CN105666793B - A kind of gold-modeling combined housing molding die and its forming method - Google Patents
A kind of gold-modeling combined housing molding die and its forming method Download PDFInfo
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- CN105666793B CN105666793B CN201610000680.6A CN201610000680A CN105666793B CN 105666793 B CN105666793 B CN 105666793B CN 201610000680 A CN201610000680 A CN 201610000680A CN 105666793 B CN105666793 B CN 105666793B
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- 238000000034 method Methods 0.000 title claims abstract description 21
- 238000000465 moulding Methods 0.000 title claims description 23
- 239000002184 metal Substances 0.000 claims abstract description 176
- 229910052751 metal Inorganic materials 0.000 claims abstract description 176
- 239000004033 plastic Substances 0.000 claims abstract description 88
- 229920003023 plastic Polymers 0.000 claims abstract description 88
- 239000000758 substrate Substances 0.000 claims abstract description 86
- 239000000498 cooling water Substances 0.000 claims abstract description 75
- 238000002347 injection Methods 0.000 claims abstract description 62
- 239000007924 injection Substances 0.000 claims abstract description 62
- 238000010438 heat treatment Methods 0.000 claims abstract description 32
- 238000001746 injection moulding Methods 0.000 claims abstract description 31
- 238000001816 cooling Methods 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 230000007797 corrosion Effects 0.000 claims description 7
- 238000005260 corrosion Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 238000005488 sandblasting Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000012544 monitoring process Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000002585 base Substances 0.000 claims 16
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 6
- 239000010931 gold Substances 0.000 claims 6
- 229910052737 gold Inorganic materials 0.000 claims 6
- 239000003513 alkali Substances 0.000 claims 2
- 238000010276 construction Methods 0.000 claims 2
- 239000012467 final product Substances 0.000 claims 2
- 239000000047 product Substances 0.000 claims 2
- 238000007493 shaping process Methods 0.000 claims 2
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- 238000005485 electric heating Methods 0.000 abstract description 34
- 239000002131 composite material Substances 0.000 abstract description 20
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 150000002739 metals Chemical class 0.000 abstract 1
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- 238000011160 research Methods 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 238000001514 detection method Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
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- 230000009477 glass transition Effects 0.000 description 1
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- 229910052749 magnesium Inorganic materials 0.000 description 1
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- 238000010112 shell-mould casting Methods 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/26—Moulds
- B29C45/2602—Mould construction elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/72—Heating or cooling
- B29C45/73—Heating or cooling of the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/76—Measuring, controlling or regulating
- B29C45/78—Measuring, controlling or regulating of temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76494—Controlled parameter
- B29C2945/76531—Temperature
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
本发明公开了一种金‑塑复合壳体成型模具及其成型方法,包括塑料注射板、金属放置板和外部控制单元;塑料注射板置于金属放置板一侧,金属放置板与外部控制单元连接;塑料注射板内部设置有注射通道,塑料注射板底部与注射通道相通的凹面作为容纳注塑熔体的空间;金属放置板上表面为凹面,可放置金属基材;金属放置板的内部设置有电热元件、冷却水通道和温度传感器;将经过表面处理的金属基材放置在金属放置板凹面,经过加热、注射、冷却等步骤制得金‑塑复合件。有效地将金属基材和塑料有机结合,且无需使用胶黏剂,可保证金属与塑料之间的连接强度,应用性强。
The invention discloses a metal-plastic composite shell forming mold and a forming method thereof, comprising a plastic injection plate, a metal placement plate and an external control unit; the plastic injection plate is placed on one side of the metal placement plate, and the metal placement plate and the external control unit connection; the inside of the plastic injection plate is provided with an injection channel, and the concave surface at the bottom of the plastic injection plate communicated with the injection channel is used as a space for accommodating the injection molding melt; the upper surface of the metal placement plate is concave, and the metal substrate can be placed; Electric heating elements, cooling water channels and temperature sensors; placing the surface-treated metal substrate on the concave surface of the metal placement plate, and making a gold-plastic composite part through steps such as heating, injection, and cooling. Effectively organically combine metal substrates and plastics without using adhesives, which can ensure the connection strength between metals and plastics, and has strong applicability.
Description
技术领域technical field
本发明属于金-塑复合产品技术领域,涉及一种金-塑复合壳体成型模具,本发明还涉及一种金-塑复合壳体成型方法。The invention belongs to the technical field of gold-plastic composite products, and relates to a molding die for a gold-plastic composite shell, and also relates to a molding method for a gold-plastic composite shell.
背景技术Background technique
随着能源消耗与环境保护的不断提升,轻质、高强部件的制造与应用在航空航天、汽车制造、通讯等领域日益得到重视。利用铝/镁合金、高强度钢板、聚合物(塑料)等材料获取质量小、强度高的工程零件是近年来国内外研究的前沿热点。各类材料制造的零件都有其自身的优势和适用领域,金属-塑料复合高强件由于具有强度高、质量小、易成形复杂结构等优点,在飞机内仓件、汽车车身、计算机及通讯类产品的壳体等领域已得到逐步应用,显示出其广阔的前景。With the continuous improvement of energy consumption and environmental protection, the manufacture and application of lightweight and high-strength components have received increasing attention in the fields of aerospace, automobile manufacturing, and communications. The use of aluminum/magnesium alloys, high-strength steel plates, polymers (plastics) and other materials to obtain engineering parts with low mass and high strength is a frontier hotspot of research at home and abroad in recent years. Parts made of various materials have their own advantages and fields of application. Metal-plastic composite high-strength parts have the advantages of high strength, small mass, and easy to form complex structures. They are used in aircraft interior parts, automobile bodies, computers and communications It has been gradually applied in fields such as the shell of the product, showing its broad prospects.
众所周知,铝、镁、钛等轻质、高强材料由于具有高的比刚度、比强度和耐磨性在航空、汽车制造、通讯、家电等领域应用广泛,高强度钢板在汽车制造领域的研究和应用更是国内外学者研究的普遍热点。然而由于金属材料的固有特性,存在导热快、热膨胀系数大、难以成形复杂结构等缺点,限制了上述轻质、高强合金的应用领域。作为材料领域的后起之秀,塑料已成为现代社会生活中必不可少的材料,塑料注射成型是将高温下具有优良流动能力的熔融态液体注入模具型腔而成型制品,具有成形简单、成本低等优点,在生产复杂制品结构方面显示出了明显的优势,但塑料制品存在尺寸稳定性差、刚性以及机械强度低等缺点。摒弃金属基材和塑料材料的成形缺点,将二者的成形优点有机结合,生产获得满足使用要求和市场需求的轻质、高强的金属-塑料制品是近年来兴起的新的研究课题。As we all know, aluminum, magnesium, titanium and other lightweight and high-strength materials are widely used in aviation, automobile manufacturing, communications, home appliances and other fields due to their high specific stiffness, specific strength and wear resistance. The research and development of high-strength steel plates in the field of automobile manufacturing Application is a common hotspot of research by scholars at home and abroad. However, due to the inherent characteristics of metal materials, there are disadvantages such as fast heat conduction, large thermal expansion coefficient, and difficulty in forming complex structures, which limit the application fields of the above-mentioned lightweight and high-strength alloys. As a rising star in the field of materials, plastic has become an indispensable material in modern social life. Plastic injection molding is to inject molten liquid with excellent flowability at high temperature into the cavity of the mold to form products. It has the advantages of simple forming and low cost. , has shown obvious advantages in the production of complex product structures, but plastic products have disadvantages such as poor dimensional stability, rigidity and low mechanical strength. Abandoning the forming shortcomings of metal substrates and plastic materials, organically combining the forming advantages of the two, and producing light-weight, high-strength metal-plastic products that meet the requirements of use and market demand is a new research topic that has emerged in recent years.
申请号200710200616.3的中国专利,公布了一种“金属件与塑料件的连接结构”,该结构是通过将塑料熔体填充在金属件内加工的锁合槽实现金属与塑件的连接。The Chinese patent with application number 200710200616.3 discloses a "connection structure between metal parts and plastic parts". This structure realizes the connection between metal parts and plastic parts by filling plastic melt into locking grooves processed in metal parts.
申请号201010587963.8的中国专利,公开了一种“金属与塑料复合件的粘结方法及其成品”,该方法是通过在金属基板上上胶,再将塑料射出成型于金属基板具有胶的内表面上,从而实现金属与塑料的连接,制成金属与塑料制品。The Chinese patent application number 201010587963.8 discloses a "bonding method of metal and plastic composite parts and its finished product". The method is to apply glue on the metal substrate, and then inject the plastic on the inner surface of the metal substrate with glue On, so as to realize the connection of metal and plastic, and make metal and plastic products.
申请号200810301527.2的中国专利,公布了一种“金属与塑料的结合件及其制造方法”,包括金属本体及塑料部。通过在金属本体与塑料部结合处形成定位结构,采用嵌入成型技术一体成型,实现金属与塑料的连接。The Chinese patent application number 200810301527.2 discloses a "metal-plastic combination and its manufacturing method", including a metal body and a plastic part. By forming a positioning structure at the junction of the metal body and the plastic part, the insert molding technology is used for integral molding to realize the connection between the metal and the plastic.
上述现有技术要么是通过在金属基体设置锁合槽或定位结构,要么是在金属基体表面涂粘结剂实现金属与塑料的连接,制成相应的制品,存在工序较多、环保性差和强度不稳定的情况。The above-mentioned existing technologies either provide locking grooves or positioning structures on the metal substrate, or apply an adhesive on the surface of the metal substrate to realize the connection of metal and plastic, and make corresponding products, which have many processes, poor environmental protection and high strength. unstable situation.
发明内容Contents of the invention
本发明的目的是提供一种金-塑复合壳体成型模具,有效地将金属基材和塑料有机结合,且无需使用胶黏剂,可保证金属与塑料之间的连接强度,应用性强。The purpose of the present invention is to provide a metal-plastic composite shell forming mold, which can effectively combine the metal base material and the plastic organically, without using adhesives, can ensure the connection strength between the metal and the plastic, and has strong applicability.
本发明的另一目的是提供一种金-塑复合壳体成型模具的成型方法。Another object of the present invention is to provide a molding method of a metal-plastic composite shell molding die.
本发明所采用的技术方案是,一种金-塑复合壳体成型模具,包括塑料注射板、金属放置板和外部控制单元;塑料注射板置于金属放置板一侧,所述金属放置板与所述外部控制单元连接;塑料注射板内部设置有注射通道,塑料注射板底部与注射通道相通的凹面作为容纳注塑熔体的空间;金属放置板上表面为凹面,该凹面上设置有金属基材;所述金属放置板的内部设置有电热元件、冷却水通道和温度传感器,冷却水通道分别设有冷却水通道入口和冷却水通道出口;外部控制单元包括水泵、电动三通阀、电动两通阀、单向阀、过滤器、调压过滤器、继电器和温控主单元;水泵的进水端通过过滤器与冷却水池连接,水泵出水端通过电动三通阀与冷却水通道入口连接;电动三通阀的一个出口直接与冷却水池连接,电动两通阀的一端通过调压过滤器与压缩空气源连接,电动两通阀另一端与冷却水通道入口连接;冷却水通道出口通过单向阀与冷却水池相连;电热元件、温度传感器、温度显示仪分别与温控主单元连接,电热元件通过继电器与交流电源连接,继电器与温控主单元连接,电动三通阀与温控主单元连接。The technical solution adopted in the present invention is, a metal-plastic composite shell forming mold, including a plastic injection plate, a metal placement plate and an external control unit; the plastic injection plate is placed on one side of the metal placement plate, and the metal placement plate is connected to the metal placement plate The external control unit is connected; the plastic injection plate is provided with an injection channel, and the concave surface at the bottom of the plastic injection plate communicated with the injection channel is used as a space for accommodating the injection molding melt; the upper surface of the metal placement plate is concave, and the metal substrate is provided on the concave surface ; The inside of the metal placement plate is provided with an electric heating element, a cooling water channel and a temperature sensor, and the cooling water channel is respectively provided with a cooling water channel inlet and a cooling water channel outlet; the external control unit includes a water pump, an electric three-way valve, an electric two-way Valve, one-way valve, filter, pressure regulating filter, relay and temperature control main unit; the water inlet end of the water pump is connected to the cooling water pool through the filter, and the water outlet end of the water pump is connected to the inlet of the cooling water channel through the electric three-way valve; One outlet of the three-way valve is directly connected to the cooling water pool, one end of the electric two-way valve is connected to the compressed air source through a pressure regulating filter, and the other end of the electric two-way valve is connected to the inlet of the cooling water channel; the outlet of the cooling water channel passes through a one-way valve It is connected to the cooling water pool; the electric heating element, temperature sensor, and temperature display are respectively connected to the temperature control main unit, the electric heating element is connected to the AC power supply through the relay, the relay is connected to the temperature control main unit, and the electric three-way valve is connected to the temperature control main unit.
进一步的,所述电热元件的轴线与冷却水通道的轴线分布在两个平面内并呈立体垂直排列,电热元件距离金属放置板表面的距离与冷却水通道距离金属放置板表面的距离不相等。Further, the axis of the electric heating element and the axis of the cooling water channel are distributed in two planes and arranged vertically, and the distance between the electric heating element and the surface of the metal placing plate is not equal to the distance between the cooling water channel and the surface of the metal placing plate.
进一步的,所述温控主单元上设置有配电器;注塑机与温控主单元连接。Further, the temperature control main unit is provided with a distributor; the injection molding machine is connected with the temperature control main unit.
进一步的,所述温度传感器的直径为2-4mm,温度传感器贯穿金属放置板与金属基材直接接触;所述冷却水通道的直径为8-10mm,电热元件的直径为6-10mm。Further, the diameter of the temperature sensor is 2-4mm, and the temperature sensor penetrates through the metal placement plate and is in direct contact with the metal substrate; the diameter of the cooling water channel is 8-10mm, and the diameter of the electric heating element is 6-10mm.
进一步的,所述温控主单元包括监控设置器与PLC,信号输出模块、数字接收模块分别与PLC连接,A/D转换模块与数字接收模块连接。Further, the temperature control main unit includes a monitoring setter and a PLC, the signal output module and the digital receiving module are respectively connected to the PLC, and the A/D conversion module is connected to the digital receiving module.
进一步的,所述冷却水通道与电热元件间隔距离为15-20mm;冷却水通道距离塑料注射板或金属放置板凹面为10-12mm,电热元件距离金属放置板凹面的表面为2-6mm。Further, the distance between the cooling water channel and the electric heating element is 15-20mm; the distance between the cooling water channel and the concave surface of the plastic injection plate or the metal placing plate is 10-12mm, and the distance between the electric heating element and the concave surface of the metal placing plate is 2-6mm.
本发明所采用的另一技术方案是,金-塑复合壳体的成型方法,按照以下步骤进行:Another technical solution adopted by the present invention is that the molding method of the gold-plastic composite shell is carried out according to the following steps:
步骤1:金属基材表面处理;Step 1: surface treatment of the metal substrate;
首先利用碱液腐蚀或阳极氧化或机械喷砂的方式在金属基材的成形表面形成纳米级微孔结构,孔径30纳米到1微米,然后将处理好的金属基材放入金-塑复合壳体成型模具中;First, use alkaline corrosion, anodic oxidation or mechanical sandblasting to form a nano-scale microporous structure on the forming surface of the metal substrate, with a pore size of 30 nanometers to 1 micron, and then put the treated metal substrate into the gold-plastic composite shell body forming mold;
步骤2,加热阶段;Step 2, heating stage;
温控主单元控制电热元件加热金属基材,使其在15-30s内加热到85℃-115℃,同时,温度传感器获取金属基材表面温度并反馈到温控主单元中与设定的温度值进行比较,当金属基材的实际温度未达到设定值时,电热元件继续加热,当金属基材实际温度达到设定值时,电热元件停止加热;The temperature control main unit controls the electric heating element to heat the metal base material, making it heated to 85°C-115°C within 15-30s. At the same time, the temperature sensor obtains the surface temperature of the metal base material and feeds it back to the temperature control main unit to match the set temperature. When the actual temperature of the metal substrate does not reach the set value, the heating element continues to heat, and when the actual temperature of the metal substrate reaches the set value, the heating element stops heating;
步骤3,成形阶段;Step 3, forming stage;
利用注射机将注塑熔体通过模具内设定的注射通道,直接在金属基材表面形成塑料结构特征;注塑熔体的温度为230-270℃,注射压力为80-110MPa,注射完成后保压时间5-10s,冷却时间20s-30s,保证注塑熔体能充分进入金属基材表面的微孔结构;Use the injection machine to pass the injection melt through the injection channel set in the mold, and directly form the plastic structural features on the surface of the metal substrate; the temperature of the injection melt is 230-270 ° C, the injection pressure is 80-110 MPa, and the pressure is maintained after the injection is completed The time is 5-10s, and the cooling time is 20s-30s to ensure that the injection melt can fully enter the microporous structure on the surface of the metal substrate;
步骤4,冷却阶段;Step 4, cooling stage;
温控主单元控制冷却水通道冷却金属基材,直至达到设定的温度为止;The temperature control main unit controls the cooling water channel to cool the metal substrate until the set temperature is reached;
步骤5,制件取出;Step 5, the workpiece is taken out;
注塑熔体在金属基材表面冷却固化后,与金属基材形成一体结构,牢固结合在一起,取出即得。After the injection molding melt is cooled and solidified on the surface of the metal base material, it forms an integrated structure with the metal base material, and is firmly combined, and it is ready to be taken out.
本发明的有益效果是利用埋在注塑模具内部的电热元件对金属基材进行加热,利用冷却水通道中通入的冷却水对模具和金属基材进行冷却,通过温度传感器了解模具内金属基材表面的温度变化,确定注塑过程加热、冷却、开模等阶段的时间,消除高温熔体与金属基材之间由于较大的温度差而在熔体表面产生的冷凝层,避免冷凝层对熔体浸入金属基材微小孔洞的影响。同时,该成形模具可提高成型金属基材与塑料表面之间的粘合强度,消除了由于金属与塑料熔体温差产生的材料间内应力,保证产品精度及质量。The beneficial effect of the present invention is to use the electric heating element buried inside the injection mold to heat the metal base material, use the cooling water passed through the cooling water channel to cool the mold and the metal base material, and know the temperature of the metal base material in the mold through the temperature sensor. Surface temperature changes, determine the time of heating, cooling, mold opening and other stages in the injection molding process, eliminate the condensation layer on the surface of the melt due to the large temperature difference between the high-temperature melt and the metal substrate, and avoid the condensation layer on the melt The impact of the body immersing into the tiny pores of the metal substrate. At the same time, the forming die can improve the bonding strength between the formed metal substrate and the plastic surface, eliminate the internal stress between materials caused by the temperature difference between the metal and plastic melt, and ensure product accuracy and quality.
附图说明Description of drawings
图1是本发明的金-塑复合壳体成型模具外部控制单元的结构示意图。Fig. 1 is a structural schematic diagram of the external control unit of the metal-plastic composite housing molding die of the present invention.
图2是温控主单元结构示意图。Fig. 2 is a structural schematic diagram of the temperature control main unit.
图3是本发明的模具结构及其控制原理示意图。Fig. 3 is a schematic diagram of the mold structure and its control principle of the present invention.
图4是采用本发明的模具结构设计的金属放置板实例示意图Fig. 4 is the example schematic diagram of the metal placement plate adopting the mold structure design of the present invention
图5是图4侧视图。Fig. 5 is a side view of Fig. 4 .
其中:1、过滤器,2、水泵,3、电动三通阀,4、单向阀,5、调压过滤器,6、电动两通阀,7、温控主单元,8.配电器,9、继电器,11、电热元件,12、交流电源,13、温度传感器,14、温度显示仪,15、注塑机,16、压缩空气源,17、冷却水通道入口,18、冷却水通道出口,19、冷却水池,20、冷却水通道,21、金属放置板,22、塑料注射板,23、金属基材,24、注塑熔体,25、PLC,26、监控设置器,27、信号输出模块,28、数字接收模块,29、A/D转换模块。Among them: 1. Filter, 2. Water pump, 3. Electric three-way valve, 4. One-way valve, 5. Pressure regulating filter, 6. Electric two-way valve, 7. Temperature control main unit, 8. Distributor, 9. Relay, 11. Heating element, 12. AC power supply, 13. Temperature sensor, 14. Temperature indicator, 15. Injection molding machine, 16. Compressed air source, 17. Cooling water channel inlet, 18. Cooling water channel outlet, 19. Cooling water pool, 20. Cooling water channel, 21. Metal placement plate, 22. Plastic injection plate, 23. Metal substrate, 24. Injection melt, 25. PLC, 26. Monitoring setter, 27. Signal output module , 28, digital receiving module, 29, A/D conversion module.
具体实施方式Detailed ways
下面结合附图和具体实施方式对本发明进行详细说明。The present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments.
本发明的金-塑壳体的成型工艺就是在注塑成型之前,将参与成形的金属基材首先进行表面处理,获取具有一定形状和尺寸的微孔特征,然后将金属基材23置于模具的金属放置板21内,通过模具内的电热元件11将在金属基材23表面注射塑料的部位加热,然后对金属基材23表面进行温度检测和反馈调节,使之达到所需温度,再将塑料熔体注塑到金属基材23表面,然后进行后续的保压、冷却、开模取件等成形过程。The molding process of the gold-plastic shell of the present invention is to firstly carry out surface treatment on the metal base material participating in the molding before injection molding to obtain micropore characteristics with a certain shape and size, and then place the metal base material 23 on the surface of the mould. The metal is placed in the plate 21, and the part where the plastic is injected on the surface of the metal substrate 23 is heated by the electric heating element 11 in the mold, and then the temperature detection and feedback adjustment are performed on the surface of the metal substrate 23 to make it reach the required temperature, and then the plastic The melt is injected onto the surface of the metal base material 23, and then subsequent forming processes such as pressure maintaining, cooling, mold opening and parts taking are performed.
实现上述工艺的一种金-塑复合壳体成型模具,包括塑料注射板22、金属放置板21和外部控制单元。A gold-plastic composite housing forming mold for realizing the above process includes a plastic injection plate 22, a metal placement plate 21 and an external control unit.
如图3所示,金属放置板21的内部设置有电热元件11、冷却水通道20和温度传感器13。冷却水通道20分别设有冷却水通道入口17和冷却水通道出口18。电热元件11的轴线与冷却水通道20的轴线分布在两个平面内并呈立体垂直排列,电热元件11距离金属放置板21表面的距离与冷却水通道20距离金属放置板21表面的距离不相等。金属放置板21与外部控制单元连接,加热模具使金属基材23达到设定温度,通过外部控制单元的控制即可完成注塑成型。As shown in FIG. 3 , an electric heating element 11 , a cooling water channel 20 and a temperature sensor 13 are arranged inside the metal placement plate 21 . The cooling water channel 20 is respectively provided with a cooling water channel inlet 17 and a cooling water channel outlet 18 . The axis of the electric heating element 11 and the axis of the cooling water channel 20 are distributed in two planes and are vertically arranged in three dimensions. The distance between the electric heating element 11 and the surface of the metal placing plate 21 is not equal to the distance between the cooling water channel 20 and the surface of the metal placing plate 21 . The metal placing plate 21 is connected with the external control unit, and the mold is heated to make the metal base material 23 reach the set temperature, and the injection molding can be completed through the control of the external control unit.
为了准确控制生产过程中金属基材的温度,本发明的模具中还包含如图1所示的外部控制单元。水泵2的进水端通过过滤器1与冷却水池19连接,水泵2出水端通过电动三通阀3与冷却水通道入口17连接,以向冷却水通道内加入冷却水;电动三通阀3的一个出口直接与冷却水池19连接,以便在冷却水通道内不需要冷却水时,由水泵2流出的水直接由电动三通阀3回到冷却水池19,通过电动三通阀3控制冷却水的流向。电动两通阀6的一端通过调压过滤器5与压缩空气源16连接,电动两通阀6另一端与冷却水通道入口17连接,以便向冷却水通道20内通入空气将冷却水全部吹出。冷却水通道出口18通过单向阀4与冷却水池19相连。当模具加热时,单向阀4避免冷却水倒流入模具内部。电热元件11、温度传感器13、温度显示仪14均与温控主单元7连接,电热元件11通过继电器9与交流电源12连接,继电器9与温控主单元7连接,实现温控主单元7控制电热元件11的工作。温度显示仪14用于输入温度等控制参数。温控主单元7上设置有配电器8。电动三通阀3与温控主单元7连接。In order to accurately control the temperature of the metal substrate during the production process, the mold of the present invention also includes an external control unit as shown in FIG. 1 . The water inlet end of the water pump 2 is connected with the cooling water pool 19 through the filter 1, and the water outlet end of the water pump 2 is connected with the cooling water channel inlet 17 through the electric three-way valve 3, so as to add cooling water to the cooling water channel; the electric three-way valve 3 One outlet is directly connected to the cooling water pool 19, so that when cooling water is not needed in the cooling water passage, the water flowing out of the water pump 2 is directly returned to the cooling water pool 19 by the electric three-way valve 3, and the flow of cooling water is controlled by the electric three-way valve 3 flow direction. One end of the electric two-way valve 6 is connected to the compressed air source 16 through the pressure regulating filter 5, and the other end of the electric two-way valve 6 is connected to the inlet 17 of the cooling water channel, so that air can be passed into the cooling water channel 20 to blow out all the cooling water . The outlet 18 of the cooling water channel is connected with the cooling water pool 19 through the one-way valve 4 . When the mold is heated, the one-way valve 4 prevents the cooling water from flowing back into the mold. The electric heating element 11, the temperature sensor 13, and the temperature display 14 are all connected to the temperature control main unit 7, the electric heating element 11 is connected to the AC power supply 12 through the relay 9, and the relay 9 is connected to the temperature control main unit 7 to realize the control of the temperature control main unit 7 The work of heating element 11. The temperature display instrument 14 is used for inputting control parameters such as temperature. A distributor 8 is arranged on the temperature control main unit 7 . The electric three-way valve 3 is connected with the temperature control main unit 7 .
其中,温控主单元7的结构如图2所示,包括监控设置器26与PLC25,信号输出模块27、数字接收模块28分别与PLC25连接,A/D转换模块29与数字接收模块28连接。Wherein, the structure of the temperature control main unit 7 is shown in FIG. 2 , including a monitoring setter 26 and a PLC 25 , a signal output module 27 and a digital receiving module 28 connected to the PLC 25 respectively, and an A/D conversion module 29 connected to the digital receiving module 28 .
在成形过程中,温度显示仪14输入金属基材23的温度范围等控制参数,由埋在模具内部的温度传感器13测量金属基材23的温度,如果温度没有位于设定的高温范围之内(注塑熔体24与金属基材23最佳粘合强度温度,一般为80-180℃),则温控主单元7控制继电器9给电热元件11供电,利用电热元件11对金属放置板21快速加热使金属基材23温度到达温度范围之内。在金属基材23的温度达到设定的温度后,温度显示仪14向温控主单元7发出准备就绪的信号,温控主单元7向注塑机15发出可以成型的信号,进行注塑,完成成型过程;完成注塑后,温控主单元7接收到注塑机15的信号后,控制电动三通阀3的开关状态,让冷却水进入金属放置板21的冷却水通道入口17,利用冷却水对金属放置板21进行快速冷却,当金属放置板21的温度被冷却到设定的温度范围之内时,温控主单元7向注塑机15发出可以打开模具的信号,取出成型零件。同时,温控主单元7接到注塑机15的开模信号,控制电动三通阀3的开关状态,让冷却水直接回到冷却水池19。同时控制电动两通阀6打开,压缩空气源16的空气经调压过滤器5和电动两通阀6由金属放置板21的冷却水通道入口17进入冷却水通道20,将金属放置板21中的残余冷却水通过冷却水通道出口18、单向阀4吹回到冷却水池19。在压缩空气进入金属放置板21中2-3秒后,外部控制单元给电热元件11供电,然后进入下一个成形循环。During the forming process, the temperature indicator 14 inputs control parameters such as the temperature range of the metal substrate 23, and the temperature sensor 13 buried inside the mold measures the temperature of the metal substrate 23. If the temperature is not within the set high temperature range ( The optimum bonding strength temperature between the injection molding melt 24 and the metal substrate 23 is generally 80-180°C), then the temperature control main unit 7 controls the relay 9 to supply power to the electric heating element 11, and uses the electric heating element 11 to quickly heat the metal placement plate 21 Make the temperature of the metal substrate 23 within the temperature range. After the temperature of the metal substrate 23 reaches the set temperature, the temperature indicator 14 sends a signal to the temperature control main unit 7 that it is ready, and the temperature control main unit 7 sends a signal to the injection molding machine 15 that it can be molded, and the injection molding is completed to complete the molding process; after the injection molding is completed, after the temperature control main unit 7 receives the signal of the injection molding machine 15, it controls the switching state of the electric three-way valve 3, allowing the cooling water to enter the cooling water channel inlet 17 of the metal placement plate 21, and utilize the cooling water to cool the metal The placing plate 21 is cooled rapidly, and when the temperature of the metal placing plate 21 is cooled to within the set temperature range, the temperature control main unit 7 sends a signal to the injection molding machine 15 that the mold can be opened, and the molded parts are taken out. At the same time, the temperature control main unit 7 receives the mold opening signal from the injection molding machine 15 to control the switching state of the electric three-way valve 3 so that the cooling water returns to the cooling water pool 19 directly. Control electric two-way valve 6 to open simultaneously, the air of compressed air source 16 enters cooling water channel 20 by the cooling water passage entrance 17 of metal placement plate 21 through pressure regulating filter 5 and electric two-way valve 6, puts metal placement plate 21 The remaining cooling water is blown back to the cooling water pool 19 through the cooling water channel outlet 18 and the one-way valve 4. After the compressed air enters the metal placing plate 21 for 2-3 seconds, the external control unit supplies power to the electric heating element 11, and then enters the next forming cycle.
图4给出了一种采用本发明结构的金-塑壳体成型模具金属放置板结构示意图。Fig. 4 shows a schematic structural view of the metal placement plate of the gold-plastic housing molding die with the structure of the present invention.
其中温度传感器13的直径为2-4mm,温度传感器13贯穿金属放置板21与金属基材23直接接触;冷却水通道20的直径为8-10mm,电热元件11的直径为6-10mm。冷却水通道20距离塑料注射板22和金属放置板21凹面10-12mm,电热元件11距离金属放置板21的凹面2-6mm,冷却水通道20及电热元件11的布置间隔距离为15-20mm。Wherein the diameter of the temperature sensor 13 is 2-4mm, the temperature sensor 13 penetrates the metal placement plate 21 and directly contacts the metal substrate 23; the diameter of the cooling water channel 20 is 8-10mm, and the diameter of the heating element 11 is 6-10mm. The cooling water channel 20 is 10-12mm away from the concave surface of the plastic injection plate 22 and the metal placing plate 21, the electric heating element 11 is 2-6mm away from the concave surface of the metal placing plate 21, and the distance between the cooling water channel 20 and the electric heating element 11 is 15-20mm.
由于金属-塑料复合件成型过程中,当注塑熔体24(即塑料熔体)与金属基材23接触时,若金属基材23温度较低,塑料熔体与金属基材23表面间的热量传递会使与金属基材23接触的表层熔体迅速降低,造成表层的塑料熔体迅速固化而形成冷凝层。冷凝层的存在会阻碍塑料熔体向金属基材23的微孔浸入,从而影响塑料熔体与金属基材23的界面结合。此外,填充过程中若金属基材23温度过低,塑料熔体冷却速度不均,会使塑料熔体与金属基材23间的结合处存在较大的应力集中,进一步影响塑料熔体与金属基材23的界面结合。当金属基材23温度高于塑料熔体的玻璃化温度或熔点时,塑料熔体的表面冷凝层会变薄或消失。在一定范围内,随着金属基材23温度的升高,塑料熔体的粘度逐步降低,塑料熔体的流动性得到提高,有利于塑料熔体填充到金属基材23表面的微小孔洞,保证二者的界面结合。Due to the metal-plastic composite molding process, when the injection molding melt 24 (i.e. plastic melt) is in contact with the metal substrate 23, if the temperature of the metal substrate 23 is low, the heat between the plastic melt and the surface of the metal substrate 23 The transfer will cause the surface melt in contact with the metal substrate 23 to drop rapidly, causing the plastic melt on the surface to solidify rapidly to form a condensation layer. The existence of the condensed layer will prevent the plastic melt from infiltrating into the micropores of the metal substrate 23 , thereby affecting the interface bonding between the plastic melt and the metal substrate 23 . In addition, if the temperature of the metal substrate 23 is too low during the filling process, the cooling rate of the plastic melt will be uneven, which will cause a large stress concentration at the joint between the plastic melt and the metal substrate 23, further affecting the plastic melt and metal. Interfacial bonding of the substrate 23 . When the temperature of the metal substrate 23 is higher than the glass transition temperature or melting point of the plastic melt, the surface condensation layer of the plastic melt will become thinner or disappear. Within a certain range, as the temperature of the metal substrate 23 increases, the viscosity of the plastic melt gradually decreases, and the fluidity of the plastic melt improves, which is conducive to filling the tiny holes on the surface of the metal substrate 23 with the plastic melt, ensuring interface of the two.
根据以上金属-塑料成形工艺流程及对金属板材温度的要求,发明了一种金-塑复合壳体成型模具的成型方法。According to the above metal-plastic forming process and the requirements on the temperature of the metal sheet, a forming method of a metal-plastic composite shell forming die is invented.
具体如下:details as follows:
步骤1:金属基材23表面处理;Step 1: surface treatment of the metal substrate 23;
首先利用碱液腐蚀或阳极氧化或机械喷砂的方式在金属基材23的成形表面形成纳米级微孔结构,孔径30纳米到1微米,然后将处理好的金属基材23放入本发明的金-塑复合壳体成型模具中;First utilize alkaline solution corrosion or anodic oxidation or the mode of mechanical sandblasting to form nanoscale microporous structure on the forming surface of metal substrate 23, aperture 30 nanometers to 1 micron, then put the processed metal substrate 23 into the present invention Gold-plastic composite shell forming mold;
步骤2,加热阶段Step 2, heating phase
温控主单元7控制电热元件11加热金属基材23,使其在15-30s内加热到85-115℃,同时,温度传感器13获取金属基材23表面温度并反馈到温控主单元7中与设定的温度值(假定为110摄氏度)进行比较,当金属基材23的实际温度未达到设定值时,电热元件11继续加热,当金属基材23实际温度达到设定值时,电热元件11停止加热;The temperature control main unit 7 controls the electric heating element 11 to heat the metal base material 23, making it heated to 85-115°C within 15-30s. At the same time, the temperature sensor 13 obtains the surface temperature of the metal base material 23 and feeds it back to the temperature control main unit 7 Compared with the set temperature value (assumed to be 110 degrees Celsius), when the actual temperature of the metal substrate 23 did not reach the set value, the electric heating element 11 continued to heat, and when the actual temperature of the metal substrate 23 reached the set value, the electric heating Element 11 stops heating;
步骤3,成形阶段;Step 3, forming stage;
利用注射机15,将注塑熔体24通过模具内设定的浇注系统,直接在金属基材23表面形成塑料结构特征。注塑熔体24的温度为230-270℃,注射压力为80-110MPa,注射完成后保压时间5-10s,冷却时间20s-30s,保证注塑熔体24能充分进入金属基材23表面的微孔结构,提高塑料与金属表面的结合强度;Using the injection machine 15, the injection melt 24 passes through the gating system set in the mold to directly form plastic structural features on the surface of the metal substrate 23. The temperature of the injection molding melt 24 is 230-270°C, the injection pressure is 80-110MPa, the holding time after injection is 5-10s, and the cooling time is 20s-30s, so as to ensure that the injection molding melt 24 can fully enter the microscopic particles on the surface of the metal substrate 23. Pore structure, improve the bonding strength of plastic and metal surface;
步骤4,冷却阶段;Step 4, cooling stage;
温控主单元7控制冷却水通道20冷却金属基材23,直至达到设定的温度(70℃)为止。温控主单元7既保证温控系统自身的信号控制又能与注塑机15实现信号互动,保证成形过程的顺利进行;The temperature control main unit 7 controls the cooling water channel 20 to cool the metal substrate 23 until the set temperature (70° C.) is reached. The temperature control main unit 7 not only ensures the signal control of the temperature control system itself but also realizes signal interaction with the injection molding machine 15 to ensure the smooth progress of the molding process;
步骤5,制件取出;Step 5, the workpiece is taken out;
注塑熔体24在金属基材23表面冷却固化后,与金属基材23形成一体结构,牢固结合在一起。After the injection molding melt 24 is cooled and solidified on the surface of the metal base material 23 , it forms an integral structure with the metal base material 23 and is firmly combined.
通过该方法可以实现将金属基材23和塑料(注塑熔体24)有机结合,无需使用胶黏剂,避免了胶黏剂释放的有害气体对操作人员的身体伤害。利用金属基材23制得产品的外表面,能满足产品的壁厚、强度和外观要求。塑料制作产品内表面能起到减震隔热的作用,同时,由于注塑熔体24的易流动性,还能生产带有螺钉孔、加强筋等复杂结构的制品,满足产品后续的装配需求。Through this method, the organic combination of the metal substrate 23 and the plastic (injection melt 24 ) can be realized without using adhesives, and the harmful gas released by the adhesives is avoided from causing bodily harm to operators. The outer surface of the product is made by using the metal base material 23, which can meet the wall thickness, strength and appearance requirements of the product. The inner surface of the product made of plastic can play the role of shock absorption and heat insulation. At the same time, due to the easy fluidity of the injection molding melt 24, products with complex structures such as screw holes and ribs can also be produced to meet the subsequent assembly requirements of the product.
实施例1Example 1
首先利用碱液腐蚀或阳极氧化或机械喷砂的方式在金属基材的成形表面形成纳米级微孔结构,孔径30纳米到1微米,然后将处理好的金属基材放入金-塑复合壳体成型模具中;温控主单元控制电热元件加热金属基材,使其在15s内加热到85℃,同时,温度传感器获取金属基材表面温度并反馈到温控主单元中与设定的温度值110℃进行比较,当金属基材的实际温度未达到设定值时,电热元件继续加热,当金属基材实际温度达到设定值时,电热元件停止加热;利用注射机将注塑熔体通过模具内设定的浇注系统,直接在金属基材表面形成塑料结构特征;注塑熔体的温度为230℃,注射压力为110MPa,注射完成后保压时间5s,冷却时间20s,保证注塑熔体能充分进入金属基材表面的微孔结构;温控主单元控制冷却水通道冷却金属基材,直至达到设定的温度70℃为止;注塑熔体在金属基材表面冷却固化后,与金属基材形成一体结构,牢固结合在一起,取出即得。First, use alkaline corrosion, anodic oxidation or mechanical sandblasting to form a nano-scale microporous structure on the forming surface of the metal substrate, with a pore size of 30 nanometers to 1 micron, and then put the treated metal substrate into the gold-plastic composite shell In the body forming mold; the temperature control main unit controls the electric heating element to heat the metal base material, making it heated to 85°C within 15s. At the same time, the temperature sensor obtains the surface temperature of the metal base material and feeds it back to the temperature control main unit to match the set temperature. When the actual temperature of the metal substrate does not reach the set value, the electric heating element continues to heat, and when the actual temperature of the metal substrate reaches the set value, the electric heating element stops heating; the injection molding melt is passed through the injection machine The pouring system set in the mold directly forms the plastic structural features on the surface of the metal substrate; the temperature of the injection melt is 230°C, the injection pressure is 110MPa, the pressure holding time is 5s after the injection is completed, and the cooling time is 20s to ensure the performance of the injection melt. Fully enter the microporous structure on the surface of the metal substrate; the temperature control main unit controls the cooling water channel to cool the metal substrate until it reaches the set temperature of 70°C; after the injection melt is cooled and solidified on the surface of the metal substrate, it Form a one-piece structure, combine firmly together, and take it out.
实施例2Example 2
首先利用碱液腐蚀或阳极氧化或机械喷砂的方式在金属基材的成形表面形成纳米级微孔结构,孔径30纳米到1微米,然后将处理好的金属基材放入金-塑复合壳体成型模具中;温控主单元控制电热元件加热金属基材,使其在30s内加热到115℃,同时,温度传感器获取金属基材表面温度并反馈到温控主单元中与设定的温度值110℃进行比较,当金属基材的实际温度未达到设定值时,电热元件继续加热,当金属基材实际温度达到设定值时,电热元件停止加热;利用注射机将注塑熔体通过模具内设定的浇注系统,直接在金属基材表面形成塑料结构特征;注塑熔体的温度为270℃,注射压力为110MPa,注射完成后保压时间10s,冷却时间30s,保证注塑熔体能充分进入金属基材表面的微孔结构;温控主单元控制冷却水通道冷却金属基材,直至达到设定的温度70℃为止;注塑熔体在金属基材表面冷却固化后,与金属基材形成一体结构,牢固结合在一起,取出即得。First, use alkaline corrosion, anodic oxidation or mechanical sandblasting to form a nano-scale microporous structure on the forming surface of the metal substrate, with a pore size of 30 nanometers to 1 micron, and then put the treated metal substrate into the gold-plastic composite shell In the body forming mold; the temperature control main unit controls the electric heating element to heat the metal base material, making it heated to 115°C within 30s. At the same time, the temperature sensor obtains the surface temperature of the metal base material and feeds it back to the temperature control main unit to match the set temperature. When the actual temperature of the metal substrate does not reach the set value, the electric heating element continues to heat, and when the actual temperature of the metal substrate reaches the set value, the electric heating element stops heating; the injection molding melt is passed through the injection machine The pouring system set in the mold directly forms the plastic structural features on the surface of the metal substrate; the temperature of the injection melt is 270°C, the injection pressure is 110MPa, the pressure holding time is 10s after injection, and the cooling time is 30s to ensure the performance of the injection melt. Fully enter the microporous structure on the surface of the metal substrate; the temperature control main unit controls the cooling water channel to cool the metal substrate until it reaches the set temperature of 70°C; after the injection melt is cooled and solidified on the surface of the metal substrate, it Form a one-piece structure, combine firmly together, and take it out.
实施例3Example 3
首先利用碱液腐蚀或阳极氧化或机械喷砂的方式在金属基材的成形表面形成纳米级微孔结构,孔径30纳米到1微米,然后将处理好的金属基材放入金-塑复合壳体成型模具中;温控主单元控制电热元件加热金属基材,使其在20s内加热到100℃,同时,温度传感器获取金属基材表面温度并反馈到温控主单元中与设定的温度值110℃进行比较,当金属基材的实际温度未达到设定值时,电热元件继续加热,当金属基材实际温度达到设定值时,电热元件停止加热;利用注射机将注塑熔体通过模具内设定的浇注系统,直接在金属基材表面形成塑料结构特征;注塑熔体的温度为250℃,注射压力为100MPa,注射完成后保压时间7s,冷却时间25s,保证注塑熔体能充分进入金属基材表面的微孔结构;温控主单元控制冷却水通道冷却金属基材,直至达到设定的温度70℃为止;注塑熔体在金属基材表面冷却固化后,与金属基材形成一体结构,牢固结合在一起,取出即得。First, use alkaline corrosion, anodic oxidation or mechanical sandblasting to form a nano-scale microporous structure on the forming surface of the metal substrate, with a pore size of 30 nanometers to 1 micron, and then put the treated metal substrate into the gold-plastic composite shell In the body forming mold; the temperature control main unit controls the electric heating element to heat the metal base material, making it heated to 100°C within 20s. At the same time, the temperature sensor obtains the surface temperature of the metal base material and feeds it back to the temperature control main unit to match the set temperature. When the actual temperature of the metal substrate does not reach the set value, the electric heating element continues to heat, and when the actual temperature of the metal substrate reaches the set value, the electric heating element stops heating; the injection molding melt is passed through the injection machine The pouring system set in the mold directly forms the plastic structural features on the surface of the metal substrate; the temperature of the injection melt is 250°C, the injection pressure is 100MPa, the holding time after injection is 7s, and the cooling time is 25s to ensure the performance of the injection melt. Fully enter the microporous structure on the surface of the metal substrate; the temperature control main unit controls the cooling water channel to cool the metal substrate until it reaches the set temperature of 70°C; after the injection melt is cooled and solidified on the surface of the metal substrate, it Form a one-piece structure, combine firmly together, and take it out.
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| CN106426692A (en) * | 2016-11-07 | 2017-02-22 | 绵阳市兴和模具有限公司 | Bakelite poured mould |
| CN110970581A (en) * | 2019-12-23 | 2020-04-07 | 东莞塔菲尔新能源科技有限公司 | Light lithium battery shell and preparation method thereof |
| CN111068183B (en) * | 2019-12-31 | 2021-07-27 | 青岛温可微电子科技有限公司 | Manufacturing method of welding type heating device |
| CN111516206A (en) * | 2020-05-17 | 2020-08-11 | 惠州市恺琞实业有限公司 | Battery shell embedded with metal piece and forming method thereof |
| CN112341941B (en) * | 2020-11-27 | 2023-02-03 | 浙江师范大学 | Method for improving bonding of polymer and metal interface |
| CN116175992B (en) * | 2022-12-14 | 2024-04-30 | 湖北三江航天江河橡塑有限公司 | Plastic liner and metal joint integrated forming method |
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