CN103083138B - Manual lifting sling device - Google Patents
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- CN103083138B CN103083138B CN201110334697.2A CN201110334697A CN103083138B CN 103083138 B CN103083138 B CN 103083138B CN 201110334697 A CN201110334697 A CN 201110334697A CN 103083138 B CN103083138 B CN 103083138B
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Abstract
Description
技术领域technical field
本发明涉及提升装置,更具体地说,涉及一种手动提升吊索装置。The present invention relates to lifting devices and, more particularly, to a manual lifting sling device.
背景技术Background technique
医院通常使用提升吊索装置来搬运病人或行动不便的人。在使用提升吊索装置中关键的问题是要防止发生意外和避免病人之间的交叉感染。最早使用的提升吊索装置采用纺织织物制成,且结构较为复杂,设计不够合理,使得产品造价高昂。Hospitals often use lifting sling devices to move patients or people with reduced mobility. The key issues in using lifting sling devices are to prevent accidents and to avoid cross-infection between patients. The earliest hoisting sling device used was made of textile fabric, and the structure was relatively complicated, and the design was not reasonable enough, which made the product cost high.
因此,出于成本问题这些提升吊索装置需要重复使用,因此不可避免地易于发生交叉感染。纺织织物制成的吊索的洗涤过程不是总能杀灭引起感染的生物体,尤其是当采用吊索能承受的温度进行洗涤时。因此当纺织吊索在高于吊索能够承受的温度进行洗涤甚至干燥企图杀死所有传染性生物体时,将导致吊索的损坏。吊索还可能在使用地点和洗涤地点之间运输时遗失或者损坏,因此需要准备足够多的备用吊索,能够在一些吊索被洗涤或者运输时供病人使用。基于由此产生的不良影响,一些医院禁止使用吊索。如果能够降低提升吊索装置的成本,将有利于推广一次性的或有限次使用的提升吊索装置,从而能够解决病人之间的交叉感染问题。因此,如何有效地开发出一种设计合理且成本较低的提升吊索装置是目前亟待解决的问题。Therefore, these lifting sling devices need to be reused due to cost issues, and thus inevitably prone to cross-infection. The washing process for slings made of textile fabrics does not always kill the infection-causing organisms, especially when washed at temperatures that the slings can withstand. Thus when textile slings are washed or even dried at a temperature higher than the sling can withstand in an attempt to kill all infectious organisms, damage to the sling will result. Slings can also be lost or damaged in transit between the point of use and the laundering location, so it is necessary to have enough spare slings available to the patient while some are being laundered or transported. Some hospitals have banned the use of slings due to the resulting adverse effects. If the cost of the lifting sling device can be reduced, it will be beneficial to popularize the one-time or limited-use lifting sling device, thereby being able to solve the problem of cross-infection among patients. Therefore, how to effectively develop a hoisting sling device with reasonable design and low cost is an urgent problem to be solved at present.
发明内容Contents of the invention
本发明要解决的技术问题在于,针对现有提升吊索装置的结构复杂成本较高的缺陷,提供一种手动提升吊索装置。The technical problem to be solved by the present invention is to provide a manual lifting sling device for the defects of the existing lifting sling device which has a complex structure and high cost.
本发明解决其技术问题所采用的技术方案是:构造一种手动提升吊索装置,包括由织物制成的:The technical scheme adopted by the present invention to solve its technical problems is: to construct a kind of manual lifting sling device, including being made of fabric:
用于支撑病人臀部及腿部的底部支撑部;A bottom support for supporting the patient's buttocks and legs;
与所述底部支撑部呈倾斜角接合的用于支撑所述病人背部的后侧支撑部;a rear support for supporting the patient's back engaged at an oblique angle with the bottom support;
分别在左右两侧对病人进行限位的左侧阻挡部和右侧阻挡部,所述左侧阻挡部和右侧阻挡部均同时与所述底部支撑部和后侧支撑部接合;且所述左侧阻挡部和右侧阻挡部上均设有至少两个提升把手。A left blocking part and a right blocking part respectively limit the position of the patient on the left and right sides, and both the left blocking part and the right blocking part are engaged with the bottom supporting part and the rear supporting part at the same time; and the Both the left blocking part and the right blocking part are provided with at least two lifting handles.
在根据本发明所述的手动提升吊索装置中,所述织物为纺织织物或者无纺织物。In the manual lifting sling device according to the present invention, the fabric is a woven fabric or a non-woven fabric.
在根据本发明所述的手动提升吊索装置中,所述底部支撑部、后侧支撑部、左侧阻挡部和右侧阻挡部的边缘被折叠和/或加强,且通过缝合成整体。In the manual lifting sling device according to the present invention, the edges of the bottom supporting part, the rear side supporting part, the left blocking part and the right blocking part are folded and/or reinforced, and integrated by sewing.
在根据本发明所述的手动提升吊索装置中,所述底部支撑部和后侧支撑部被剪裁成符合人体体型,且设置有褶皱。In the manual lifting sling device according to the present invention, the bottom support part and the rear side support part are cut to conform to the body shape of a human body, and are provided with folds.
在根据本发明所述的手动提升吊索装置中,所述织物上设有标识。In the manual lifting sling device according to the present invention, the fabric is provided with a mark.
在根据本发明所述的手动提升吊索装置中,所述织物为一层或者多层纺织或者无纺薄膜层压而成。In the manual lifting sling device according to the present invention, the fabric is formed by laminating one or more layers of woven or non-woven films.
在根据本发明所述的手动提升吊索装置中,所述织物的一侧或两侧上附着有透气的不可生物降解或可生物降解的薄膜。In the manual lifting sling device according to the present invention, a breathable non-biodegradable or biodegradable film is attached to one or both sides of the fabric.
在根据本发明所述的手动提升吊索装置中,所述织物由不可生物降解材料制成,所述不可生物降解材料包括聚丙烯、聚乙烯、聚对苯二甲酸乙二酯或者聚酰胺。In the manual lifting sling device according to the present invention, the fabric is made of non-biodegradable material including polypropylene, polyethylene, polyethylene terephthalate or polyamide.
在根据本发明所述的手动提升吊索装置中,所述纺织织物为可生物降解聚合物材料制成,所述可生物降解聚合物材料为聚乳酸、聚羟基烷基酸酯、聚己二酸-对苯二甲酸丁二酯、聚丁二酸丁二醇酯、聚-β-羟丁酸,或者其中多种材料的共混物。In the manual lifting sling device according to the present invention, the textile fabric is made of a biodegradable polymer material, and the biodegradable polymer material is polylactic acid, polyhydroxyalkanoate, polyhexamethylene Acid - Butylene terephthalate, polybutylene succinate, poly-beta-hydroxybutyrate, or a blend of several of these materials.
在根据本发明所述的手动提升吊索装置中,所述织物由热粘合的不可生物降解或者可生物降解的无规定向纤维制成。In the hand lift sling device according to the present invention, the fabric is made of thermally bonded non-biodegradable or biodegradable randomly oriented fibers.
在根据本发明所述的手动提升吊索装置中,所述无纺织物采用水刺缠结或针刺而成的连续长丝网或者短纤维网制成。In the manual lifting sling device according to the present invention, the non-woven fabric is made of a continuous filament web or a short fiber web formed by hydroentanglement or needle punching.
在根据本发明所述的手动提升吊索装置中,所述无纺织物由采用不可生物 降解或者可生物降解的化学物粘接而成的连续长丝网或者短纤维网制成,所述化学物包括乳胶粘合剂或粘接剂。In the manual lifting sling device according to the present invention, the non-woven fabric is made of a continuous filament web or a short fiber web bonded with non-biodegradable or biodegradable chemicals, and the chemical Substances include latex adhesives or adhesives.
本发明还提供了一种用于防止被搬运的病人之间交叉感染的方法,每个病人具有专用的如上所述的手动提升吊索装置。The present invention also provides a method for preventing cross-infection between patients being carried, each patient having a dedicated manual lifting sling device as described above.
实施本发明的手动提升吊索装置,具有以下有益效果:本发明提供的手动提升吊索装置结构简单,设计合理,舒适度高,且成本低能够为每位病人配置专用的手动提升吊索装置以供有限次的使用。Implementing the manual lifting sling device of the present invention has the following beneficial effects: the manual lifting sling device provided by the present invention is simple in structure, reasonable in design, high in comfort, and low in cost and can be equipped with a dedicated manual lifting sling device for each patient for limited use.
附图说明Description of drawings
下面将结合附图及实施例对本发明作进一步说明,附图中:The present invention will be further described below in conjunction with accompanying drawing and embodiment, in the accompanying drawing:
图1是根据本发明优选实施例中手动提升吊索装置的透视图;Figure 1 is a perspective view of a manual lifting sling device according to a preferred embodiment of the present invention;
图2是根据本发明优选实施例中手动提升吊索装置使用状态示意图。Fig. 2 is a schematic diagram of the use state of the manual lifting sling device according to the preferred embodiment of the present invention.
具体实施方式detailed description
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments.
本发明涉及一种手动提升吊索装置,用于支撑病人身体进行手动搬运。在一些情况下,这种手动提升吊索装置也可以作为担架使用。术语“手动提升吊索装置”、“吊索”、“提升吊索”和“担架”在本发明的描述中可以交换使用,是指一种可供看护人员或者病患搬抬者频繁使用的吊索或者担架。例如,该装置可被用于将受伤病人从事发地点搬运到临近救护车,此时可被称为担架。当随后将病人从床上移动到医院的其它位置时,该装置可被称为提升吊索装置。The invention relates to a manual lifting sling device for supporting a patient's body for manual transport. In some cases, this manual lifting sling unit can also be used as a stretcher. The terms "manual lifting sling device", "sling", "lifting sling" and "stretcher" are used interchangeably in the description of the present invention, and refer to a device that can be frequently used by caregivers or patient lifters. Sling or stretcher. For example, the device may be used to transport an injured patient from the scene of the incident to an adjacent ambulance, in which case it may be referred to as a stretcher. When subsequently moving the patient from the bed to another location in the hospital, the device may be referred to as a lift sling device.
本发明也提供了一种防止使用手动提升吊索搬运的病人之间交叉感染的方法,即这些病人由两个人使用不可生物降解或者可生物降解的手动提升吊索搬抬,其中每个病人具有自己专用的手动提升吊索装置。优选地,每个提升吊索装置清楚地进行了标记,以清楚地识别出该吊索是供哪位病人专用。该提升吊索可以采用持久性的墨水进行标记以保障不被其它人使用。进一步地,提升吊索中的织物由可生物降解的聚合物材料制成,人们已经发现可生物降解的无 纺吊索的成本仅为纺织吊索成本的几分之一,并在大部分人的承受范围内。因此,可以为每个人配置专用的吊索,能在防止病人之间发生交叉感染的同时,因为该手动提升吊索装置采用的织物材料可生物降解和/或可堆肥,使得使用后丢弃的吊索不会污染环境。The present invention also provides a method of preventing cross-infection between patients carried using manual lifting slings, i.e. the patients are lifted by two persons using non-biodegradable or biodegradable manual lifting slings, wherein each patient has Own dedicated manual lifting sling device. Preferably, each lifting sling assembly is clearly marked to clearly identify which patient it is intended for. The lifting sling can be marked with permanent ink to secure it from being used by others. Furthermore, the fabric in the lifting sling is made of a biodegradable polymer material, and it has been found that the cost of a biodegradable non-woven sling is only a fraction of the cost of a textile sling, and in most people within the acceptable range. Therefore, a dedicated sling can be configured for each person, while preventing cross-infection between patients, because the fabric material used in the manual lifting sling device is biodegradable and/or compostable, so that the sling that is discarded after use cable will not pollute the environment.
图1是根据本发明优选实施例的手动提升吊索装置的透视图。如图1所示,图中示出了手动提升吊索装置10包括由织物制成的:底部支撑部12、后侧支撑部11、左侧阻挡部13和右侧阻挡部14。其中,底部支撑部12位于底部用于支撑病人臀部及腿部。后侧支撑部11与底部支撑部12呈倾斜角,用于支撑该病人背部。后侧支撑部11的下侧边缘与底部支撑部12的后侧边缘接合,且所呈的倾斜角优选为钝角,以便于病人坐在该手动提升吊索装置10中。后侧支撑部11和底部支撑部12优选呈等腰梯形形状,两个较长的底边接合在一起。Figure 1 is a perspective view of a manual lift sling arrangement according to a preferred embodiment of the present invention. As shown in FIG. 1 , a manual lifting sling device 10 is shown comprising: a bottom support part 12 , a rear support part 11 , a left stop part 13 and a right stop part 14 made of fabric. Wherein, the bottom supporting part 12 is located at the bottom for supporting the patient's buttocks and legs. The rear support part 11 and the bottom support part 12 form an oblique angle for supporting the patient's back. The lower edge of the rear support portion 11 joins the rear edge of the bottom support portion 12 at an obtuse angle so that the patient can sit in the manual lift sling device 10 . The rear support portion 11 and the bottom support portion 12 are preferably in the shape of an isosceles trapezoid, with two longer bases joined together.
左侧阻挡部13和右侧阻挡部14分别在左右两侧对病人进行限位。左侧阻挡部13和右侧阻挡部14均同时与底部支撑部12和后侧支撑部11接合。在一些实施例中,左侧阻挡部13大致呈三角形,其中一个底边与底部支撑部12的左侧腰相接,另一个底边与后侧支撑部11的左侧腰相接。同理,右侧阻挡部14与之相对应。在另一些实施例中,如图1中左侧阻挡部13由分别与底部支撑部12或后侧支撑部11接合的两个三角形组成,以便扩大手动提升吊索装置10所围成的空间。该手动提升吊索装置10关于中轴面对称。The left blocking part 13 and the right blocking part 14 limit the position of the patient on the left and right sides respectively. Both the left side stopper 13 and the right side stopper 14 are engaged with the bottom support part 12 and the rear side support part 11 at the same time. In some embodiments, the left blocking portion 13 is roughly triangular in shape, one of the bases is connected to the left waist of the bottom support portion 12 , and the other bottom is connected to the left waist of the rear support portion 11 . Similarly, the right blocking portion 14 corresponds thereto. In some other embodiments, as shown in FIG. 1 , the left blocking portion 13 is composed of two triangles respectively connected with the bottom supporting portion 12 or the rear supporting portion 11 , so as to expand the space enclosed by the manual lifting sling device 10 . The manual lifting sling device 10 is symmetrical about the central axis.
在左侧阻挡部13和右侧阻挡部14上均设置了至少2个提升把手15。例如在本实施例中,左侧阻挡部13的上侧和下侧分别设置了1个提升把手15,以分别对病人的背部区域和腿部区域着力。同理,右侧阻挡部14也设置了2个提升把手15。At least two lifting handles 15 are provided on the left blocking portion 13 and the right blocking portion 14 . For example, in this embodiment, a lifting handle 15 is respectively provided on the upper side and the lower side of the left blocking part 13, so as to exert force on the patient's back area and leg area respectively. Similarly, two lifting handles 15 are also provided on the right blocking portion 14 .
优选地,底部支撑部12、后侧支撑部11、左侧阻挡部13和右侧阻挡部14的边缘均被折叠和/或加强,且通过缝合成整体。例如边缘16处采用多次折叠,并通过针线缝合或者超声粘合。优选地,底部支撑部12和后侧支撑部11被剪裁成符合人体体型,例如设置有褶皱18。在设置提升把手15的区域17,对其进行增强,例如进行加厚处理,在织物上额外增设织物薄膜。Preferably, the edges of the bottom support portion 12 , the rear support portion 11 , the left blocking portion 13 and the right blocking portion 14 are all folded and/or reinforced, and stitched into a whole. For example, multiple folds are used at the edge 16 and stitched or ultrasonically bonded. Preferably, the bottom support portion 12 and the rear support portion 11 are cut to conform to the body shape of the human body, for example, folds 18 are provided. In the area 17 where the lifting handle 15 is located, it is reinforced, for example thickened, with an additional fabric film on the fabric.
此外,可以在该手动提升吊索装置10的织物上设置标识。例如缝上标签 或者用持久性墨水笔写上相关文字。例如,可以标签的上部写上病人的名字,或者其它一些通用识别字符,如“请勿清洗”“请勿熨烫”“请勿甩干”等。In addition, markings may be provided on the fabric of the manual lifting sling device 10 . For example, sew on a label or write on it with a permanent ink pen. For example, the patient's name can be written on the upper part of the label, or some other common identification characters, such as "do not wash", "do not iron", "do not tumble dry" and so on.
如图2所示,为根据本发明优选实施例中手动提升吊索装置使用状态示意图。病人坐入该手动提升吊索装置围成的空间内,由该吊索支撑背部、臀部和腿部。由两个人来搬抬该手动提升吊索装置。其中每个人抓住吊索每侧的2个把手,其中一个把手支撑病人的背部,另一个把手支撑坐下的病人的臀部和腿部。As shown in FIG. 2 , it is a schematic diagram of the use state of the manual lifting sling device according to the preferred embodiment of the present invention. The patient sits in the space enclosed by the manual lifting sling device, and the back, buttocks and legs are supported by the sling. Two people are required to lift the hand lift sling. Each of them grasps the 2 handles on each side of the sling, one of which supports the patient's back and the other supports the seated patient's buttocks and legs.
本发明可以采用纺织织物或者无纺织物制成。优选采用无纺织物制成,可以在无纺织物上设置有通过滚压(压延)形成的凸起图案,以使其具有纺织织物的外观。可通过附件织物层加固吊索装置。本发明提供的手动提升吊索装置尽管推荐的安全重量为120kg,但是已经试验证明能经受50次提升190kg的重物且无任何磨损的迹象。The present invention can be made of woven fabric or non-woven fabric. It is preferably made of a non-woven fabric, on which a raised pattern formed by rolling (calendering) can be provided to give it the appearance of a woven fabric. The sling unit can be reinforced with an additional fabric layer. Although the manual lifting sling device provided by the present invention has a recommended safe weight of 120kg, it has been tested and proven to withstand 50 times of lifting a 190kg heavy object without any signs of wear.
此外,织物可以为一层或者多层纺织或者无纺薄膜层压而成。还可将透气的或非透气的薄膜层压到吊索的生物降解无纺织物的一侧或两侧上,以能在提升和搬运过程中吸附病人的任何体液。Additionally, the fabric may be a laminate of one or more layers of woven or nonwoven film. A breathable or non-breathable film may also be laminated to one or both sides of the biodegradable nonwoven fabric of the sling to absorb any bodily fluids of the patient during lifting and handling.
本发明的手动提升吊索装置可以由不可生物降解的织物制成。这些不可生物降解材料包括PP(聚丙烯)、PE(聚乙烯)、PET(聚对苯二甲酸乙二酯)或者PA(聚酰胺),以及其它人造聚合物。The hand lift sling device of the present invention may be made of non-biodegradable fabric. These non-biodegradable materials include PP (polypropylene), PE (polyethylene), PET (polyethylene terephthalate) or PA (polyamide), among other man-made polymers.
优选地,本发明的手动提升吊索装置还可以由无纺的可生物降解/堆肥的材料制成,典型的为PLA(聚乳酸)、或主要部分为PLA加少量的PHA(聚羟基烷基酸酯)的共混物、或主要部分为PLA加少量的PHA和PBAT(聚己二酸-对苯二甲酸丁二酯)的共混物、或主要部分为PLA加少量的PHA、PBAT和PBS(聚丁二酸丁二醇酯)的共混物、或主要部分为PLA加少量的PBAT和PBS的共混物、或PBAT和PBS的共混物、或主要部分为PLA加少量的PHB(聚-β-羟丁酸)的共混物。Preferably, the manual lifting sling device of the present invention can also be made of non-woven biodegradable/compostable materials, typically PLA (polylactic acid), or a major part of PLA plus a small amount of PHA (polyhydroxyalkyl ester), or a blend of PLA plus a small amount of PHA and PBAT (polybutylene adipate-terephthalate), or a blend of PLA plus a small amount of PHA, PBAT and A blend of PBS (polybutylene succinate), or a blend of PLA plus a small amount of PBAT and PBS, or a blend of PBAT and PBS, or a major part of PLA plus a small amount of PHB (poly-beta-hydroxybutyric acid) blend.
优选地,可以通过热粘接的生物降解/堆肥的聚合物无规定向纤维制成所述吊索,但是也可通过干法成网、化学粘接(采用生物降解粘接剂)的织物制成,或由干法成网或水刺(水刺缠结)织物制成。该材料通常是具有透气性(除 非有非透气的生物降解薄膜粘附在上面)但不能穿过水,且可能需要在吊索中设置穿孔,以用于降低病人进入到浴池中。织物可以采用水刺缠结或针刺而成的连续长丝网或者短纤维网制成。该织物可以由采用不可生物降解或者可生物降解的化学物粘接而成的连续长丝网或者短纤维网制成,所述化学物包括乳胶粘合剂或粘接剂。Said slings are preferably made from thermally bonded biodegradable/compostable polymer random oriented fibers, but can also be made from dry laid, chemically bonded (with biodegradable adhesive) fabrics into, or from dry-laid or spunlace (spunlace entangled) fabrics. The material is usually breathable (unless a non-breathable biodegradable film is adhered to it) but impermeable to water and may require perforations in the sling for lowering the patient's access to the bath. Fabrics can be made from webs of continuous filaments or staple fibers that are hydroentangled or needle punched. The fabric may be made from a web of continuous filaments or staple fibers bonded with non-biodegradable or biodegradable chemicals, including latex binders or adhesives.
为了使不再使用的丢弃的手动提升吊索装置不会对环境造成负面影响,手动提升吊索装置中的织物优选采用可生物降解的和/或可堆肥的织物。以下将讨论上述可生物降解的和/或可堆肥的织物。本发明中所采用的可生物降解的材料既能确保吊索装置具有相应的承载能力,防止在提升中出现意外;同时也不会增加吊索装置的制造成本,从而使得病人可以承担得起专人专用的提升吊索装置,避免交叉感染的发生。In order that the discarded hand lift sling that is no longer used has no negative impact on the environment, the fabric in the hand lift sling is preferably biodegradable and/or compostable. The aforementioned biodegradable and/or compostable fabrics are discussed below. The biodegradable material used in the present invention can not only ensure that the sling device has a corresponding bearing capacity and prevent accidents during lifting; Special lifting sling device to avoid cross-infection.
在当前常见的可生物降解的聚合物中,聚乳酸(PLA)在用于塑料和织物的可生物降解/堆肥的聚合物领域的优势在于,尽管PLA从自然的和可再生的材料中提取,但是它具有热塑性,能通过熔融挤压以生产塑料制品、纤维和织物,与基于石油合成制成的类似材料,诸如聚烯烃(聚乙烯和聚丙烯)和聚酯(聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯)相比,PLA制品具有良好的机械强度,韧性和柔软性。PLA由乳酸制成,该乳酸是从玉米、小麦、谷物或甜菜中提取的发酵副产品。当聚合形成时,乳酸形成具有以下所示的二聚体重复单元的脂肪族聚酯:Among the current common biodegradable polymers, the advantage of polylactic acid (PLA) in the field of biodegradable/compostable polymers for plastics and fabrics is that although PLA is extracted from natural and renewable materials, However, it is thermoplastic and can be melt-extruded to produce plastic products, fibers and fabrics, and similar materials based on petroleum synthesis, such as polyolefins (polyethylene and polypropylene) and polyester (polyethylene terephthalate) Compared with alcohol esters and polyethylene terephthalate), PLA products have good mechanical strength, toughness and flexibility. PLA is made from lactic acid, a by-product of fermentation extracted from corn, wheat, grains or sugar beets. When polymerized, lactic acid forms aliphatic polyesters with dimer repeat units shown below:
已发现聚(聚羟基烷基酸酯)(PHA)能通过多种作为碳源和能源的细胞内贮存材料的细菌的自然合成制得。其中P(3HB-co-4HB)的共聚酯重复单元如以下所示:It has been discovered that poly(polyhydroxyalkanoate) (PHA) can be produced by the natural synthesis of various bacteria as an intracellular storage material of carbon and energy. Wherein the copolyester repeating unit of P(3HB-co-4HB) is as follows:
聚己二酸-对苯二甲酸丁二酯(PBAT)这种可生物降解的聚合物目前无法从细菌源制得,但是可以从基于石油的产品合成制得。尽管PBAT的熔点为120℃,低于PLA的熔点,但是PBAT具有比PLA更高的弹性、优良的耐冲击强度和良好的熔体加工性能。虽然PLA具有良好熔体加工性能、强度和生物降解/堆肥性能,但是其弹性和耐冲击强度不佳。而PBAT和PLA的共混物的具有增强的弹性、柔韧性和耐冲击强度。PBAT的化学结构如以下所示:Polybutylene adipate-terephthalate (PBAT), a biodegradable polymer, cannot currently be produced from bacterial sources, but can be produced synthetically from petroleum-based products. Although the melting point of PBAT is 120°C, which is lower than that of PLA, PBAT has higher elasticity, excellent impact strength and good melt processability than PLA. While PLA has good melt processability, strength and biodegradability/compostability, it suffers from poor elasticity and impact strength. The blend of PBAT and PLA has enhanced elasticity, flexibility and impact strength. The chemical structure of PBAT is shown below:
聚丁二酸丁二醇酯(PBS)可通过乙二醇的缩聚反应合成制得。PBS的化学结构如以下所示:Polybutylene succinate (PBS) can be synthesized by polycondensation of ethylene glycol. The chemical structure of PBS is shown below:
尽管已显示P(3HB-co-4HB)产品易于在土壤、污泥和海水中生物降解,但是因水中缺乏微生物而使水中的生物降解速率非常慢(Saito,Yuji,Shigeo Nakamura,MasayaHiramitsu and Yoshiharu Doi,“Microbial Synthesis and Properties of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate),”Polymer International 39(1996),169-174)。因此P(3HB-co-4HB)产品的保存期限在诸如密封包装的干燥存储、清洁溶液等的清洁环境中应当是非常优良的。然而,当置于包含微生物的诸如土壤、河水、河泥、海水以及肥料和沙子、污泥和海水的堆肥的脏环境中时,丢弃的P(3HB-co-4HB)织物、薄膜和封装材料应当易于降解。应当注意的是,聚乳酸(PLA)在以上的脏环境中和环境温度下不易于生物降解,但是必须进行堆肥。首先,堆肥堆中的热度和湿度必须将PLA聚合物分解成更小的聚合物链,最后分解成乳酸。堆肥和土壤中的微生物将更小的聚合物片段和乳酸作为养分而消耗了它们。因此,诸如具有PLA的P(3HB-co-4HB)产品的聚羟基烷酸酯(PHA)混合物应当增强了由PHAs-PLA的共混物制成的产品的降解。另外,由PHA和PLA的共混物制成 的产品应当已经增强了在清洁环境中保存期限。然而,在过去的10年,PLA的价格已经大幅度地降低到只比诸如聚丙烯和PET聚酯的合成聚合物稍高一点;与此同时,PHAs的价格继续保持比PLA的高2到3倍,该PLA可大规模地由乳酸合成。PHAs有具有特定碳源的细菌制成,且必须采用溶剂从细菌提取。因此,在商业上无法实现将超过25%的PHA与PLA混合,以熔融挤压形成产品,诸如纺织织物、针织和无纺织物、薄膜、食品包装容器等。Although P(3HB-co-4HB) products have been shown to be readily biodegradable in soil, sludge and seawater, the rate of biodegradation in water is very slow due to the absence of microorganisms in water (Saito, Yuji, Shigeo Nakamura, Masaya Hiramitsu and Yoshiharu Doi , "Microbial Synthesis and Properties of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)," Polymer International 39(1996), 169-174). Therefore the shelf life of the P(3HB-co-4HB) product should be very good in clean environments such as dry storage in airtight packaging, cleaning solutions, and the like. However, discarded P(3HB-co-4HB) fabrics, films, and packaging materials, when placed in dirty environments containing microorganisms such as soil, river water, river mud, seawater, and composts of manure and sand, sludge, and seawater Should be readily degradable. It should be noted that polylactic acid (PLA) does not readily biodegrade in the above dirty environments and ambient temperatures, but must be composted. First, the heat and humidity in the compost heap must break down the PLA polymers into smaller polymer chains and finally into lactic acid. Microorganisms in the compost and soil consumed the smaller polymer fragments and lactic acid as nutrients. Therefore, polyhydroxyalkanoate (PHA) blends such as P(3HB-co-4HB) products with PLA should enhance the degradation of products made from blends of PHAs-PLA. Additionally, products made from blends of PHA and PLA should have enhanced shelf life in clean environments. However, in the past 10 years, the price of PLA has dropped dramatically to only slightly higher than that of synthetic polymers such as polypropylene and PET polyester; meanwhile, the price of PHAs continues to remain 2 to 3 times higher than that of PLA. times, the PLA can be synthesized from lactic acid on a large scale. PHAs are made by bacteria with a specific carbon source and must be extracted from the bacteria using a solvent. Therefore, it is commercially impossible to blend more than 25% PHA with PLA to melt-extrude to form products such as woven fabrics, knitted and non-woven fabrics, films, food packaging containers, and the like.
表1中示出了生物降解无纺织物、生物降解薄膜和无纺织物与生物降解薄膜的层压结构。从中国的供应商可获得具有9微米(μm)的纯PBAT薄膜和具有20%的碳酸钙的9μm的PBAT薄膜。从美国的Biax-Fiberfilm公司可获得包含20%的聚丙烯(PP)(非生物降解的)的熔喷(MB)(非生物降解的)。可从德国的Saxon Textile研究结构获得通常质量为80g/m2的具有碳黑的黑色纺粘(SB)PLA。在分别的试验中,使用5-13g/m2的热熔粘接剂将纯PBAT薄膜和具有20%的碳酸钙的PBAT薄膜层压到包含20%PP的Vistamaxx MB和黑色SB PLA上。通常应当使用0.5-12g/m2的热熔粘和优选的1-7g/m2的热熔粘。另外,使用熔融粘接剂层压和粘连两层SB PLA。图1中示出了对所有的原材料和层压结构所测试的重量、厚度、韧性、断裂伸长率、撕裂强度、耐破强度、透水蒸汽速率(MVT)和水头(hydrohead)。应当注意的是这些只是本发明的不同实施例的一些示例,且使用熔融应用将以下材料的不同层粘连到一起:PBAT薄膜或其它可生物降解/堆肥的薄膜,能够通过挤压涂层直接应用的衬底上而不需要粘接剂。能通过但不限于热点压延、整体压延或超声波焊接将层压结构连接或粘接到一起。另外,取代熔融粘接剂,已能使用以胶或水或溶剂为基础的粘接剂或乳胶来将层压结构粘接到一起。Table 1 shows biodegradable nonwoven fabrics, biodegradable films, and laminated structures of nonwoven fabrics and biodegradable films. Pure PBAT films with 9 micrometers ([mu]m) and 9 [mu]m PBAT films with 20% calcium carbonate are available from suppliers in China. Meltblown (MB) containing 20% polypropylene (PP) (non-biodegradable) is available from Biax-Fiberfilm, USA (non-biodegradable). Black spunbond (SB) PLA with carbon black is available in a typical mass of 80 g /m2 from Saxon Textile Research Institute in Germany. In separate tests, neat PBAT films and PBAT films with 20% calcium carbonate were laminated to Vistamaxx MB and black SB PLA containing 20% PP using 5-13 g /m2 hot melt adhesive. Typically 0.5-12 g/ m2 of hot melt and preferably 1-7 g/ m2 of hot melt should be used. Alternatively, two layers of SB PLA were laminated and bonded using a fusion adhesive. The weight, thickness, toughness, elongation at break, tear strength, burst strength, water vapor transmission rate (MVT) and hydrohead tested for all raw materials and laminated structures are shown in FIG. 1 . It should be noted that these are just a few examples of different embodiments of the invention and that melt application is used to bond together different layers of: PBAT film or other biodegradable/compostable film that can be applied directly by extrusion coating substrate without the need for adhesives. The laminated structures can be joined or bonded together by, but not limited to, hot spot calendering, bulk calendering, or ultrasonic welding. Additionally, instead of melt adhesives, glue or water or solvent based adhesives or latexes have been used to bond laminated structures together.
表1聚合物的强度和阻隔属性Table 1 Strength and barrier properties of polymers
*DNB:表示由于高弹性而没有被顶破*DNB: means not broken due to high elasticity
如表1所示,9μm的纯(100%)PBAT薄膜(样品1)在MD方向具有良好的伸长率且在CD方向上的断裂伸长率高达300%以上。不能对样品1到5执行耐破强度测试,因为所有的这些薄膜和层压结构的弹性的非常好,在测试过程中不会断裂且在测试后也不会表现出变形。样品1的透水蒸汽速率相当好,为每24小时3380g/m2的,同时静压头为549mm。具有20%碳酸钙(CaCO3)的PBAT薄膜(样品2)具有与样品1类似的数据,其中WVTR和静水头(hydrostatichead)都相对更低。预计与样品1和2类似的且具有6μm或以下更小厚度的PBAT薄膜也具有良好的伸长率和更高的WVTR,尽管水头可能更低。熔喷样品3包含80%的(基于Vistamaxx聚烯烃的聚合物具有高弹性且通过ExxonMobil制成)和20%的PP,因为该织物是适度开放的,因此具有约300%的MD和CD伸长率以及每24小时8816g/m2的高WVTR。尽管MBVistamaxx织物不是生物降解的,但是它是有可能从生物降解聚合物制成的一种弹性无纺材料的示例,所述生物降解聚合物诸如具有非常高伸长率和形变恢复能力的PBAT和其它生物降解聚合物。样品3的水头相当高,为1043mm,表明其具有良好的阻隔性能。应当注意的是,将20%的PP添加到Vistamaxx聚合物颗粒,并且在共混物喂入MB挤压机之前进行物理混合,且进行熔融以使得Vistamaxx MB织物不会太黏。如果熔喷100%的Vistamaxx,则将非常黏,且可能在滚压中结块,且难于在后续的层压或使用中展开(un-wind)。As shown in Table 1, a 9 μm pure (100%) PBAT film (Sample 1) has good elongation in MD direction and a high elongation at break of more than 300% in CD direction. Bursting strength tests could not be performed on samples 1 to 5 because all of these films and laminated structures were very resilient, did not break during the test and did not exhibit deformation after the test. The water vapor transmission rate of sample 1 is quite good at 3380 g/m2 per 24 hours with a static head of 549 mm. The PBAT film with 20% calcium carbonate (CaCO3) (Sample 2 ) had similar data to Sample 1, with relatively lower WVTR and hydrostatic head. PBAT films similar to Samples 1 and 2 and having a smaller thickness of 6 μm or less are also expected to have good elongation and higher WVTR, although the water head may be lower. Melt blown sample 3 contained 80% of (Vistamaxx polyolefin based polymer with high elasticity and made by ExxonMobil) and 20% PP, since the fabric is moderately open, it has about 300% MD and CD elongation and 8816 g/m per 24 hours High WVTR of 2 . Although MBVistamaxx fabric is not biodegradable, it is an example of a type of elastic nonwoven material that is possible to make from biodegradable polymers such as PBAT and Other biodegradable polymers. Sample 3 had a fairly high head of 1043 mm, indicating good barrier properties. It should be noted that 20% PP was added to the Vistamaxx polymer pellets and the blend was physically mixed and melted before the blend was fed into the MB extruder so that the Vistamaxx MB fabric was not too sticky. If 100% Vistamaxx is melt blown, it will be very sticky and may clump during rolling and be difficult to un-wind for subsequent lamination or use.
与仅有Vistamaxx相比,使用热熔粘接剂且具有Vistamaxx的纯PBAT和 包含20%的CaC03的PBAT的层压结构显著增加了MD和CD韧性。该样品还具有非常高的MD伸长率和尤其高的CD伸长率(样品4为390%,样品5为542%)。样品4和样品5还具有显著高的MVTR值,分别为每24小时1671和1189g/m2,且具有高水头,分别为339和926mm水。再次应当注意的是,PBAT薄膜已经能直接挤压涂层到MB 100%Vistamaxx上或具有一些PP的MBVistamaxx上且使用或没有使用热熔粘接剂,并且挤压涂层已经允许使用更薄规格的PBAT薄膜,低至4或5μm,由此具有更高的MVTR,但是可能具有更低的水头。Laminations of pure PBAT with Vistamaxx and PBAT containing 20 % CaC03 using hot-melt adhesives significantly increased MD and CD toughness compared to Vistamaxx alone. The samples also had very high MD elongation and especially high CD elongation (390% for sample 4 and 542% for sample 5). Samples 4 and 5 also had significantly high MVTR values of 1671 and 1189 g/m2 per 24 hours, respectively, and high water heads of 339 and 926 mm water, respectively. Again it should be noted that PBAT films have been extrusion coated directly onto MB 100% Vistamaxx or MBVistamaxx with some PP with or without hot melt adhesive and extrusion coating has allowed thinner gauges PBAT films, down to 4 or 5 μm, thus have higher MVTR, but possibly lower water head.
黑色SB PLA的目标重量是80g/m2,MD韧性为104N且CD韧性为31N,但是具有更低的MD断裂伸长率,为3.6%,而具有高CD伸长率,为30.7%。耐破强度为177KN/m2且WVTR相当高,为每24小时8322g/m2,且水头相当明显,为109mm。采用熔热粘接剂层压到纯PBAT上的80gsm的黑色SB PLA的MD和CD韧性分别比单纯的SB PLA高,其分别为107和39N,但是CD伸长率仅为9.8%。但是层压了SB PLA的PBAT具有更高的耐破强度,为220KN/m2。但是透气性仍然保持优良,WVTR为每24小时2459g/m2,且具有非常高的水头,为3115mm水。层压了包含20%CaCO3的PBAT的SB PLA具有与样品8类似的属性,除了水头比较低,尽管仍高达2600mm水。具有更薄PBAT薄膜以及特别具有通过挤压涂层沉积形成的更薄PBAT薄膜的SBPLA层压结构,可生产用于具有高MVTR的医学、工业或体育应用的防护服,因其能穿着舒适且具有高净水头以用于屏障防护。能通过在薄膜的层压之前或之后,要么在PBAT薄膜侧要么在任一侧上的SB PLA上应用整理剂(氟硅或其它类型的整理剂),来进一步增强屏障防护。还可通过在薄膜的层压之前或之后将MB PLA与SB PLA层压结合来增强屏障防护。还可能将整理剂添加到用于制备例如PBAT薄膜、SB或MB PLA的聚合物熔体中。The black SB PLA had a target weight of 80 g/m 2 , a MD toughness of 104N and a CD toughness of 31N, but had a lower MD elongation at break of 3.6% and a high CD elongation of 30.7%. The bursting strength is 177KN/m 2 and the WVTR is quite high at 8322g/m 2 per 24 hours, and the water head is quite significant at 109mm. The MD and CD toughness of 80 gsm black SB PLA laminated to pure PBAT with hot melt adhesive is higher than pure SB PLA, which are 107 and 39 N, respectively, but the CD elongation is only 9.8%. But the PBAT laminated with SB PLA has a higher bursting strength of 220KN/m 2 . But the air permeability is still excellent, the WVTR is 2459g/m 2 per 24 hours, and it has a very high water head, which is 3115mm of water. SB PLA laminated with PBAT containing 20 % CaCO3 had similar properties to sample 8, except for a lower hydraulic head, although still as high as 2600 mm water. SBPLA laminate structures with thinner PBAT films and especially with thinner PBAT films deposited by extrusion coating, can produce protective clothing for medical, industrial or sports applications with high MVTR, because they can be worn comfortably and Has a high net head for barrier protection. Barrier protection can be further enhanced by applying a finish (fluorosilicone or other type of finish) either on the PBAT film side or on the SB PLA on either side, before or after lamination of the film. Barrier protection can also be enhanced by laminating MB PLA with SB PLA either before or after lamination of the film. It is also possible to add finishing agents to the polymer melts used to make eg PBAT films, SB or MB PLA.
当将两层SB PLA熔粘接结合在一起而形成样品9时,MD和CD韧性和耐破强度实质上是一层结构的样品6的两倍。对应从110g/m2SB PP产生的病人提升吊索的断裂伸长率(%伸长率)的目标MD和CD韧性分别至少每5cm为200和140N,MD和CD中的伸长率值至少都为40%。如表1所示,两个 粘接结合的SB PLA层的MD韧性为215N,但CD韧性仅为所需级别的50%。而且MD和CD的断裂伸长率比40%的所需最小值要低得多。能通过在SB织物挤压之前将PLA与5到60%的PBAT或优选地20到50%的PBAT共混,以增强SB PLA的MD和CD伸长率。另外,可将PBAT和PBS与PLA共混以获得具有所需MD和CD韧性和伸长率值以及热暴露后稳定性的织物。另外,可通过非热点压延的工艺粘接SB长丝网,以获得更大的多方向强度和伸长率以包含水刺缠结式和针刺式。能生成110g/m2和更大重量的针刺SB PLA而不需要将两个或多个SB PLA织物层压或粘接结合在一起以获得所需的强度和伸长率值。When two layers of SB PLA were melt-bonded together to form Sample 9, the MD and CD toughness and burst strength were substantially double those of Sample 6, which was a one-layer construction. Target MD and CD tenacities corresponding to elongation at break (% elongation) of patient lifting slings produced from 110 g/m 2 SB PP are at least 200 and 140 N per 5 cm, respectively, with elongation values in MD and CD of at least Both are 40%. As shown in Table 1, the MD toughness of two adhesively bonded SB PLA layers was 215N, but the CD toughness was only 50% of the required grade. Also the elongation at break in MD and CD is much lower than the required minimum of 40%. The MD and CD elongation of SB PLA can be enhanced by blending PLA with 5 to 60% PBAT or preferably 20 to 50% PBAT prior to SB fabric extrusion. Additionally, PBAT and PBS can be blended with PLA to obtain fabrics with desired MD and CD tenacity and elongation values and stability after heat exposure. In addition, the SB filament web can be bonded by non-hot spot calendering to obtain greater multi-directional strength and elongation to include hydroentangling and needle punching. Needlepunched SB PLA of 110 g/ m2 and greater can be produced without the need to laminate or bond two or more SB PLA fabrics together to obtain the desired strength and elongation values.
在表2中,将两种SB PLA织物进行了对比,其中一种由100%PLA组成,另一种由质量百分比80%PLA和20%PHB组成。表中示出了80%PLA/20%PHB的混合物比100%PLA SB具有更好地MD和CD韧性,且MD伸长率为100%PLA SB的4倍,CD伸长率为100%PLA SB的3倍。使用热熔胶层压两层样品11来制备表1中的样品9,这样制得的织物与前述样品9相比具有非常高的MD和CD拉升强度和撕裂强度,以及较高的伸长率。In Table 2, two SB PLA fabrics are compared, one of which is composed of 100% PLA and the other is composed of 80% PLA and 20% PHB by mass percentage. The table shows that the blend of 80% PLA/20% PHB has better MD and CD toughness than 100% PLA SB, and the elongation in MD is 4 times that of 100% PLA SB, and the elongation in CD is 100% PLA 3 times of SB. Sample 9 in Table 1 was prepared by laminating two layers of sample 11 with hot melt adhesive, and the resulting fabric had very high MD and CD tensile and tear strengths, as well as higher elongation compared to the previous sample 9. long rate.
表2 SB 100%PLA与SB 80%PLA/20%PHB的性能对比Table 2 Performance comparison of SB 100% PLA and SB 80% PLA/20% PHB
本发明是根据特定实施例进行描述的,但本领域的技术人员应明白在不脱离本发明范围时,可进行各种变化和等同替换。此外,为适应本发明技术的特定场合或材料,可对本发明进行诸多修改而不脱离其保护范围。因此,本发明并不限于在此公开的特定实施例,而包括所有落入到权利要求保护范围的实施例。The present invention has been described based on specific embodiments, but those skilled in the art will understand that various changes and equivalent substitutions can be made without departing from the scope of the present invention. In addition, many modifications may be made to adapt the technique to a particular situation or material without departing from its scope. Therefore, it is intended that the invention not be limited to the particular embodiments disclosed herein, but include all embodiments falling within the scope of the appended claims.
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| CN1524509A (en) * | 2003-02-27 | 2004-09-01 | back support pad | |
| CN200939220Y (en) * | 2006-08-24 | 2007-08-29 | 美亚无纺布工业(美商)有限公司 | ambulance delivery device |
| CN101805523A (en) * | 2010-04-06 | 2010-08-18 | 王文广 | Superfine biological powder filling masterbatch and method for preparing same |
| CN102219988A (en) * | 2010-04-14 | 2011-10-19 | 美亚无纺布工业有限公司 | Degradable recycling material |
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| CN1184628A (en) * | 1996-09-05 | 1998-06-17 | 阿佐有限公司 | Lifting slings |
| GB2347135A (en) * | 1999-02-26 | 2000-08-30 | Pauline Guilfoyle | Invalid lifting sling |
| CN1524509A (en) * | 2003-02-27 | 2004-09-01 | back support pad | |
| CN200939220Y (en) * | 2006-08-24 | 2007-08-29 | 美亚无纺布工业(美商)有限公司 | ambulance delivery device |
| CN101805523A (en) * | 2010-04-06 | 2010-08-18 | 王文广 | Superfine biological powder filling masterbatch and method for preparing same |
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