CN110571877A - A bendable wireless charging device - Google Patents

A bendable wireless charging device Download PDF

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Publication number
CN110571877A
CN110571877A CN201910405176.8A CN201910405176A CN110571877A CN 110571877 A CN110571877 A CN 110571877A CN 201910405176 A CN201910405176 A CN 201910405176A CN 110571877 A CN110571877 A CN 110571877A
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battery
flexible
wireless charging
control module
switch
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CN110571877B (en
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刘晨敏
路胜博
韩颖龙
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Nano and Advanced Materials Institute Ltd
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Nano and Advanced Materials Institute Ltd
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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J50/00Circuit arrangements or systems for wireless supply or distribution of electric power
    • H02J50/10Circuit arrangements or systems for wireless supply or distribution of electric power using inductive coupling
    • H02J50/12Circuit arrangements or systems for wireless supply or distribution of electric power using inductive coupling of the resonant type

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  • Engineering & Computer Science (AREA)
  • Computer Networks & Wireless Communication (AREA)
  • Power Engineering (AREA)
  • Secondary Cells (AREA)
  • Charge And Discharge Circuits For Batteries Or The Like (AREA)

Abstract

A bendable wireless charging device having an operational bend radius of approximately 90 degrees includes a flexible substrate, a receiving coil, a battery, a flexible EMI shielding layer, and a control module. The receiving coil is arranged on one surface of the substrate and is electrically connected to the control module. The battery, which may be a flexible battery, is disposed below the other surface of the substrate. An EMI shielding layer is disposed between the receiver coil and the battery.

Description

一种可弯曲的无线充电装置A bendable wireless charging device

技术领域technical field

本发明涉及电子充电装置,尤其涉及一种具有能够在使用上达到大约90度可操作的弯曲半径的无线充电装置。The present invention relates to an electronic charging device, in particular to a wireless charging device with an operable bending radius of about 90 degrees in use.

背景技术Background technique

近来,随着非接触(即无线)充电技术的发展,便携式电子设备已经采用了感应式无线充电设备进行无线充电。无线电力传输可以被定义为,通过位于电力发送单元(PTU)的线圈和位于电力接收单元(PRU)的线圈之间的磁感应而进行的谐振式无线电力传输;然后,PRU将所接收的电力传送到各种类型的便携式电子设备的电池。Recently, with the development of non-contact (ie, wireless) charging technology, portable electronic devices have adopted inductive wireless charging devices for wireless charging. Wireless power transfer can be defined as resonant wireless power transfer through magnetic induction between a coil located in a power transmitting unit (PTU) and a coil located in a power receiving unit (PRU); the PRU then transmits the received power to batteries of various types of portable electronic devices.

可穿戴电子设备尤其需要薄而轻的电池,以使佩戴者舒适并确保其安全。由于可穿戴电子设备呈更为复杂的形状,因此需要能够随着佩戴者的身体弯曲或屈伸的电池。尽管已经有一些柔性电池被公开,但是这些电池往往具有各种刚性或脆性部件,例如陶瓷隔板,它们限制了电池可能弯曲的程度。PRU本身与前述柔性电池的集成也被认为是另一个挑战;因为接收线圈通常由不易弯曲的粗金属线形成。Wearable electronics in particular require thin and light batteries to keep the wearer comfortable and secure. As wearable electronics take on more complex shapes, there is a need for batteries that can bend or flex with the wearer's body. Although some flexible batteries have been disclosed, these often have various rigid or brittle components, such as ceramic separators, that limit the extent to which the battery can be bent. The integration of the PRU itself with the aforementioned flexible battery was also considered another challenge; since the receiving coil is usually formed from thick metal wires that are not easily bendable.

因此,对于电池制造商而言,将PRU和柔性电池集成到柔性充电设备中已成为一项挑战。亟需一种可弯曲的无线充电设备以及柔性电池;这种设备及电池可以用在可弯曲的电子设备中,例如便携式可穿戴电子设备。Therefore, integrating PRUs and flexible batteries into flexible charging devices has become a challenge for battery manufacturers. There is an urgent need for a bendable wireless charging device and a flexible battery; such a device and battery can be used in bendable electronic devices, such as portable wearable electronic devices.

发明内容Contents of the invention

本发明的目的是提供一种解决上述和其他需求的无线充电装置。根据本发明的一个方面,提供一种集成了电池的可弯曲的无线充电装置,特别是柔性电池。It is an object of the present invention to provide a wireless charging device that addresses the above and other needs. According to one aspect of the present invention, there is provided a bendable wireless charging device integrating a battery, especially a flexible battery.

根据本发明的一个实施例,可弯曲的无线充电装置包括柔性(flexible)基板、柔性接收线圈、电池、柔性EMI屏蔽层和控制模块。基板具有大约90度的可操作的弯曲半径。接收线圈设置在基板的一表面上。电池位于基板的另一表面之下。EMI屏蔽层设置在设于基板上的接收线圈和电池之间。控制模块设置或形成在基板的与接收线圈相邻的一侧,并分别电性连接接收线圈和电池。According to one embodiment of the present invention, a bendable wireless charging device includes a flexible substrate, a flexible receiving coil, a battery, a flexible EMI shielding layer and a control module. The base plate has an operable bend radius of approximately 90 degrees. The receiving coil is arranged on a surface of the substrate. The battery is located under the other surface of the substrate. The EMI shielding layer is disposed between the receiving coil and the battery on the substrate. The control module is arranged or formed on the side of the substrate adjacent to the receiving coil, and is electrically connected to the receiving coil and the battery respectively.

根据本发明的另一方面,可弯曲的无线充电装置还包括另外的输出连接组,其连接到外部负载,使柔性电池能够同时对外部负载执行无线充电过程和放电过程。控制模块控制柔性电池的充电过程和/或负载的放电过程。According to another aspect of the present invention, the bendable wireless charging device further includes an additional output connection group connected to an external load, enabling the flexible battery to simultaneously perform a wireless charging process and a discharging process on the external load. The control module controls the charging process of the flexible battery and/or the discharging process of the load.

附图说明Description of drawings

本发明各附图以示例性而非限制的方式示出了本发明。在附图中,相同或相似的附图标记表示相同或相似的元件,其中:The drawings of the invention show the invention by way of illustration and not limitation. In the drawings, identical or similar reference numerals denote identical or similar elements, wherein:

图1示意性地示出了根据本发明一实施例的一种可弯曲的无线充电装置;Fig. 1 schematically shows a bendable wireless charging device according to an embodiment of the present invention;

图2示出了根据本发明实施例的一种可弯曲的无线充电装置的示例;Fig. 2 shows an example of a bendable wireless charging device according to an embodiment of the present invention;

图3示出了没有电池的可弯曲的无线充电装置的截面图的示例;Figure 3 shows an example of a cross-sectional view of a bendable wireless charging device without a battery;

图4示出了根据本发明一实施例的一种可弯曲的无线充电装置的实际实现的示例;Fig. 4 shows an example of practical implementation of a bendable wireless charging device according to an embodiment of the present invention;

图5示意性地示出了根据本发明一实施例的控制模块;Fig. 5 schematically shows a control module according to an embodiment of the present invention;

图6示意性地示出了根据本发明另一实施例的一种可弯曲的无线充电装置;Fig. 6 schematically shows a bendable wireless charging device according to another embodiment of the present invention;

图7示出了根据图6所示实施例的可弯曲的无线充电装置的示例;Fig. 7 shows an example of a bendable wireless charging device according to the embodiment shown in Fig. 6;

图8示意性地示出了根据图6所示实施例的可弯曲的无线充电装置;Fig. 8 schematically shows a bendable wireless charging device according to the embodiment shown in Fig. 6;

图9描绘出一可用于如图1所示的可弯曲的无线充电装置的柔性电池结构;FIG. 9 depicts a flexible battery structure that can be used in the bendable wireless charging device shown in FIG. 1;

图10描绘出一可用于如图1所示的可弯曲的无线充电装置的Jellyroll电池结构;以及Figure 10 depicts a Jellyroll battery structure that can be used in the bendable wireless charging device shown in Figure 1; and

图11A及图11B分别描绘出本发明及对应前案的海绵隔膜的结构。FIG. 11A and FIG. 11B respectively depict the structures of the sponge membranes of the present invention and the corresponding prior art.

具体实施方式Detailed ways

在以下描述中,举例说明了各种柔性电池和柔性无线充电装置。对于本领域技术人员显而易见的是,在不脱离本发明的范围和精神的情况下,可以进行修改,包括添加和/或替换。为免模糊本发明,可以省略描述具体细节;然而,本说明书的编写能够使本领域技术人员可以在不进行过度实验的情况下实践本文的教导。In the following description, various flexible batteries and flexible wireless charging devices are exemplified. It will be apparent to those skilled in the art that modifications, including additions and/or substitutions, can be made without departing from the scope and spirit of the present invention. Descriptions of specific details may be omitted in order not to obscure the invention; however, this specification has been written to enable one skilled in the art to practice the teachings herein without undue experimentation.

参照图1和图2,图1是根据本发明一实施例的一种可弯曲的无线充电装置的示意图;图2是示出根据本发明实施例的可弯曲的无线充电装置的示例图。在该实施例中,可弯曲的无线充电装置10包括柔性基板100、基本上为平面的接收线圈20、柔性电池40、柔性EMI屏蔽(电磁干扰屏蔽)层102、以及控制模块30。基板100具有至少90度的可操作的弯曲半径。术语“可操作的弯曲半径”是指充电装置可弯曲至至少90度并仍具有电子和机械方面的功能。更进一步,其也可能可在弯曲达120度或是180度(各半相互叠合)仍运作正常。接收线圈20设置在基板100的表面上,并且用于接收来自外部的传输电感线圈11的电能。该外部的传输电感线圈通常连接到电源,例如传统的墙上电源插座,或者通过USB端口连接到计算机电源。执得注意的是,所述电池40可为一柔性电池,相关细节将容后描述。或者是,其又可以是一个非常小的电池,例如钮扣电池或薄膜电池,通过小体积容许充电装置在导通和弯折不会受到干扰。柔性电池40位于也可以设置于具有接收线圈20的基板100的另一个表面附近之下。EMI屏蔽层102设置在接收线圈20和柔性电池40之间。控制模块30设置在或者形成在基板100的与接收线圈20相邻的一侧上,并且分别电连接到接收线圈20和柔性电池40。Referring to FIG. 1 and FIG. 2, FIG. 1 is a schematic diagram of a bendable wireless charging device according to an embodiment of the present invention; FIG. 2 is an example diagram showing a bendable wireless charging device according to an embodiment of the present invention. In this embodiment, the bendable wireless charging device 10 includes a flexible substrate 100 , a substantially planar receiving coil 20 , a flexible battery 40 , a flexible EMI shielding (electromagnetic interference shielding) layer 102 , and a control module 30 . The substrate 100 has an operable bend radius of at least 90 degrees. The term "operable bend radius" means that the charging device can be bent to at least 90 degrees and still be electrically and mechanically functional. Furthermore, it may also be able to bend up to 120 degrees or 180 degrees (with the halves superimposed on each other) and still function. The receiving coil 20 is disposed on the surface of the substrate 100 and used for receiving electric energy from the external transmitting inductive coil 11 . This external transmitting inductor is typically connected to a power source, such as a conventional wall outlet, or to a computer power source through a USB port. It should be noted that the battery 40 can be a flexible battery, and the relevant details will be described later. Alternatively, it can be a very small battery, such as a button battery or a thin-film battery, and the small volume allows the charging device to be turned on and bent without being disturbed. The flexible battery 40 is located under the vicinity of another surface of the substrate 100 which may also be provided with the receiving coil 20 . The EMI shielding layer 102 is disposed between the receiving coil 20 and the flexible battery 40 . The control module 30 is disposed or formed on a side of the substrate 100 adjacent to the receiving coil 20, and is electrically connected to the receiving coil 20 and the flexible battery 40, respectively.

控制模块30还可包括形成有两个电极302、304(例如导电垫)的第一输出连接组300,这两个电极表示相应的柔性电池40的正极端子和负极端子。The control module 30 may also include a first set of output connections 300 formed with two electrodes 302 , 304 (eg conductive pads) representing the positive and negative terminals of the respective flexible battery 40 .

此外,参考图3,图3是示出了没有柔性电池的可弯曲的无线充电装置的截面图的示例图。接收线圈20由金属层202和附着到金属层202的至少一个覆盖层204组成,其中金属层202通过使用加成或减成涂覆方式(subtractive coating method)而制造在柔性基板100上。金属层202的材料可以是铜、银、铜合金、银复合材料或其组合。至少一个覆盖层204保护金属层202免受机械损坏或氧化,并且它还可包括在金属层202上方的可选的粘合剂层(未示出),覆盖层204位于可选的粘合剂层上。基板100和覆盖层204的材料可以是聚酰亚胺(PI)薄片、聚醚醚酮(PEEK)、透明导电聚酯薄膜、弹性体薄膜、聚对苯二甲酸乙二醇酯(PET)或其组合。In addition, refer to FIG. 3 , which is an exemplary diagram illustrating a cross-sectional view of a bendable wireless charging device without a flexible battery. The receiving coil 20 consists of a metal layer 202 fabricated on the flexible substrate 100 using an additive or subtractive coating method and at least one cover layer 204 attached to the metal layer 202 . The material of the metal layer 202 may be copper, silver, copper alloy, silver composite material or a combination thereof. At least one cover layer 204 protects the metal layer 202 from mechanical damage or oxidation, and it may also include an optional adhesive layer (not shown) over the metal layer 202, the cover layer 204 being positioned over the optional adhesive layer. The material of the substrate 100 and the cover layer 204 may be polyimide (PI) sheet, polyether ether ketone (PEEK), transparent conductive polyester film, elastomer film, polyethylene terephthalate (PET) or its combination.

金属层202的厚度在5-100μm的范围内,并且基板100或覆盖层204的厚度在2-100μm的范围内。The thickness of the metal layer 202 is in the range of 5-100 μm, and the thickness of the substrate 100 or the cover layer 204 is in the range of 2-100 μm.

EMI屏蔽层102可以由吸收电磁波材料或反射电磁波的材料(例如热塑性或弹性体材料或其组合)与导电金属膜或粉末或纤维填料(例如金属/碳粉末或纤维)形成。示例性的EMI屏蔽材料包括铜和镍涂覆的聚氨酯片、具有埋入式磁性铁氧体颗粒的硅橡胶。The EMI shielding layer 102 may be formed of an electromagnetic wave absorbing material or an electromagnetic wave reflecting material such as thermoplastic or elastomeric material or a combination thereof and a conductive metal film or powder or fibrous filler such as metal/carbon powder or fiber. Exemplary EMI shielding materials include copper and nickel coated polyurethane sheets, silicone rubber with embedded magnetic ferrite particles.

参照图4,图4示出了根据本发明一实施例的无线充电装置的一种实现的示例图。在该实施例中,无线充电装置安装在一头盔的外表面上。如图4所示,无线充电装置10沿着头盔50的轮廓弯曲成弧形。Referring to Fig. 4, Fig. 4 shows an example diagram of an implementation of a wireless charging device according to an embodiment of the present invention. In this embodiment, the wireless charging device is mounted on the outer surface of a helmet. As shown in FIG. 4 , the wireless charging device 10 is bent into an arc along the contour of the helmet 50 .

根据本发明的可弯曲无线装置的接收线圈能够承受至少2000次反复弯曲(弯曲半径在20-40mm且至少120度的弯曲角度)而不损失充电性能。The receiving coil of the bendable wireless device according to the present invention can withstand at least 2000 repeated bendings (with a bending radius of 20-40 mm and a bending angle of at least 120 degrees) without loss of charging performance.

参照图1、图2和图5。图5是根据本发明一实施例的控制模块的示意图。在该实施例中,控制模块30包括串联连接的无线充电电路300、电池充电电路320和保护电路340。Refer to Figure 1, Figure 2 and Figure 5. FIG. 5 is a schematic diagram of a control module according to an embodiment of the invention. In this embodiment, the control module 30 includes a wireless charging circuit 300 , a battery charging circuit 320 and a protection circuit 340 connected in series.

无线充电电路300电性连接接收线圈20。电池充电电路320调节来自无线充电电路300的电压和电流,并向保护电路340输出调节后的电压和电流。The wireless charging circuit 300 is electrically connected to the receiving coil 20 . The battery charging circuit 320 regulates the voltage and current from the wireless charging circuit 300 , and outputs the regulated voltage and current to the protection circuit 340 .

保护电路通过第一输出连接组连接到柔性电池,并且还包括连接在保护电路和柔性电池之间的开关模块360。保护电路用于感测和控制开关模块。当从电池充电电路输入的电流或电压超过或低于预定值时,开关模块变为OFF,这样可避免柔性电池的错误充电。预定值可定义为包括短路、过充电和欠充电等相应场景的阈值。本领域技术人员会认识到,可以基于期望的用途或柔性电池的类型来改变预定值。例如,在第一输出连接组之间测量的过电压范围可以选择为3.5伏至5伏,并且欠电压范围可以选择为2伏至3伏。The protection circuit is connected to the flexible battery through the first output connection group, and further includes a switch module 360 connected between the protection circuit and the flexible battery. A protection circuit is used to sense and control the switch module. When the current or voltage input from the battery charging circuit exceeds or falls below a predetermined value, the switch module turns OFF, which can avoid wrong charging of the flexible battery. Predetermined values can be defined as thresholds for corresponding scenarios including short circuit, overcharge and undercharge. Those skilled in the art will recognize that the predetermined value may vary based on the desired use or type of flexible battery. For example, the overvoltage range measured between the first set of output connections may be chosen to be 3.5 volts to 5 volts, and the undervoltage range may be chosen to be 2 volts to 3 volts.

参照图6至图8。图6是根据本发明另一实施例的可弯曲无线充电装置的示意图;图7是示出了根据图6所示实施例的可弯曲无线的示例图;图8是根据图6所示实施例的控制模块的示意图。该实施例类似于图1所示实施例。不同之处在于,图6所示实施例的控制模块还包括:第二输出连接组310和开关模块361,其中,第二输出连接组310电性连接到外部的负载、系统或电子设备(下文称为“负载60”),开关模块361由串联级联的充电开关和放电开关组成。Refer to FIGS. 6 to 8 . Fig. 6 is a schematic diagram of a bendable wireless charging device according to another embodiment of the present invention; Fig. 7 is an example diagram showing a bendable wireless charging device according to the embodiment shown in Fig. 6; Fig. 8 is a diagram according to the embodiment shown in Fig. 6 Schematic diagram of the control module. This embodiment is similar to the embodiment shown in FIG. 1 . The difference is that the control module of the embodiment shown in FIG. 6 further includes: a second output connection group 310 and a switch module 361, wherein the second output connection group 310 is electrically connected to an external load, system or electronic device (hereinafter Referred to as "load 60"), the switch module 361 is composed of a charge switch and a discharge switch cascaded in series.

在该实施例中,如图6和图7所示,控制模块30位于基板100的邻近接收线圈20的一侧,并电性连接到接收线圈20、柔性电池40和负载60,用于控制柔性电池40的充电过程和/或向负载60放电的过程。柔性电池40位于EMI屏蔽层102下方。图7中未示出负载60,但是它可以被认为是任何类型的受电池驱动的电子设备,例如无线电动牙刷、手表或眼镜。本领域技术人员会认识到,对这些设备进行无线充电的实现和配置可以是不同的,因本发明的可弯曲无线充电装置通常会利用其灵活能力设置在相应的设备中。In this embodiment, as shown in FIGS. 6 and 7 , the control module 30 is located on the side of the substrate 100 adjacent to the receiving coil 20 , and is electrically connected to the receiving coil 20 , the flexible battery 40 and the load 60 for controlling the flexible battery 40 and the load 60 . The process of charging the battery 40 and/or the process of discharging the load 60 . The flexible battery 40 is located below the EMI shielding layer 102 . The load 60 is not shown in Figure 7, but it can be considered any type of battery powered electronic device, such as a cordless electric toothbrush, a watch or eyeglasses. Those skilled in the art will recognize that the implementation and configuration of wireless charging for these devices may be different, because the bendable wireless charging device of the present invention will generally be provided in corresponding devices by taking advantage of its flexible capabilities.

如图8所示,开关模块361包括充电开关362和放电开关363。在该实施例中,充电开关362和放电开关363中的每一个可以是N型MOSFET(金属氧化物-半导体场效应晶体管)。每个MOSFET都有一个栅极、一个漏极和一个源极。充电开关362和放电开关363的栅极分别连接到保护电路340。充电开关362和放电开关363的漏极彼此连接。充电开关362的源极连接到负载60的负极端子。放电开关363的源极连接到柔性电池40的负极端子。柔性电池40和负载60的正极端子连接到一公共节点。As shown in FIG. 8 , the switch module 361 includes a charge switch 362 and a discharge switch 363 . In this embodiment, each of the charge switch 362 and the discharge switch 363 may be an N-type MOSFET (Metal Oxide-Semiconductor Field Effect Transistor). Each MOSFET has a gate, a drain and a source. Gates of the charge switch 362 and the discharge switch 363 are connected to the protection circuit 340, respectively. Drains of the charge switch 362 and the discharge switch 363 are connected to each other. The source of charge switch 362 is connected to the negative terminal of load 60 . The source of the discharge switch 363 is connected to the negative terminal of the flexible battery 40 . The positive terminals of the flexible battery 40 and the load 60 are connected to a common node.

电池充电电路320调节来自无线充电电路300的电压和电流,并通过图8所示的VBAT向保护电路340输出调节后的电压和电流。保护电路340将通过检测柔性电池40和负载60的电压和/或电流状态来连续地监视柔性电池40和负载60。The battery charging circuit 320 regulates the voltage and current from the wireless charging circuit 300 , and outputs the regulated voltage and current to the protection circuit 340 through VBAT shown in FIG. 8 . The protection circuit 340 will continuously monitor the flexible battery 40 and the load 60 by detecting the voltage and/or current status of the flexible battery 40 and the load 60 .

如以上段落中所描述的那样,保护电路340包括多个预定值,用于确定本发明的可弯曲的无线充电装置是否正常工作。当充电或放电过程中检测到的电压高于或低于某个预定值时,保护电路340将在充电过程中选择性地降低充电开关362的栅极上的电压或者在放电过程中选择性地降低放电开关363的栅极上的电压。由于栅极电压较低,充电开关362和放电开关363将被切换为关断(OFF),因此保护电路340将由于关断的(OFF)MOSET型开关的大电阻而处于打开(open)状态。As described in the above paragraphs, the protection circuit 340 includes a plurality of predetermined values for determining whether the bendable wireless charging device of the present invention is working normally. When the voltage detected during charging or discharging is higher or lower than a certain predetermined value, the protection circuit 340 will selectively reduce the voltage on the gate of the charging switch 362 during the charging process or selectively reduce the voltage on the gate of the charging switch 362 during the discharging process. The voltage on the gate of discharge switch 363 is lowered. Since the gate voltage is low, the charge switch 362 and the discharge switch 363 will be switched OFF, so the protection circuit 340 will be open due to the high resistance of the OFF MOSET type switch.

相比之下,对于没有额外的(即第二)输出连接组的传统无线充电装置而言,相应的外部负载或电子设备仍然可以连接电池并从电池获取电力。具有连接到控制模块的保护电路的第二输出连接组的好处在于,本发明的无线充电装置不仅能够防止在充电和放电过程中电池过度充电或过度放电而损坏电池,还可以对电池进行无线充电,并同时向负载放电;从而,增强了本发明的实用性和便利性。In contrast, for a conventional wireless charging device without an additional (ie, second) output connection set, a corresponding external load or electronic device can still be connected to and draw power from the battery. The advantage of having the second output connection group connected to the protection circuit of the control module is that the wireless charging device of the present invention can not only prevent the battery from being damaged by overcharging or over-discharging during charging and discharging, but also wirelessly charge the battery , and discharge to the load at the same time; thus, the practicability and convenience of the present invention are enhanced.

图9示意性地示出根据本公开的一个方面的柔性可折叠锂离子电池的一部分的截面,其可作为本发明可弯曲的无线充电装置中所使用电池40。电池40具有180度的操作弯曲半径。本文使用的术语“操作弯曲半径”是指电池可以弯曲到仍然能产生电力而不造成操作中断的弯曲程度。180度的操作弯曲半径意味着电池可以完全自身折叠,同时仍然产生电力。FIG. 9 schematically shows a cross-section of a portion of a flexible and foldable lithium-ion battery according to an aspect of the present disclosure, which can be used as the battery 40 in the bendable wireless charging device of the present invention. The battery 40 has an operational bend radius of 180 degrees. As used herein, the term "operating bend radius" refers to the degree to which a battery can be bent to still generate power without interruption of operation. The 180-degree operating bend radius means the battery can completely fold on itself while still producing electricity.

在图9中,元件5表示包括第一集电体521、第二集电体531和隔膜51的电池(battery)的电池单元(single cell)。第一集电体521可以选自金属,如铝。铝可以是具有大约5微米至大约100微米的厚度的片材。活性材料522可以涂覆在铝片的一面或两面上以形成阴极。活性材料可以选自例如LiCoO2、LiMn2O4、Li2MnO3、LiNiMnCoO2、LiNiCoAlO2、LiFePO4或LiNi0.5Mn1.5O4,但是也可以使用其它活性材料及其混合物。In FIG. 9 , element 5 represents a single cell of a battery including a first current collector 521 , a second current collector 531 , and a separator 51 . The first current collector 521 may be selected from metals such as aluminum. Aluminum may be a sheet having a thickness of about 5 microns to about 100 microns. Active material 522 may be coated on one or both sides of the aluminum sheet to form a cathode. The active material can be selected, for example, from LiCoO2, LiMn2O4, Li2MnO3, LiNiMnCoO2, LiNiCoAlO2, LiFePO4 or LiNi0.5Mn1.5O4, but other active materials and mixtures thereof can also be used.

第二集电体可以选自金属,如铜。铜可以是具有大约5微米至大约100微米的厚度的片材。活性材料532可以涂覆在铜片的一面或两面上以形成阳极。用于阳极的活性材料包括碳基活性材料,如石墨、碳纳米管、石墨烯、硅、硅/碳复合材料、锗、锡、金属氧化物、金属氢化物及它们的混合物。The second current collector may be selected from metals such as copper. Copper may be a sheet having a thickness of about 5 microns to about 100 microns. Active material 532 may be coated on one or both sides of the copper sheet to form an anode. Active materials for the anode include carbon-based active materials such as graphite, carbon nanotubes, graphene, silicon, silicon/carbon composites, germanium, tin, metal oxides, metal hydrides, and mixtures thereof.

隔膜51位于集电体之间,防止集电体相互接触。隔膜51是高度多孔的高弹性聚合物纤维毡海绵,不管电池弯曲、折叠、切割或异物刺入,该海绵的回弹力都足以维持集电体521和531的分离。本文所用的术语“海绵”是指在保留液体的同时又能保持回弹力的多孔性、吸收性且弹性的结构。海绵在变形后恢复到其原来的形状。即,只要保持外力,就可以将海绵挤压到更小的区域中;一旦外力消除,海绵就恢复其原来的形状和体积。该隔膜作为海绵,能牢固地保持液体电解质,但是当电池外壳被刺穿或切割时,该隔膜也保持充分的吸收能力以将液体电解质保持在无泄漏状态,从而防止有害电解质的逸出。此外,海绵隔膜的回弹力能使电极在机械伤害(例如切割和穿刺)之后返回到其适当的分开的位置,从而使整体结构具有自恢复特性。本文使用的术语“自恢复”是指这样一种电池结构,该电池结构可以在机械伤害之后返回到其原始配置,使得在机械伤害引起的电力中断之后电力继续产生。海绵隔膜由于其海绵特性而能恢复到原来的形状和体积,从而使整个电池结构能够自恢复。The separator 51 is located between the current collectors and prevents the current collectors from contacting each other. The separator 51 is a highly porous high-elastic polymer fiber felt sponge, and the resilience of the sponge is sufficient to maintain the separation of the current collectors 521 and 531 no matter the battery is bent, folded, cut or penetrated by foreign objects. As used herein, the term "sponge" refers to a porous, absorbent, and elastic structure that retains liquid while maintaining resiliency. The sponge returns to its original shape after being deformed. That is, as long as the external force is maintained, the sponge can be squeezed into a smaller area; once the external force is removed, the sponge returns to its original shape and volume. The separator acts as a sponge to hold the liquid electrolyte firmly, but also maintains sufficient absorbency to keep the liquid electrolyte in a leak-free state when the battery case is punctured or cut, thereby preventing the escape of harmful electrolyte. In addition, the resilience of the sponge septum enables the electrodes to return to their proper separated positions after mechanical damage such as cutting and puncturing, thereby endowing the overall structure with self-healing properties. As used herein, the term "self-restoring" refers to a battery structure that can return to its original configuration after mechanical damage such that power continues to be generated after a power interruption caused by the mechanical damage. The sponge separator can return to its original shape and volume due to its sponge properties, thus enabling the self-healing of the entire battery structure.

电池中使用的电解质可以包括一种或多种有机溶剂,例如碳酸亚乙酯、碳酸二甲酯和碳酸二乙酯中的一者或多者。溶于溶剂中的是一种或多种锂盐,如LiPF6、LiBF4或LiClO4。通常基于被选择用于阴极和阳极的活性材料来调节电解质的组成。Electrolytes used in batteries may include one or more organic solvents, such as one or more of ethylene carbonate, dimethyl carbonate, and diethyl carbonate. Dissolved in the solvent is one or more lithium salts such as LiPF6, LiBF4 or LiClO4. The composition of the electrolyte is typically adjusted based on the active materials selected for the cathode and anode.

尽管图9示出的是基于组件堆层结构的电池的电池单元,但是可以形成组件的层并且将其卷成所谓的“卷芯”结构,如图10所示。在图10中,隔膜层51不仅位于每个“电池单元”层的阴极和阳极之间,而且还位于相邻电池单元层之间以防止电极之间短路,从而产生可自行恢复的整体有柔性且有回弹力的结构。Although FIG. 9 shows the cells of a battery based on a stack of components, layers of components can be formed and rolled into a so-called "core roll" configuration, as shown in FIG. 10 . In Figure 10, a separator layer 51 is placed not only between the cathode and anode of each "cell" layer, but also between adjacent cell layers to prevent short circuits between electrodes, resulting in a self-recoverable overall flexible And has a resilient structure.

海绵隔膜可以由亚微米级纤维的毡形成。在一个方面,纤维可以具有大约100nm至300nm之间的直径。孔隙率可以为约60%至约90%、平均孔径小于约1微米。具体地、亚微米级纤维可以由聚合物如聚偏氟乙烯(PVDF)、聚酰亚胺(PI)、聚酰胺(PA)、聚丙烯腈(PAN)、聚对苯二甲酸乙二醇酯(PET)、聚(偏氟乙烯-六氟丙烯)(PVDF-HFP)、(偏氟乙烯-三氟氯乙烯)共聚物(PVDF-co-CTFE)或其混合物制成。Sponge membranes can be formed from a mat of submicron fibers. In one aspect, the fibers can have a diameter between about 100 nm and 300 nm. The porosity may be from about 60% to about 90%, with an average pore size of less than about 1 micron. Specifically, submicron fibers can be made of polymers such as polyvinylidene fluoride (PVDF), polyimide (PI), polyamide (PA), polyacrylonitrile (PAN), polyethylene terephthalate (PET), poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP), (vinylidene fluoride-chlorotrifluoroethylene) copolymer (PVDF-co-CTFE) or a mixture thereof.

在另一个实施方案中,海绵隔膜可以是非织造聚合物纤维毡,其中聚合物纤维是第一聚合物材料和第二聚合物材料的复合材料。第一聚合物材料可以包括聚(偏氟乙烯)(PVDF)、聚酰亚胺(PI)、聚酰胺(PA)或聚丙烯腈(PAN)。第二聚合物材料可以包括聚乙二醇(PEG)、聚丙烯腈(PAN)、聚对苯二甲酸乙二醇酯(PET)、聚偏氟乙烯(PVDF)、聚(偏氟乙烯-六氟丙烯)(PVDF-HFP)或(偏氟乙烯-三氟氯乙烯)共聚物(PVDF-co-CTFE),其中第二聚合物材料不同于第一聚合物材料。第一和第二聚合物材料的重量比可以在约3:1至约1:1、更具体地约3:1至约2:1、更具体地约3:1至约3:2的范围内,并且更具体地是约3:1。In another embodiment, the sponge membrane may be a nonwoven polymer fiber mat, wherein the polymer fibers are a composite of a first polymer material and a second polymer material. The first polymer material may include poly(vinylidene fluoride) (PVDF), polyimide (PI), polyamide (PA) or polyacrylonitrile (PAN). The second polymer material may include polyethylene glycol (PEG), polyacrylonitrile (PAN), polyethylene terephthalate (PET), polyvinylidene fluoride (PVDF), poly(vinylidene fluoride-hexa Fluoropropylene) (PVDF-HFP) or (vinylidene fluoride-chlorotrifluoroethylene) copolymer (PVDF-co-CTFE), wherein the second polymer material is different from the first polymer material. The weight ratio of the first and second polymeric materials may range from about 3:1 to about 1:1, more specifically from about 3:1 to about 2:1, more specifically from about 3:1 to about 3:2 within, and more specifically about 3:1.

PVDF由于其优异的耐化学性和良好的热稳定性而被广泛用于制造超滤膜和微滤膜。纯PVDF聚合物具有较高的熔点和结晶度,并具有良好的机械性能。然而,它仅可溶于有限种类的溶剂中,例如N-甲基-2-吡咯烷酮(NMP)、N,N-二甲基乙酰胺(DMAC)、N,N-二甲基甲酰胺(DMF)、二甲亚砜(DMSO),并且在普通电解质中浸泡时显示低膨胀能力。PVDF is widely used in the manufacture of ultrafiltration and microfiltration membranes due to its excellent chemical resistance and good thermal stability. Pure PVDF polymer has a high melting point and crystallinity, and has good mechanical properties. However, it is only soluble in a limited class of solvents such as N-methyl-2-pyrrolidone (NMP), N,N-dimethylacetamide (DMAC), N,N-dimethylformamide (DMF ), dimethyl sulfoxide (DMSO), and exhibit low swelling capacity when soaked in common electrolytes.

PVDF-HFP共聚物可改善电解质溶解度,使得聚合物可溶于普通有机溶剂如丙酮和四氢呋喃(THF)中,这可进一步提高加工能力。此外,它具有非常高的膨胀能力,这可以增强隔膜层的电解质吸收。The PVDF-HFP copolymer can improve electrolyte solubility, making the polymer soluble in common organic solvents such as acetone and tetrahydrofuran (THF), which can further enhance the processability. In addition, it has a very high swelling capacity, which can enhance the electrolyte absorption of the separator layer.

本申请的发明人发现,PVDF和PVDF-HFP的复合材料在制造隔膜方面提供了许多优于其他聚合物的优点,例如:相对于Li+/Li从0V到5V的电化学稳定性;比单独的纯PVDF更好的溶解性,这可增强加工性;电解质的润湿性比PVDF更快;更好地控制电解质的泄漏;与电极持久粘合;以及良好的柔性。The inventors of the present application have found that the composite of PVDF and PVDF-HFP provides many advantages over other polymers in the manufacture of separators, such as: electrochemical stability from 0 V to 5 V with respect to Li+/Li; Pure PVDF has better solubility, which enhances processability; faster electrolyte wettability than PVDF; better control of electrolyte leakage; durable adhesion to electrodes; and good flexibility.

可以通过静电纺丝将复合材料形成为非织造纤维毡,下面进一步详细描述。静电纺丝可以从聚合物配方到铝箔上,以得到自立的隔膜。聚合物配方可以包括总量占该配方的约15-25重量%、优选约15-20重量%、更优选约16.5重量%的第一和第二聚合物材料。用于静电纺丝得到海绵隔膜的聚合物配方可以进一步包含约1-5重量%、优选约2-5重量%、更优选约3-5重量%、最优选约5重量%的至少一种添加剂。添加剂可以是氯化锂(LiCl),以促进离子转移穿过隔膜并且通过增加聚合物溶液的电导率来促进静电纺丝过程。在一个优选的实施方案中,聚合物配方可以包含约0.1-0.6μg、优选约0.1-0.5μg、更优选约0.2-0.4μg、最优选约0.3-0.4μg的LiCl。The composite material can be formed into a nonwoven fibrous mat by electrospinning, described in further detail below. Electrospinning can be performed from a polymer formulation onto aluminum foil to obtain a free-standing separator. The polymeric formulation may comprise the first and second polymeric materials in a total amount of about 15-25%, preferably about 15-20%, more preferably about 16.5% by weight of the formulation. The polymer formulation for electrospinning to obtain a sponge membrane may further comprise about 1-5% by weight, preferably about 2-5% by weight, more preferably about 3-5% by weight, most preferably about 5% by weight of at least one additive . The additive may be Lithium Chloride (LiCl) to facilitate ion transfer across the membrane and to facilitate the electrospinning process by increasing the conductivity of the polymer solution. In a preferred embodiment, the polymer formulation may comprise about 0.1-0.6 μg, preferably about 0.1-0.5 μg, more preferably about 0.2-0.4 μg, most preferably about 0.3-0.4 μg of LiCl.

在另一个实施方案中,结合任何上述和下述实施方案,用于静电纺丝得到本申请的非织造纳米纤维隔膜的聚合物配方可以包括至少一种选自以下的溶剂:N-甲基-2-吡咯烷酮(NMP)、N,N-二甲基乙酰胺(DMAC)、N,N-二甲基甲酰胺(DMF)、二甲亚砜(DMSO)、丙酮和四氢呋喃(THF)。在一个优选的实施方案中,聚合物配方可以包括DMF和丙酮。在另一个优选的实施方案中,聚合物配方可以包括重量比为约3:1至约1:1、优选约2:1至约1:1、更优选约1.5:1至1:1、最优选约1.25:1的DMF和丙酮。In another embodiment, in combination with any of the above and following embodiments, the polymer formulation used for electrospinning to obtain the nonwoven nanofibrous membrane of the present application may include at least one solvent selected from the group consisting of: N-methyl- 2-Pyrrolidone (NMP), N,N-Dimethylacetamide (DMAC), N,N-Dimethylformamide (DMF), Dimethylsulfoxide (DMSO), Acetone, and Tetrahydrofuran (THF). In a preferred embodiment, the polymer formulation may include DMF and acetone. In another preferred embodiment, the polymer formulation may comprise a weight ratio of about 3:1 to about 1:1, preferably about 2:1 to about 1:1, more preferably about 1.5:1 to 1:1, most preferably About 1.25:1 DMF and acetone is preferred.

在另一个实施方案中,结合任何上述和下述实施方案,本申请的非织造纳米纤维隔膜可以通过以下步骤进行静电纺丝:将第一和第二聚合物材料加入至少一种溶剂中,任选与LiCl一起加入;将所得混合物在80-100℃左右加热并搅拌约2-5小时;任选地加入至少一种添加剂,随后在80-100℃左右加热约2-5小时;将聚合物配方溶液冷却至室温;并将聚合物配方溶液加载到用于静电纺丝的输送筒(carriage)中。In another embodiment, in combination with any of the above and following embodiments, the nonwoven nanofibrous membrane of the present application can be electrospun by adding the first and second polymeric materials to at least one solvent, either Optionally added together with LiCl; the resulting mixture was heated and stirred at about 80-100°C for about 2-5 hours; optionally at least one additive was added, followed by heating at about 80-100°C for about 2-5 hours; the polymer The formulation solution was cooled to room temperature; and the polymer formulation solution was loaded into the carriage for electrospinning.

本申请的海绵隔膜的静电纺丝可以在以下参数下进行:温度:约20-30℃;电压:约20-50kV;相对湿度(RH):约25-60%;纺丝器高度:100-150mm;进料速率:5.5-8.5ml/h。The electrospinning of the sponge separator of the present application can be carried out under the following parameters: temperature: about 20-30°C; voltage: about 20-50kV; relative humidity (RH): about 25-60%; spinner height: 100- 150mm; feed rate: 5.5-8.5ml/h.

另一方面,原硅酸四甲酯(TMOS)或原硅酸四乙酯(TEOS)的添加剂可与聚合物配方一起使用。这些添加剂可以水解成陶瓷组分,从而改善海绵隔膜的表面纹理并提高尺寸稳定性。On the other hand, additives such as tetramethylorthosilicate (TMOS) or tetraethylorthosilicate (TEOS) can be used with polymer formulations. These additives can be hydrolyzed into ceramic components, thereby improving the surface texture of the sponge separator and increasing dimensional stability.

示例性的海绵隔膜的微结构在图11A中示出;如图11A所示,单根纤维容易区分,并且形成了许多孔,孔隙率大约80%。相比之下,具有约40%孔隙率的现有技术的市售隔膜(Celgard 2400聚丙烯隔膜)的微观结构在图11B中示出。在这种较低孔隙率的结构中,单根纤维不容易区分。图11A的海绵中的单独互连的纤维产生有柔性且有回弹力的海绵隔膜,该隔膜有助于各种实施方案的电池的自恢复特性。The microstructure of an exemplary sponge membrane is shown in FIG. 11A ; as shown in FIG. 11A , individual fibers were easily distinguished and formed many pores with a porosity of about 80%. In comparison, the microstructure of a prior art commercially available separator (Celgard 2400 polypropylene separator) with about 40% porosity is shown in FIG. 11B . In this lower porosity structure, individual fibers are not easily distinguishable. The individually interconnected fibers in the sponge of FIG. 11A create a flexible and resilient sponge membrane that contributes to the self-healing properties of batteries of various embodiments.

虽然本申请已经通过多个实施例及其实现予以描述,但是本申请不限于此,而是涵盖了落入所附权利要求的范围内的各种明显的修改和等同配置。虽然本申请的特征以权利要求之间的某些组合呈现,但是可以预期的是,这些特征可以以任何组合和顺序设置。While the application has been described in terms of several embodiments and implementations thereof, the application is not so limited but covers various obvious modifications and equivalent arrangements, which fall within the scope of the appended claims. Although features of the present application are presented in certain combinations between the claims, it is contemplated that these features can be arranged in any combination and order.

Claims (20)

1. a bendable wireless charging device, comprising:
A flexible substrate having an operable bend radius of at least 90 degrees;
A substantially planar receiving coil for receiving electrical energy from an external transmitting inductor and disposed on a surface of the flexible substrate;
A flexible battery having a bend radius of at least 90 degrees operable;
A flexible EMI shield layer positioned between the receiver coil and the flexible battery for blocking electromagnetic interference from the receiver coil;
And the control module is positioned or formed at one side of the flexible substrate, is adjacent to the receiving coil and is electrically communicated with the receiving coil and the battery, wherein the control module is used for controlling the charging process of the flexible battery and the discharging process of the load.
2. The apparatus of claim 1, wherein the control module further comprises a first set of output connections and a second set of output connections, wherein the control module is connected to the flexible battery through the first set of output connections and to the load through the second set of output connections.
3. The apparatus of claim 1, wherein the control module further comprises a wireless charging circuit, a battery charging circuit, and a protection circuit connected in series, wherein the wireless charging circuit is connected to the receiving coil, and a switch module is connected between the protection circuit and the flexible battery.
4. The apparatus of claim 3, the switch module comprising a charge switch and a discharge switch connected in series.
5. The apparatus of claim 4, wherein the protection circuit selectively turns on and off a charge switch during charging or selectively turns on and off a discharge switch during discharging by comparing a predetermined value with a voltage and/or current of the flexible battery or the load.
6. the apparatus of claim 4, wherein the charge switch and the discharge switch are MOSFET devices having a gate, a drain, and a source,
The grid electrode of the charging switch and the grid electrode of the discharging switch are respectively connected to the protection circuit;
The drain electrode of the charging switch and the drain electrode of the discharging switch are connected with each other;
a source of the charge switch is connected to a negative terminal of the load;
the source of the discharge switch is connected to the negative terminal of the flexible battery, and the positive terminal of the flexible battery and the positive terminal of the load are connected to a common node.
7. The device of claim 1, wherein the flexible battery is a lithium ion battery.
8. The device of claim 7, wherein the lithium ion battery comprises an electrospun polymer fiber sponge separator.
9. The apparatus of claim 8, wherein the lithium ion battery is a self-healing lithium ion battery.
10. A bendable wireless charging device, comprising:
a flexible substrate having an operable bend radius of at least 90 degrees;
A substantially planar receiving coil for receiving electrical energy from an external transmitting inductor and disposed on a surface of the flexible substrate;
A battery;
A flexible EMI shield layer positioned between the receiver coil and the battery for blocking electromagnetic interference from the receiver coil;
a control module located or formed on one side of the flexible substrate adjacent to the receiving coil and in electrical communication with the receiving coil, the battery and an external load, wherein the control module is configured to control a charging process of the battery.
11. The apparatus of claim 10, wherein the control module further comprises a first output connection set having two electrodes on the flexible substrate, wherein the two electrodes are electrically connected to two ends of the battery, respectively.
12. The apparatus of claim 11, wherein the control module further comprises a wireless charging circuit, a battery charging circuit, and a protection circuit connected in series, wherein the wireless charging circuit is connected to the receiving coil, and a switching module is connected between the protection circuit and the battery.
13. The apparatus of claim 12, wherein the protection circuit selectively turns the switching module on and off during charging by comparing a predetermined value with a voltage and/or current of the flexible battery.
14. The apparatus of claim 10, wherein the receive coil is comprised of a metal layer and at least one cover layer attached to the metal layer, wherein the metal layer is fabricated on the flexible substrate by additive or subtractive coating.
15. The apparatus of claim 14, wherein the metal layer is selected from the group consisting of copper, silver, copper alloys, silver composites.
16. The apparatus of claim 14, wherein the at least one capping layer protects the metal layer from mechanical damage or oxidation.
17. The apparatus of claim 14, wherein said receiver coil further comprises an adhesive layer over said metal layer, said cover layer being over said adhesive layer.
18. The apparatus of claim 14, wherein the material of the flexible substrate and the cover layer comprises a Polyimide (PI) sheet, Polyetheretherketone (PEEK), transparent conductive polyester film, elastomeric film, polyethylene terephthalate (PET), or a combination thereof.
19. the apparatus of claim 14, wherein the metal layer has a thickness in a range of about 5-100 μ ι η, and the flexible substrate and the cover layer have a thickness in a range of about 2-100 μ ι η.
20. The apparatus of claim 10, wherein the flexible EMI shielding layer is selected from the group consisting of metal-coated polymers or polymers with embedded conductive particles or fibers, polyurethane sheets, silicone rubber with embedded magnetic ferrite particles, polyesters, elastomers, and combinations thereof.
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