wherein the second fragrance is different from the fragrance.

[11]如[8]至[10]中任1項所記載之香味吸嚐器,其中前述外周面具有擔載有前述香料之環狀擔載部。 [11] The flavor taster according to any one of [8] to [10], wherein the outer peripheral surface has a ring-shaped support portion on which the fragrance is supported.

[12]如[6]所記載之香味吸嚐器,其中前述突出部係具有外周面,前述香料係擔載於前述外周面。 [12] The flavor taster according to [6], wherein the protruding portion has an outer peripheral surface, and the fragrance is carried on the outer peripheral surface.

[13]如[6]所記載之香味吸嚐器,其中前述突出部係具有前端面及鄰接前述前端面之外周面;前述燃燒型熱源係具有於前述固持器的內部供給空氣之通氣路、及由前述前端面及前述外周面之至少一者凹陷而設置於前述突出部,並與前述通氣路連通之溝部;前述香料係擔載於前述溝部。 [13] The flavor taster according to [6], wherein the protruding portion has a front end surface and an outer peripheral surface adjacent to the front end surface; the combustion-type heat source has an air passage for supplying air inside the holder, And a groove portion that is recessed by at least one of the front end surface and the outer peripheral surface, is provided in the protruding portion, and communicates with the air passage; and the fragrance is carried in the groove portion.

[14]如[13]所記載之香味吸嚐器,其中前述香料係擔載於前述前端面。 [14] The flavor taster according to [13], wherein the fragrance is carried on the front end surface.

[15]如[13]或[14]所記載之香味吸嚐器,其中前述突出部係具有擔載於前述外周面之第2香料。 [15] The flavor taster according to [13] or [14], wherein the protruding portion has a second fragrance carried on the outer peripheral surface.

[16]如[15]所記載之香味吸嚐器,其中前述第2香料係 與前述香料相同。 [16] The aroma taster as described in [15], wherein the aforementioned second fragrance system Same as the aforementioned fragrance.

[17]如[15]所記載之香味吸嚐器,其中前述第2香料係與前述香料相異。 [17] The flavor taster according to [15], wherein the second fragrance is different from the fragrance.

[18]如[15]至[17]中任1項所記載之香味吸嚐器,其中前述外周面係具有擔載有前述第2香料之環狀擔載部。 [18] The flavor taster according to any one of [15] to [17], wherein the outer peripheral surface has a ring-shaped support portion on which the second fragrance is supported.

[19]如[13]至[18]中任1項所記載之香味吸嚐器,其中前述通氣路係擔載第3香料。 [19] The flavor inhaler as described in any one of [13] to [18], wherein the third flavor is carried on the aeration channel.

[20]如[19]所記載之香味吸嚐器,其中前述第3香料係與前述香料相同。 [20] The flavor taster according to [19], wherein the third fragrance is the same as the fragrance.

[21]如[19]所記載之香味吸嚐器,其中前述第3香料係與前述香料相異。 [21] The flavor taster according to [19], wherein the third fragrance is different from the fragrance.

[22]如[1]至[21]中任1項所記載之香味吸嚐器,其中前述香料係含有選自由茴香腦、2-蒎烯、β-香茅醇、乙酸沈香酯、檸檬烯、大茴香醛、4-萜品醇、2-β-蒎烯、茉莉酮、檜烯、沈香醇、1,8-桉油醇、苯乙醇、及肉豆蔻醚所組成群組之至少一種。 [22] The fragrance taster as described in any one of [1] to [21], wherein the fragrance contains a compound selected from the group consisting of anethole, 2-pinene, β-citronellol, agarin acetate, limonene, At least one of the group consisting of anisaldehyde, 4-terpineol, 2-β-pinene, jasmone, juniperol, linalool, 1,8-cineol, phenethyl alcohol, and myristyl ether.

[23]如[8]至[11]及[15]至[18]中任1項所記載之香味吸嚐器,其中前述第2香料係含有選自由茴香腦、2-蒎烯、β-香茅醇、乙酸沈香酯、檸檬烯、大茴香醛、4-萜品醇、2-β-蒎烯、茉莉酮、檜烯、沈香醇、1,8-桉油醇、苯乙醇、及肉豆蔻醚所組成群組之至少一種。 [23] The flavor inhaler according to any one of [8] to [11] and [15] to [18], wherein the second fragrance system contains a compound selected from the group consisting of anethole, 2-pinene, and β- Citronellol, agarwood acetate, limonene, anisaldehyde, 4-terpineol, 2-β-pinene, jasmone, juniper, linalool, 1,8-eucalyptus alcohol, phenethyl alcohol, and nutmeg At least one kind of ether.

[24]如[19]至[21]中任1項所記載之香味吸嚐器,其中前述第3香料係含有選自由茴香腦、2-蒎烯、β-香茅醇、乙酸沈香酯、檸檬烯、大茴香醛、4-萜品醇、2-β-蒎烯、 茉莉酮、檜烯、沈香醇、1,8-桉油醇、苯乙醇、及肉豆蔻醚所組成群組之至少一種。 [24] The flavor applicator as described in any one of [19] to [21], wherein the third flavor system contains a compound selected from the group consisting of anethole, 2-pinene, β-citronellol, agarin acetate, Limonene, Anisaldehyde, 4-terpineol, 2-β-pinene, At least one of the group consisting of jasmone, juniper, linalool, 1,8-cineol, phenethyl alcohol, and myristyl ether.

[24]如[1]至[23]中任1項所記載之香味吸嚐器,其中前述燃燒型熱源係具有圓柱形。 [24] The flavor inhaler according to any one of [1] to [23], wherein the combustion-type heat source has a cylindrical shape.

[25]如[1]至[24]中任1項所記載之香味吸嚐器,其中前述燃燒型熱源係具有前端面、與前述前端面相對向之基端面、及連結前述前端面與前述基端面之外周面,前述前端面係在與前述外周面鄰接之位置具有倒角部。 [25] The aroma taster according to any one of [1] to [24], wherein the combustion-type heat source has a front end surface, a base end surface facing the front end surface, and connecting the front end surface and the foregoing On the outer peripheral surface of the base end surface, the front end surface has a chamfered portion at a position adjacent to the outer peripheral surface.

[26]如[1]至[25]中任1項所記載之香味吸嚐器,其中前述燃燒型熱源係具有由前述固持器之前述前端突出之突出部,前述香料係不擔載於與前述突出部之前端面相對向之前述突出部之基端面。 [26] The aroma taster according to any one of [1] to [25], wherein the combustion-type heat source has a protruding portion protruding from the front end of the holder, and the fragrance is not supported on the The front end surface of the protruding portion is opposed to the base end surface of the protruding portion.

[27]如[1]至[26]中任1項所記載之香味吸嚐器,其具備過濾器部,該過濾器部係設置在前述固持器內之前述吸口端側且具有香料膠囊。 [27] The flavor inhaler according to any one of [1] to [26], which includes a filter portion provided on the suction port end side in the holder and having a fragrance capsule.

[28]如[27]所記載之香味吸嚐器,其中在前述香料膠囊內封入有薄荷醇、醛系香料及單萜烯香料中之至少一種。 [28] The flavor taster according to [27], wherein at least one of menthol, aldehyde-based flavor, and monoterpene flavor is enclosed in the flavor capsule.

[29]如[27]所記載之香味吸嚐器,其中在前述香料膠囊內封入有薄荷醇。 [29] The flavor inhaler according to [27], wherein menthol is enclosed in the fragrance capsule.

[30]如[1]至[29]中任1項所記載之香味吸嚐器,其中前述固持器為紙筒。 [30] The flavor inhaler as described in any one of [1] to [29], wherein the holder is a paper tube.

[31]如[1]至[30]中任1項所記載之香味吸嚐器,更具備貼合於前述固持器的內側之鋁。 [31] The flavor inhaler described in any one of [1] to [30] further includes aluminum attached to the inside of the holder.

[32]如[1]至[31]中任1項所記載之香味吸嚐器,其中前 述香味源為菸草原料。 [32] The aroma inhaler as described in any one of [1] to [31], in which the front The flavor source is tobacco raw material.

[33]如[1]至[32]中任1項所記載之香味吸嚐器,更具備杯具,該杯具係於內部收納有前述香味源,且以朝向前述前端側開口的方向插入前述固持器內,並於底部具有開孔部。 [33] The flavor inhaler as described in any one of [1] to [32] further includes a cup set that houses the flavor source inside and is inserted in a direction opening toward the front end side The aforementioned holder has an opening at the bottom.

[34]如[33]所記載之香味吸嚐器,其中前述杯具為金屬製或紙製者。 [34] The flavor inhaler as described in [33], wherein the cup is made of metal or paper.

[35]一種燃燒型熱源,係設置於香味吸嚐器之前端,含有活性碳且擔載有香料,前述活性碳之BET比表面積為1300m2/g以上者。 [35] A combustion-type heat source, which is provided at the front end of the flavor inhaler, contains activated carbon and carries fragrance, and the BET specific surface area of the activated carbon is 1300 m 2 /g or more.

[36]如[35]所記載之燃燒型熱源,其中前述活性碳之BET比表面積為1300m2/g以上2500m2/g以下。 [36] The combustion-type heat source according to [35], wherein the BET specific surface area of the activated carbon is 1300 m 2 /g or more and 2500 m 2 /g or less.

[37]如[36]所記載之燃燒型熱源,其中前述活性碳之BET比表面積為2000m2/g以上2500m2/g以下。 [37] The combustion-type heat source according to [36], wherein the BET specific surface area of the activated carbon is 2000 m 2 /g or more and 2500 m 2 /g or less.

[38]如[37]所記載之燃燒型熱源,其中前述活性碳之BET比表面積為2050m2/g以上2300m2/g以下。 [38] to [37] described the combustion type heat source, wherein the activated carbon the BET specific surface area of 2050m 2 / g or more 2300m 2 / g or less.

[39]如[35]至[38]中任1項所記載之燃燒型熱源,其中前述燃燒型熱源所含的前述活性碳之濃度為30重量%以上60重量%以下。 [39] The combustion-type heat source according to any one of [35] to [38], wherein the concentration of the activated carbon contained in the combustion-type heat source is 30% by weight or more and 60% by weight or less.

[40]如[39]所記載之燃燒型熱源,其中前述燃燒型熱源所含的前述活性碳之濃度為30重量%以上45重量%以下。 [40] The combustion-type heat source according to [39], wherein the concentration of the activated carbon contained in the combustion-type heat source is 30% by weight or more and 45% by weight or less.

11‧‧‧香味吸嚐器 11‧‧‧Fragrant taste taster

12‧‧‧固持器 12‧‧‧Retainer

12A‧‧‧吸口端 12A‧‧‧Suction port

12B‧‧‧前端 12B‧‧‧Front end

13‧‧‧燃燒型熱源 13‧‧‧Combustion heat source

14‧‧‧突出部 14‧‧‧Projection

15‧‧‧香料 15‧‧‧ Spice

16‧‧‧香味源 16‧‧‧Scent source

17‧‧‧杯具 17‧‧‧Cup

17A‧‧‧段部 17A‧‧‧

18‧‧‧鋁貼合紙 18‧‧‧Aluminum laminated paper

21‧‧‧過濾器部 21‧‧‧Filter Department

22‧‧‧膠囊 22‧‧‧ capsules

23‧‧‧第1部分 23‧‧‧Part 1

24‧‧‧第2部分 24‧‧‧Part 2

25‧‧‧底部 25‧‧‧Bottom

25A‧‧‧開孔部 25A‧‧‧Opening

26‧‧‧緣部 26‧‧‧ Edge

27‧‧‧本體部分 27‧‧‧Body part

28‧‧‧前端面 28‧‧‧Front face

29‧‧‧基端面 29‧‧‧Base end face

31‧‧‧通氣路 31‧‧‧Ventilation

32‧‧‧外周面 32‧‧‧Perimeter

36‧‧‧吸口 36‧‧‧Suction

C‧‧‧中心軸 C‧‧‧Central axis

Claims (10)

一種香味吸嚐器,係具備:由吸口端延伸至前端之筒狀固持器;保持於前述固持器內之香味源;燃燒型熱源,係設置於前述前端,含有活性碳且擔載有香料,前述活性碳之BET比表面積為1300m2/g以上2500m2/g以下。 A fragrance taster is provided with: a cylindrical holder extending from the suction end to the front end; a fragrance source held in the holder; a combustion-type heat source, which is provided at the front end and contains activated carbon and carries fragrance, The BET specific surface area of the aforementioned activated carbon is 1300 m 2 /g or more and 2500 m 2 /g or less. 如申請專利範圍第1項所述之香味吸嚐器,其中前述活性碳之BET比表面積為2000m2/g以上2500m2/g以下。 The flavor taster as described in item 1 of the patent application range, wherein the BET specific surface area of the activated carbon is 2000 m 2 /g or more and 2500 m 2 /g or less. 如申請專利範圍第2項所述之香味吸嚐器,其中前述活性碳之BET比表面積為2050m2/g以上2300m2/g以下。 The application of the fragrance in item 2 patentable scope suction taste, wherein the activated carbon the BET specific surface area of 2050m 2 / g or more 2300m 2 / g or less. 如申請專利範圍第1項所述之香味吸嚐器,其中前述燃燒型熱源所含的前述活性碳之濃度為30重量%以上60重量%以下。 The aroma taster as described in item 1 of the patent application range, wherein the concentration of the activated carbon contained in the combustion-type heat source is 30% by weight or more and 60% by weight or less. 如申請專利範圍第4項所述之香味吸嚐器,其中前述燃燒型熱源所含的前述活性碳之濃度為30重量%以上45重量%以下。 The aroma taster as described in item 4 of the patent application range, wherein the concentration of the activated carbon contained in the combustion-type heat source is 30% by weight or more and 45% by weight or less. 如申請專利範圍第1項所述之香味吸嚐器,其中前述燃燒型熱源係具有由前述固持器之前述前端突出之突出部;前述香料係擔載於前述突出部。 The fragrance taster according to item 1 of the patent application range, wherein the combustion-type heat source has a protrusion protruding from the front end of the holder; and the fragrance is carried on the protrusion. 如申請專利範圍第6項所述之香味吸嚐器,其中前述突出部係具有前端面;前述香料係擔載於前述前端面。 The flavor taster according to item 6 of the patent application scope, wherein the protruding portion has a front end surface; and the fragrance is carried on the front end surface. 如申請專利範圍第1項所述之香味吸嚐器,其具備過濾器部,該過濾器部係設置於前述固持器內之前述吸口端側且具有香料膠囊。 The flavor inhaler as described in item 1 of the patent application scope includes a filter portion provided on the end of the mouthpiece in the holder and having a fragrance capsule. 如申請專利範圍第8項所述之香味吸嚐器,其中前述香料膠囊內封入有薄荷醇、醛系香料及單萜烯香料中之至少一種。 The flavor inhaler as described in item 8 of the patent application range, wherein at least one of menthol, aldehyde flavor and monoterpene flavor is enclosed in the flavor capsule. 一種燃燒型熱源,係設置於香味吸嚐器之前端,含有活性碳且擔載有香料,前述活性碳之BET比表面積為1300m2/g以上。 A combustion-type heat source is provided at the front end of a flavor absorber, contains activated carbon and carries fragrance, and the BET specific surface area of the activated carbon is 1300 m 2 /g or more.
TW106121982A 2016-07-01 2017-06-30 Flavor inhaler, combustion type heat source TWI682726B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN88100383A (en) * 1987-01-23 1988-08-03 R·J·雷诺兹烟公司 Aerosol delivery article
CN102481021A (en) * 2009-08-24 2012-05-30 R.J.雷诺兹烟草公司 Segmented smoking article with insulation mat
TW201402027A (en) * 2012-06-08 2014-01-16 Japan Tobacco Inc Flavor inhaler

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN88100383A (en) * 1987-01-23 1988-08-03 R·J·雷诺兹烟公司 Aerosol delivery article
CN102481021A (en) * 2009-08-24 2012-05-30 R.J.雷诺兹烟草公司 Segmented smoking article with insulation mat
CN102481021B (en) 2009-08-24 2014-12-10 R.J.雷诺兹烟草公司 Segmented smoking articles with insulating pads
TW201402027A (en) * 2012-06-08 2014-01-16 Japan Tobacco Inc Flavor inhaler

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